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Chem 2444: (Second Semester Organic Chemistry) UConn

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Chem 2444: (Second Semester Organic Chemistry) UConn

Chemistry
Publisher
LibreTexts
Source
LibreTexts
Language
EN
Category
Basic Sciences
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Contents· 131 sections
  1. 01: Structure Determination (Mass Spectrometry IR and UV-Vis Spectroscopy)
  2. 1.01: Mass Spectrometry of Small Molecules - Magnetic-Sector Instruments
  3. 1.02: Interpreting Mass Spectra
  4. 1.03: Mass Spectrometry of Some Common Functional Groups
  5. 1.04: Spectroscopy and the Electromagnetic Spectrum
  6. 1.05: Infrared Spectroscopy
  7. 1.06: Interpreting Infrared Spectra
  8. 1.07: Infrared Spectra of Some Common Functional Groups
  9. 1.08: Structure Determination in Conjugated Systems- Ultraviolet Spectroscopy
  10. 1.09: Interpreting Ultraviolet Spectra- The Effect of Conjugation
  11. 1.S: Conjugated Compounds and Ultraviolet Spectroscopy (Summary)
  12. 02: Nuclear Magnetic Resonance
  13. 2.01: Hydrogen Nuclear Magnetic Resonance
  14. 2.02: Using NMR Spectra to Analyze Molecular Structure- The Proton Chemical Shift
  15. 2.03: Integration
  16. 2.04: Spin-Spin Splitting- The Effect of Nonequivalent Neighboring Hydrogens
  17. 2.05: Carbon-13 Nuclear Magnetic Resonance
  18. 03: Conjugated Pi-Systems and Aromaticity
  19. 3.01: Stability of Conjugated Dienes- Molecular Orbital Theory
  20. 3.02: Electrophilic Additions to Conjugated Dienes- Allylic Carbocations
  21. 3.03: Kinetic vs. Thermodynamic Control of Reactions
  22. 3.04: Naming Aromatic Compounds
  23. 3.05: Structure and Stability of Benzene
  24. 3.06: Aromaticity and the Huckel 4n 2 Rule
  25. 3.07: Aromatic Ions
  26. 3.08: Aromatic Heterocycles- Pyridine and Pyrrole
  27. 3.09: Polycyclic Aromatic Compounds
  28. 3.10: Spectroscopy of Aromatic Compounds
  29. 3.S: Benzene and Aromaticity (Summary)
  30. 04: Electrophilic Aromatic Substitution Reactions
  31. 4.01: Chemistry of Benzene - Electrophilic Aromatic Substitution
  32. 4.1.01: Introduction
  33. 4.1.02: Electrophilic Aromatic Substitution Reactions - Bromination
  34. 4.1.03: Other Aromatic Substitutions
  35. 4.1.04: Alkylation and Acylation of Aromatic Rings - The Friedel-Crafts Reaction
  36. 4.1.05: Substituent Effects in Substituted Aromatic Rings
  37. 4.1.06: An Explanation of Substituent Effects
  38. 4.1.07: Trisubstituted Benzenes - Additivity of Effects
  39. 4.1.08: Reduction of Aromatic Compounds
  40. 4.1.09: Synthesis of Polysubstituted Benzenes
  41. 4.1.S: Chemistry of Benzene - Electrophilic Aromatic Substitution (Summary)
  42. 05: Reactions at the Allylic and Benzylic Positions
  43. 5.01: Reactivity at the Phenylmethyl (Benzyl) Carbon- Benzylic Resonance Stabilization
  44. 5.02: Oxidation of Aromatic Compounds
  45. 5.03: Benzylic Oxidations and Reductions
  46. 06: Aryl Halides and Nucleophilic Aromatic Substitution Reactions
  47. 6.01: Nucleophilic Aromatic Substitution
  48. 6.02: Preparation of Phenols- Nucleophilic Aromatic Substitution
  49. 6.03: Arenediazonium Salts
  50. 6.04: Benzyne
  51. 07: Review of RedOx Reactions
  52. 7.01: Oxidation-Reduction Reactions of Organic Compounds- An Overview
  53. 7.02: Reduction Reactions
  54. 7.03: Chemoselective Reactions
  55. 7.04: Oxidation of Alcohols
  56. 7.05: Oxidation of Aldehydes and Ketones
  57. 7.06: Oxidation of Alkenes to 12 Diols
  58. 08: Reactions of Carboxylic Acid Derivatives
  59. 8.01: Structure and Properties of Carboxylic Acids
