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Introduction to Organometallic Chemistry

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Introduction to Organometallic Chemistry

Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkaline, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and tin.

Inorganic ChemistryChemistry
Author
M. S. Balakrishna & Prasenjit Ghosh
Publisher
Indian Institute of Technology Bombay
Source
LibreTexts
License
CC BY-NC-SA
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 50 sections
  1. 01: Introduction
  2. 1.01: Bonding Concepts in Main Group Chemistry
  3. 1.02: VSEPR Theory and its Utility
  4. 02: Organometallic Chemistry of s- and p-block Elements
  5. 2.01: General Methods of Preparation
  6. 2.02: Organometallic Compounds of Alkali Metals (Sodium and Lithium)
  7. 2.03: Organometallic Compounds of Alkaline Earth Metals (Beryllium and Magnesium)
  8. 2.04: Structure and Bonding
  9. 03: Organometallic Chemistry of p-block Elements
  10. 3.01: Reactions of Organometallic Compounds
  11. 3.02: Organometallic Compounds of Boron and Aluminium
  12. 3.03: Organometallic Compounds of Gallium and Indium
  13. 3.04: Zeigler Natta Polymerization Catalysts
  14. 3.05: Organosilicon and Organogermanium Compounds
  15. 3.06: Organotin and Organolead Compounds
  16. 04: Organoelement Compounds of Group 15
  17. 4.01: Organometallic Compounds of As(V) and Sb(V)
  18. 4.02: Organometallic Compounds of As(III) and Sb(III)
  19. 4.03: Phosphines
  20. 05: Group 12 Elements
  21. 5.01: Organometallic Compounds of Zinc and Cadmium
  22. 5.02: Organometallic Compounds of Mercury
  23. 06: General Properties of Transition Metal Organometallic Complexes
  24. 6.01: 18 Valence Electron Rule
  25. 6.02: Synthesis and Stability
  26. 07: Metal Alkyls and Metal Hydrides
  27. 7.01: Transition Metal Alkyl Complexes
  28. 7.02: Metal Hydrides
  29. 08: Carbonyls and Phosphine Complexes
  30. 8.01: Metal Carbonyls
  31. 8.02: Metal Phosphines
  32. 09: Complexes of bound Ligands
  33. 9.01: Metal Alkene Complexes
  34. 9.02: Metal Allyl and Diene Complexes
  35. 9.03: Metal Cyclopentadienyl Complexes
  36. 10: Reaction Mechanisms
  37. 10.01: Oxidative Addition and Reductive Elimination
  38. 10.02: Insertion and Elimination Reactions
  39. 10.03: Nucleophilic and Electrophilic Addition and Abstraction
  40. 11: Applications
  41. 11.01: Homogeneous Catalysis - I
  42. 11.02: Homogeneous Catalysis - II
  43. 12: Physical Methods in Organometallic Chemistry
  44. 12.01: Characterization of Organometallic Complexes
  45. 13: Multiply-Bonded Ligands
  46. 13.01: Metal-Carbenes
  47. 13.02: Metal-Carbynes
  48. 14: Metathesis
  49. 14.01: Catalytic Applications of Organometallic Compounds- Alkene Metathesis
  50. 14.02: Credits