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Chem 322 Lecture Content

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Chem 322 Lecture Content

Chemistry
Author
Prof. Jacqueline Bennett
Publisher
SUNY oneonta
Source
LibreTexts
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 112 sections
  1. 01: Phosphate Transfer Reactions
  2. 1.01: Prelude to Phosphate Transfer Reactions
  3. 1.02: Overview of Phosphate Groups
  4. 1.03: Phosphate Transfer Reactions - An Overview
  5. 1.04: ATP The Principal Phosphate Group Donor
  6. 1.05: Phosphorylation of Alcohols
  7. 1.06: Phosphorylation of Carboxylates
  8. 1.07: Hydrolysis of Organic Phosphates
  9. 1.08: Phosphate Diesters in DNA and RNA
  10. 1.09: The Organic Chemistry of Genetic Engineering
  11. 1.10: NMR of phosphorylated compounds
  12. 1.P: Phosphate Transfer Reactions (Problems)
  13. 1.S: Phosphate Transfer Reactions (Summary)
  14. 02: Nucleophilic Carbonyl Addition Reactions
  15. 2.01: Prelude to Nucleophilic Carbonyl Addition Reactions
  16. 2.02: Nucleophilic Additions to Aldehydes and Ketones - An Overview
  17. 2.03: Hemiacetals Hemiketals and Hydrates
  18. 2.04: Acetals and Ketals
  19. 2.05: N-glycosidic Bonds
  20. 2.06: Imines
  21. 2.07: A Look Ahead - Addition of Carbon and Hydride Nucleophiles to Carbonyls
  22. 2.P: Nucleophilic Carbonyl Addition Reactions (Problems)
  23. 2.S: Nucleophilic Carbonyl Addition Reactions (Summary)
  24. 03: Oxidation and Reduction Reactions
  25. 3.01: Prelude to Oxidation and Reduction Reactions
  26. 3.02: Oxidation and Reduction of Organic Compounds - An Overview
  27. 3.03: Oxidation and Reduction in the Context of Metabolism
  28. 3.04: Hydrogenation of Carbonyl and Imine Groups
  29. 3.05: Hydrogenation of alkenes and Dehydrogenation of Alkanes
  30. 3.06: Monitoring Hydrogenation and Dehydrogenation Reactions by UV Spectroscopy
  31. 3.07: Redox Reactions of Thiols and Disulfides
  32. 3.08: Flavin-Dependent Monooxygenase Reactions - Hydroxylation Epoxidation and the Baeyer-Villiger Oxidation
  33. 3.09: Hydrogen Peroxide is a Harmful - Reactive Oxygen Species
  34. 3.P: Oxidation and Reduction Reactions (Problems)
  35. 3.S: Oxidation and Reduction Reactions (Summary)
  36. 04: Arenes Electrophilic Aromatic Substitution
  37. 4.01: Nomenclature of Arenes
  38. 4.02: Physical Properties of Arenes
  39. 4.03: Spectral Properties of Arenes
  40. 4.04: Molecular orbital theory- conjugation and aromaticity
  41. 4.05: Electrophilic Aromatic Substitution
  42. 4.06: Effect of Substituents on Reactivity and Orientation in Electrophilic Aromatic Substitution
  43. 4.07: Orientation in Disubstituted Benzenes
  44. 4.08: Addition Reactions of Arenes
  45. 4.09: Oxidation Reactions
  46. 4.10: Sources and Uses of Aromatic Hydrocarbons
  47. 4.11: Some Conjugated Cyclic Polyenes
  48. 4.12: Fluxional Compounds
  49. 4.E: Arenes Electrophilic Aromatic Substitution (Exercises)
  50. 05: Organohalogen and Organometallic Compounds
  51. 5.01: Prelude to Organohalogen and Organometallic Compounds
