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Chem 260: Inorganic Chemistry

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Chem 260: Inorganic Chemistry

Inorganic chemistry deals with the synthesis and behavior of inorganic and organometallic compounds and covers all chemical compounds except the myriad organic compounds (carbon-based compounds), which are the subjects of organic chemistry. Inorganic chemistry has applications in every aspect of the chemical industry, including catalysis, materials science, pigments, surfactants, coatings, medications, fuels, and agriculture.

Chemistry
Author
Steven N. Girard
Publisher
University of Wisconsin - Whitewater
Source
LibreTexts
License
CC BY-SA
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 115 sections
  1. 01: Review of Chemical Bonding
  2. 1.01: Prelude to Chemical Bonding
  3. 1.02: Waves and Electromagnetic Radiation
  4. 1.03: Quantization of Energy
  5. 1.04: Atomic Orbitals and Their Energies
  6. 1.05: Slater's Rules
  7. 1.06: References
  8. 02: Molecular Orbital Theory
  9. 2.01: Valence Bond Theory- Lewis Dot Structures the Octet Rule Formal Charge Resonance and the Isoelectronic Principle
  10. 2.02: The Shapes of Molecules (VSEPR Theory) and Orbital Hybridization
  11. 2.03: Prelude to Molecular Orbital Theory
  12. 2.04: Molecular Orbital Theory
  13. 2.05: Constructing Molecular Orbitals from Atomic Orbitals
  14. 2.06: Orbital Symmetry
  15. 2.07: and orbitals
  16. 2.08: Diatomic Molecules
  17. 2.09: Orbital Filling
  18. 2.10: Second-Row Diatomic Molecules
  19. 2.11: Periodic Trends in Bonding
  20. 2.12: References
  21. 03: Coordination Chemistry
  22. 3.01: History of Coordination Compounds
  23. 3.02: Metal Complexes
  24. 3.03: Ligands with more than one Donor Atom
  25. 3.04: Nomenclature of Coordination Chemistry
  26. 3.05: Isomerization
  27. 3.06: Enantiomers in Octahedral Complexes with Bidentate Ligands
  28. 3.07: Structural Isomers- Coordination Isomerism in Transition Metal Complexes
  29. 3.08: Structural Isomers- Ionization Isomerism in Transition Metal Complexes
  30. 3.09: Structural Isomers- Linkage Isomerism in Transition Metal Complexes
  31. 3.10: Color and Magnetism
  32. 04: Coordination Chemistry and Crystal Field Theory
  33. 4.01: Prelude to Coordination Chemistry and Crystal Field Theory
  34. 4.02: Chelate and Macrocyclic Effects
  35. 4.03: Ligand Substitution Reactions
  36. 4.04: Counting Electrons in Transition Metal Complexes
  37. 4.05: Crystal Field Theory
  38. 4.06: Spectrochemical Series
  39. 4.07: -Bonding between Metals and Ligands
  40. 4.08: Crystal Field Stabilization Energy Pairing and Hund's Rule
  41. 4.09: Magnetic Susceptibility and the Spin-only Formula
  42. 4.10: Jahn-Teller Distortions
  43. 4.11: Non-octahedral Complexes
  44. 4.12: Tetrahedral Complexes
  45. 4.13: Stability of Transition Metal Complexes
  46. 4.14: Ligand Field Theory
  47. 4.15: The 18-electron Rule
  48. 4.16: References
  49. 05: Thermodynamics of Lattices
  50. 5.01: Lattice Energy
  51. 5.02: Lattice Energy- The Born-Haber cycle
  52. 5.03: Lattice Enthalpies and Born Haber Cycles
  53. 5.04: The Born-Lande' equation
  54. 06: Acid-Base Chemistry
  55. 6.01: Prelude to Acid-Base Chemistry
  56. 6.02: Brnsted and Lewis Acids and Bases
  57. 6.03: Molecular Structure and Acid-Base Behavior
  58. 6.04: Oxides
  59. 6.05: Lewis Acids and Bases
  60. 6.06: Hard and Soft Acids and Bases
  61. 6.07: References
  62. 07: Molecular Symmetry
  63. 7.01: Introduction
  64. 7.02: Symmetry Operations and Elements
  65. 7.03: Symmetry Elements
  66. 7.04: Successive Operations
  67. 7.05: Point Groups
  68. 7.06: Character Tables - An Introduction
  69. 08: Solids
  70. 8.01: The Solid State of Matter
  71. 8.02: Lattice Structures in Crystalline Solids
  72. 8.03: Simple Cubic
  73. 8.04: Body Centered Packing
  74. 8.05: Metal Structures
  75. 8.06: Solids
  76. 8.07: Sphere Packing
  77. 8.08: Tetrahedral and Octahedral Sites
  78. 09: Electronic Properties of Materials - Superconductors and Semiconductors
  79. 9.01: Prelude to Electronic Properties of Materials - Superconductors and Semiconductors
  80. 9.02: Bonding in Metals
  81. 9.03: Band Theory of Solids
  82. 9.04: Semiconductors and Doping
  83. 9.05: Resistivity
  84. 9.06: Metal-Insulator Transitions
  85. 9.07: Superconductors
  86. 9.08: Periodic Trends- Metals Semiconductors and Insulators
  87. 9.09: Semiconductors- Band Gaps Colors Conductivity and Doping
  88. 9.10: Semiconductor p-n Junctions
  89. 9.11: Diodes LEDs and Solar Cells
  90. 9.12: Amorphous Semiconductors
  91. 9.13: References
  92. 10: Metals and Alloys- Structure Bonding Electronic and Magnetic Properties
  93. 10.01: Prelude to Metals and Alloys
  94. 10.02: Unit Cells and Crystal Structures
  95. 10.03: Bravais Lattices
  96. 10.04: Crystal Structures of Metals
  97. 10.05: Bonding in Metals
  98. 10.06: Conduction in Metals
  99. 10.07: Atomic Orbitals and Magnetism
  100. 10.08: Ferro- Ferri- and Antiferromagnetism
  101. 10.09: Hard and Soft Magnets
  102. 10.10: Discussion Questions
  103. 10.11: Problems
  104. 10.12: References
  105. 11: Basic Science of Nanomaterials
  106. 11.01: Prelude to Basic Science of Nanomaterials
  107. 11.02: Physics and Length Scales- Cavity Laser Coulomb Blockade Nanoscale Magnets
  108. 11.03: Semiconductor Quantum Dots
  109. 11.04: Synthesis of Semiconductor Nanocrystals
  110. 11.05: Surface Energy
  111. 11.06: Nanoscale Metal Particles
  112. 11.07: Applications of Nanomaterials
  113. 11.08: Discussion Questions
  114. 11.09: Problems
  115. 11.10: References