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Thermodynamics and Chemistry

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Thermodynamics and Chemistry

Thermodynamics and Chemistry is designed primarily as a textbook for a one-semester course in classical chemical thermodynamics at the graduate or undergraduate level.

Physical and Theoretical Chemistry Textbook MapsChemistry
Author
Howard DeVoe
Publisher
University of Maryland
Source
LibreTexts
License
CC BY
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 131 sections
  1. 01: Introduction
  2. 1.01: Units
  3. 1.02: Quantity Calculus
  4. 1.03: Dimensional Analysis
  5. 1.04: Chapter 1 Problem
  6. 02: Systems and Their Properties
  7. 2.01: The System Surroundings and Boundary
  8. 2.02: Phases and Physical States of Matter
  9. 2.03: Some Basic Properties and Their Measurement
  10. 2.04: The State of the System
  11. 2.05: Processes and Paths
  12. 2.06: The Energy of the System
  13. 2.07: Chapter 2 Problems
  14. 03: The First Law
  15. 3.01: Heat Work and the First Law
  16. 3.02: Spontaneous Reversible and Irreversible Processes
  17. 3.03: Heat Transfer
  18. 3.04: Deformation Work
  19. 3.05: Applications of Expansion Work
  20. 3.06: Work in a Gravitational Field
  21. 3.07: Shaft Work
  22. 3.08: Electrical Work
  23. 3.09: Irreversible Work and Internal Friction
  24. 3.10: Reversible and Irreversible Processes- Generalities
  25. 3.11: Chapter 3 Problems
  26. 04: The Second Law
  27. 4.01: Types of Processes
  28. 4.02: Statements of the Second Law
  29. 4.03: Concepts Developed with Carnot Engines
  30. 4.04: Derivation of the Mathematical Statement of the Second Law
  31. 4.05: Irreversible Processes
  32. 4.06: Applications
  33. 4.07: Summary
  34. 4.08: The Statistical Interpretation of Entropy
  35. 4.09: Chapter 4 Problems
  36. 05: Thermodynamic Potentials
  37. 5.01: Total Differential of a Dependent Variable
  38. 5.02: Total Differential of the Internal Energy
  39. 5.03: Enthalpy Helmholtz Energy and Gibbs Energy
  40. 5.04: Closed Systems
  41. 5.05: Open Systems
  42. 5.06: Expressions for Heat Capacity
  43. 5.07: Surface Work
  44. 5.08: Criteria for Spontaneity
  45. 5.09: Chapter 5 Problems
  46. 06: The Third Law and Cryogenics
  47. 6.01: The Zero of Entropy
  48. 6.02: Molar Entropies
  49. 6.03: Cryogenics
  50. 6.04: Chapter 6 Problem
  51. 07: Pure Substances in Single Phases
  52. 7.01: Volume Properties
  53. 7.02: Internal Pressure
  54. 7.03: Thermal Properties
  55. 7.04: Heating at Constant Volume or Pressure
  56. 7.05: Partial Derivatives with Respect to (T) (p) and (V)
  57. 7.06: Isothermal Pressure Changes
  58. 7.07: Standard States of Pure Substances
  59. 7.08: Chemical Potential and Fugacity
  60. 7.09: Standard Molar Quantities of a Gas
  61. 7.10: Chapter 7 Problems
  62. 08: Phase Transitions and Equilibria of Pure Substances
  63. 8.01: Phase Equilibria
  64. 8.02: Phase Diagrams of Pure Substances
  65. 8.03: Phase Transitions
  66. 8.04: Coexistence Curves
  67. 8.05: Chapter 8 Problems
  68. 09: Mixtures
  69. 9.01: Composition Variables
  70. 9.02: Partial Molar Quantities
  71. 9.03: Gas Mixtures
  72. 9.04: Liquid and Solid Mixtures of Nonelectrolytes
  73. 9.05: Activity Coefficients in Mixtures of Nonelectrolytes
  74. 9.06: Evaluation of Activity Coefficients
  75. 9.07: Activity of an Uncharged Species
  76. 9.08: Mixtures in Gravitational and Centrifugal Fields
  77. 9.09: Chapter 9 Problems
  78. 10: Electrolyte Solutions
  79. 10.01: Single-ion Quantities
  80. 10.02: Solution of a Symmetrical Electrolyte
  81. 10.03: Electrolytes in General
  82. 10.04: The Debye-Huckel Theory
  83. 10.05: Derivation of the Debye-Huckel Theory
  84. 10.06: Mean Ionic Activity Coefficients from Osmotic Coefficients
  85. 10.07: Chapter 10 Problems
  86. 11: Reactions and Other Chemical Processes
  87. 11.01: Mixing Processes
  88. 11.02: The Advancement and Molar Reaction Quantities
  89. 11.03: Molar Reaction Enthalpy
  90. 11.04: Enthalpies of Solution and Dilution
  91. 11.05: Reaction Calorimetry
  92. 11.06: Adiabatic Flame Temperature
  93. 11.07: Gibbs Energy and Reaction Equilibrium
  94. 11.08: The Thermodynamic Equilibrium Constant
  95. 11.09: Effects of Temperature and Pressure on Equilibrium Position
  96. 11.10: Chapter 11 Problems
  97. 12: Equilibrium Conditions in Multicomponent Systems
  98. 12.01: Effects of Temperature
  99. 12.02: Solvent Chemical Potentials from Phase Equilibria
  100. 12.03: Binary Mixture in Equilibrium with a Pure Phase
  101. 12.04: Colligative Properties of a Dilute Solution
  102. 12.05: Solid-Liquid Equilibria
  103. 12.06: Liquid-Liquid Equilibria
  104. 12.07: Membrane Equilibria
  105. 12.08: Liquid-Gas Equilibria
  106. 12.09: Reaction Equilibria
  107. 12.10: Evaluation of Standard Molar Quantities
  108. 12.11: Chapter 12 Problems
  109. 13: The Phase Rule and Phase Diagrams
  110. 13.01: The Gibbs Phase Rule for Multicomponent Systems
  111. 13.02: Phase Diagrams- Binary Systems
  112. 13.03: Phase Diagrams- Ternary Systems
  113. 13.04: Chapter 13 Problems
  114. 14: Galvanic Cells
  115. 14.01: Cell Diagrams and Cell Reactions
  116. 14.02: Electric Potentials in the Cell
  117. 14.03: Molar Reaction Quantities of the Cell Reaction
  118. 14.04: The Nernst Equation
  119. 14.05: Evaluation of the Standard Cell Potential
  120. 14.06: Standard Electrode Potentials
  121. 14.07: Chapter 14 Problems
  122. 15: Appendices
  123. 15.01: Appendix A- Definitions of the SI Base Units
  124. 15.02: Appendix B- Physical Constants
  125. 15.03: Appendix C- Symbols for Physical Quantities
  126. 15.04: Appendix D- Miscellaneous Abbreviations and Symbols
  127. 15.05: Appendix E- Calculus Review
  128. 15.06: Appendix F- Mathematical Properties of State Functions
  129. 15.07: Appendix G- Forces Energy and Work
  130. 15.08: Appendix H- Standard Molar Thermodynamic Properties
  131. 15.09: Appendix I- Answers to Selected Problems