  52. 5.02: Physical Properties of Organohalogen and Organometallic Compounds
  53. 5.03: Spectroscopic Properties
  54. 5.04: Alkyl Halides
  55. 5.05: Alkenyl and Alkynyl Halides
  56. 5.06: Cycloalkyl Halides
  57. 5.07: Aryl Halides
  58. 5.08: Polyhalogenated Alkanes and Alkenes
  59. 5.09: Organometallic Compounds from Organohalogen Compounds
  60. 5.10: Properties of Organometallic Compounds
  61. 5.11: Preparation of Organometallic Compounds
  62. 5.12: Organomagnesium Compounds
  63. 5.13: Organomagnesium and Organolithium Compounds in Synthesis
  64. 5.P: Organohalogen and Organometallic Compounds (Problems)
  65. 06: Nucleophilic Acyl Substitution Reactions
  66. 6.01: Prelude to Nucleophilic Acyl Substitution Reactions
  67. 6.02: Carboxylic Acid Derivatives
  68. 6.03: The Nucleophilic Acyl Substitution Mechanism
  69. 6.04: Acyl Phosphates
  70. 6.05: The Relative Reactivity of Carboxylic Acid Derivatives
  71. 6.06: Acyl Phosphates
  72. 6.07: Hydrolysis of Thioesters Esters and Amides
  73. 6.08: Protein Synthesis on the Ribosome
  74. 6.09: Nucleophilic Substitution at Activated Amides and Carbamides
  75. 6.10: Nucleophilic Acyl Substitution Reactions in the Laboratory
  76. 6.11: A Look Ahead - Acyl Substitution Reactions with a Carbanion or Hydride Ion Nucleophile
  77. 6.P: Nucleophilic Acyl Substitution Reactions (Problems)
  78. 6.S: Nucleophilic Acyl Substitution Reactions (Summary)
  79. 07: Reactions at the -Carbon Part I
  80. 7.01: Prelude to Reactions at the -carbon part I
  81. 7.02: Review of Acidity at the -Carbon
  82. 7.03: Isomerization at the -Carbon
  83. 7.04: Aldol Addition
  84. 7.05: -Carbon Reactions in the Synthesis Lab - Kinetic vs. Thermodynamic Alkylation Products
  85. 7.E: Reactions at the -Carbon Part I (Exercises)
  86. 7.S: Reactions at the -Carbon Part I (Summary)
  87. 08: Reactions at the -Carbon Part II
  88. 8.01: Prelude to Reactions at the -Carbon Part II
  89. 8.02: Decarboxylation
  90. 8.03: An Overview of Fatty Acid Metabolism
  91. 8.04: Claisen Condensation
  92. 8.05: Conjugate Addition and Elimination
  93. 8.06: Carboxylation
  94. 8.E: Reactions at the -Carbon Part II (Exercises)
  95. 8.S: Reactions at the -Carbon Part II (Summary)
  96. 09: Radical Reactions
  97. 9.01: Prelude to Radical Reactions
  98. 9.02: Overview of Single-Electron Reactions and Free Radicals
  99. 9.03: Radical Chain Reactions
  100. 9.04: Useful Polymers formed by Radical Chain Reactions
  101. 9.05: Destruction of the Ozone Layer by a Radical Chain Reaction
  102. 9.06: Oxidative Damage to cells Vitamin C and Scurvy
  103. 9.07: Flavin as a One-Electron Carrier
  104. 9.P: Radical Reactions (Problems)
  105. 10: The Organic Chemistry of Vitamins
  106. 10.01: Prelude to the Organic Chemistry of Vitamins
  107. 10.02: Pyridoxal Phosphate (Vitamin B6)
  108. 10.03: Thiamine Diphosphate (Vitamin B1)
  109. 10.04: Thiamine Diphosphate Lipoamide and the Pyruvate Dehydrogenase Reaction
  110. 10.05: Folate
  111. 10.E: The Oganic Chemistry of Vitamins (Exercises)
  112. 10.S: The Oganic Chemistry of Vitamins (Summary)