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Chem 124A: Fundamentals of Inorganic Chemistry

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Chem 124A: Fundamentals of Inorganic Chemistry

This texts address the fundamentals of inorganic chemistry with emphases on symmetry, molecular geometry and structure, molecular orbital theory of bonding (polyatomic molecules and transition metals), solid state chemistry, energetics and spectroscopy of inorganic compounds.

Chemistry
Publisher
University of California, Davis
Source
LibreTexts
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 203 sections
  1. 01: Introduction to Inorganic Chemistry
  2. 1.01: What is inorganic chemistry
  3. 1.02: Inorganic vs Organic Chemistry
  4. 1.03: History of Inorganic Chemistry
  5. 1.04: Perspectives
  6. 1.05: Practice problems
  7. 02: Atomic Structure
  8. 2.01: Historical Development of Atomic Theory
  9. 2.1.01: The Periodic Table
  10. 2.1.02: Discovery of Subatomic Particles and the Bohr Atom
  11. 2.02: The Schrodinger equation particle in a box and atomic wavefunctions
  12. 2.2.01: Particle in a Box
  13. 2.2.02: Quantum Numbers and Atomic Wave Functions
  14. 2.2.03: Aufbau Principle
  15. 2.2.04: Shielding
  16. 2.03: Periodic Properties of Atoms
  17. 2.3.01: Ionization energy
  18. 2.3.02: Electron Affinity
  19. 2.3.03: Covalent and Ionic Radii
  20. 2.04: Problems (do we want this here)
  21. 03: Simple Bonding Theory
  22. 3.01: Lewis Electron-Dot Diagrams
  23. 3.1.01: Resonance
  24. 3.1.02: Breaking the octet rule with higher electron counts (hypervalent atoms)
  25. 3.1.03: Formal Charge
  26. 3.1.04: Lewis fails to predict unusual cases- Boron and Beryllium
  27. 3.02: Valence Shell Electron-Pair Repulsion
  28. 3.2.01: Lone Pair Repulsion
  29. 3.2.02: Multiple Bonds
  30. 3.2.03: Electronegativity and Atomic Size Effects
  31. 3.2.04: Ligand Close Packing
  32. 3.03: Molecular Polarity
  33. 3.04: Hydrogen Bonding
  34. 04: Symmetry and Group Theory
  35. 4.01: Symmetry Elements and Operations
  36. 4.1.01: 1-Symmetry Elements
  37. 4.02: Molecular Point Groups
  38. 4.2.01: Point Groups
  39. 4.2.1.01: Groups of Low and High Symmetry
  40. 4.2.1.02: Other Groups
  41. 4.03: Properties and Representations of Groups
  42. 4.3.01: Matrices
  43. 4.3.02: Matrix
  44. 4.3.03: Representations of Point Groups
  45. 4.3.04: Representations
  46. 4.3.05: Character Tables
  47. 4.04: Character Tables
  48. 4.05: Examples and Applications of Symmetry
  49. 4.5.01: Chirality
  50. 4.5.02: Molecular Vibrations
  51. 4.5.03: Normal Modes of Vibration
  52. 4.5.04: Selection Rules for IR and Raman Spectroscopy
  53. 4.5.05: Stretching Frequencies and Structure Determination
  54. 4.06: Problems (do we want this here)
  55. 05: Molecular Orbitals
  56. 5.01: Formation of Molecular Orbitals from Atomic Orbitals
  57. 5.1.01: Molecular Orbitals from s Orbitals
  58. 5.1.02: Molecular Orbitals from p Orbitals
  59. 5.1.03: Molecular orbitals from d orbitals
  60. 5.1.04: Nonbonding Orbitals and Other Factors
  61. 5.02: Homonuclear Diatomic Molecules
  62. 5.2.01: Molecular Orbitals
  63. 5.2.02: Orbital Mixing
  64. 5.2.03: Diatomic Molecules of the First and Second Periods
  65. 5.2.04: Photoelectron Spectroscopy
  66. 5.03: Heteronuclear Diatomic Molecules
  67. 5.3.01: Polar bonds
  68. 5.3.02: Ionic Compounds and Molecular Orbitals
  69. 5.04: Diatomic Molecular Orbitals
  70. 5.4.01: Molecular Orbital Theory
  71. 5.P: Problems
  72. 06: Larger (Polyatomic) Molecules
  73. 6.01: Bifluoride anion
  74. 6.02: CO2
  75. 6.03: H2O
  76. 6.04: NH3
  77. 6.05: CO2 revisted with Projection Operators
  78. 6.06: BF3
  79. 6.07: SALCs and the projection operator technique
  80. 6.7.01: NH3 Molecular Orbitals
  81. 6.7.02: Td Molecular Orbitals
  82. 6.7.03: D4h Molecular Orbitals
  83. 6.7.04: Pi Donor and Acceptor Ligands
  84. 07: Solids
  85. 7.01: Crystal Lattices
  86. 7.1.01: Inorganic Solids
  87. 7.1.02: Lattice Basics