  60. 8.02: Substituent Effects on Acidity
  61. 8.03: Preparing Carboxylic Acids
  62. 8.04: Nucleophilic Acyl Substitution Reactions
  63. 8.05: Nucleophilic Acyl Substitution Reactions of Carboxylic Acids
  64. 8.06: Chemistry of Acid Halides
  65. 8.07: Chemistry of Acid Anhydrides
  66. 8.08: Chemistry of Esters
  67. 8.09: Chemistry of Amides
  68. 8.10: Spectroscopy of Carboxylic Acid Derivatives
  69. 09: Ch. 9- Reactions of Ketones and Aldehydes
  70. 9.01: Naming the Aldehydes and Ketones
  71. 9.02: Structure of the Carbonyl Group
  72. 9.03: Spectroscopic Properties of Aldehydes and Ketones
  73. 9.04: Reactivity of the Carbonyl Group- Mechanisms of Addition
  74. 9.05: Addition of Water to Form Hydrates
  75. 9.06: Addition of Alcohols to Form Hemiacetals and Acetals
  76. 9.07: Acetals as Protecting Groups
  77. 9.08: Nucleophilic Addition of Ammonia and Its Derivatives
  78. 9.09: Deoxygenation of the Carbonyl Group
  79. 9.10: Addition of Hydrogen Cyanide to Give Cyanohydrins
  80. 9.11: Addition of Phosphorus Ylides- The Wittig Reaction
  81. 9.12: Nucleophilic Addition of Hydride and Grignard Reagents- Alcohol Formation
  82. 9.13: Nucleophilic Addition of Amines- Imine and Enamine Formation
  83. 9.14: Nucleophilic Addition of Hydrazine - The Wolff-Kishner Reaction
  84. 10: Reactions at the Alpha-Carbon (Alpha Substitutions)
  85. 10.01: Keto-Enol Tautomerism
  86. 10.02: Reactivity of Enols- The Mechanism of Alpha-Substitution Reactions
  87. 10.03: Alpha Halogenation of Aldehydes and Ketones
  88. 10.04: Alpha Bromination of Carboxylic Acids
  89. 10.05: Acidity of Alpha Hydrogen Atoms- Enolate Ion Formation
  90. 10.06: Reactivity of Enolate Ions
  91. 10.07: Alkylation of Enolate Ions
  92. 10.08: Carbonyl Condensations - The Aldol Reaction
  93. 10.09: Dehydration of Aldol Products - Synthesis of Enones
  94. 10.10: The Claisen Condensation Reaction
  95. 10.11: Mixed Claisen Condensations
  96. 10.12: Conjugate Carbonyl Additions - The Michael Reaction
  97. 10.13: The Robinson Annulation Reaction
  98. 11: Chemistry of Amines
  99. 11.01: Naming Amines
  100. 11.02: Structure and Properties of Amines
  101. 11.03: Basicity of Amines
  102. 11.04: Basicity of Arylamines
  103. 11.05: Synthesis of Amines
  104. 11.06: Reactions of Amines
  105. 11.07: Heterocyclic Amines
  106. 11.08: Quaternary Ammonium Salts- Hofmann Elimination
  107. 12: Carbohydrates and Sugars
  108. 12.01: Classification of Carbohydrates
  109. 12.02: Fischer Projections
  110. 12.03: D L Sugars
  111. 12.04: Configurations of Aldoses
  112. 12.05: Anomers
  113. 13: Nucleic Acids
  114. 13.01: Biosynthesis of Proteins- Nucleic Acids
  115. 13.02: Nucleotides and Nucleic Acids
  116. 13.03: Base Pairing in DNA - The Watson-Crick Model
  117. 14: Amino Acids
  118. 14.01: Structure and Properties of Amino Acids
  119. 14.02: Synthesis of Amino Acids- A Combination of Amine and Carboxylic Acid Chemistry
  120. 14.03: Determination of Primary Structure- Amino Acid Sequencing
  121. 14.04: Amino Acids the Henderson-Hasselbalch Equation and Isoelectric Points
  122. 15: Coupling Reactions
  123. 15.01: Organometallic Coupling Reactions
  124. 15.02: 12- and 14-Additions of Organometallic Reagents
  125. 16: Pericyclic Reactions
  126. 16.01: Molecular Orbitals and Orbital Symmetry
  127. 16.02: Cycloaddition Reactions
  128. 16.03: The Diels-Alder Cycloaddition Reaction
  129. 16.04: Characteristics of the Diels-Alder Reaction
  130. 16.05: An Electrocyclic Reaction of the Benzene Ring- The Claisen Rearrangement
  131. 16.06: Sigmatropic Rearrangements