  88. 7.1.2.01: Covalent Network Solids
  89. 7.1.2.02: How to Decide What Type of Structure
  90. 7.1.2.03: Ionic Structures
  91. 7.1.2.04: Metallic Structures
  92. 7.1.2.05: Molecular Structures
  93. 7.1.03: Lattice Defects
  94. 7.1.3.01: Frenkel Defect
  95. 7.1.3.02: Metal Oxides
  96. 7.1.3.03: Schottky Defects
  97. 7.1.3.04: Solid Defects
  98. 7.1.04: Metal Lattices
  99. 7.1.4.01: Structure and Properties of Metals
  100. 7.1.4.02: Metal Packing- Layers
  101. 7.1.4.03: Metal Packing- Three Dimensions
  102. 7.1.4.04: Problems
  103. 7.1.4.05: Solutions to Selected Problems
  104. 7.1.05: Solids
  105. 7.1.5.01: Body Centered Packing
  106. 7.1.5.02: Metal Structures
  107. 7.1.5.03: Simple Cubic
  108. 7.1.5.04: Solids
  109. 7.1.5.05: Sphere Packing
  110. 7.1.5.06: Tetrahedral and Octahedral Sites
  111. 7.1.06: Thermodynamics of Lattices
  112. 7.1.6.01: Lattice Energy
  113. 7.1.6.02: Lattice Energy- The Born-Haber cycle
  114. 7.1.6.03: Lattice Enthalpies and Born Haber Cycles
  115. 7.1.6.04: The Born-Lande' equation
  116. 7.02: Solids
  117. 7.2.01: Crystalline and Amorphous Solids
  118. 7.2.02: Arrangement of Atoms in Crystals
  119. 7.2.03: Stucture of Simple Binary Compounds
  120. 7.2.04: Crystal Defects
  121. 7.2.05: Bonding and Properties of Solids
  122. 7.2.06: Metals and Semiconductors
  123. 7.2.07: Superconductors
  124. 7.2.08: Polymers
  125. 7.2.09: Modern Materials
  126. 7.2.10: End of Chapter Material
  127. 08: Coordination Chemistry
  128. 8.01: Introduction and History of Coordination Compounds
  129. 8.1.01: History of Coordination Compounds
  130. 8.02: Structure and Nomenclature of Coordination Compounds
  131. 8.2.01: Intro to Coordination Chemistry
  132. 8.2.02: Coordination Numbers and Geometry
  133. 8.2.2.01: Jahn-Teller Distortions
  134. 8.2.2.02: Molecular Examples
  135. 8.2.03: Introduction to Coordination Chemistry
  136. 8.2.04: Isomers
  137. 8.2.4.01: Optical Isomers in Inorganic Complexes
  138. 8.2.4.1.01: Enantiomers in Octahedral Complexes with Bidentate Ligands
  139. 8.2.4.1.02: Identifying Planes of Symmetry in Octahedral Complexes
  140. 8.2.4.1.03: Polarimetry
  141. 8.2.4.02: Stereoisomers- Geometric Isomers in cis-platin
  142. 8.2.4.03: Stereoisomers- Geometric Isomers in Transition Metal Complexes
  143. 8.2.4.04: Stereoisomers- Geometric Isomers in Transition Metal Complexes II
  144. 8.2.4.05: Stereoisomers of Complex Metal Complexes
  145. 8.2.4.06: Structural Isomers- Coordination Isomerism in Transition Metal Complexes
  146. 8.2.4.07: Structural Isomers- Ionization Isomerism in Transition Metal Complexes
  147. 8.2.4.08: Structural Isomers- Linkage Isomerism in Transition Metal Complexes
  148. 8.2.05: Ligands
  149. 8.2.5.01: EDTA
  150. 8.2.5.02: The Irving-Williams Series
  151. 8.2.06: What is a Complex Ion
  152. 8.2.07: Nomenclature of Coordination Complexes
  153. 8.03: Complex Ion Chemistry
  154. 8.3.01: Acidity of the Hexaaqua Ions
  155. 8.3.02: Geometry of Complex Ions
  156. 8.3.03: Ligand Exchange Reactions (Introduction)
  157. 8.3.04: Ligand Exchange Reactions (Thermodynamics)
  158. 8.3.05: Nomenclature of Complex Ions
  159. 8.3.06: Origin of Color in Complex Ions
  160. 8.3.07: Reactions of the Hexaaqua Ions with Ammonia
  161. 8.3.08: Reactions of the Hexaaqua Ions with Carbonate Ions
  162. 8.3.09: Reactions of the Hexaaqua Ions with Hydroxide Ions
  163. 8.3.10: Stereoisomerism in complex ions
  164. 8.04: Complex Ion Equilibria
  165. 8.4.01: Chelation
  166. 8.4.02: Complex-Ion Equilibria
  167. 8.4.03: Complex Equilibrium
  168. 8.4.04: Hard and Soft Acids and Bases
  169. 8.4.05: Stability of Metal Complexes and Chelation
  170. 09: Crystal Field Theory
  171. 9.01: Colors of Coordination Complexes
  172. 9.02: Crystal Field Stabilization Energy
  173. 9.03: Crystal Field Theory
  174. 9.04: High Spin and Low Spin Complexes
  175. 9.05: Introduction to Crystal Field Theory
  176. 9.06: Magnetic Moments of Transition Metals
  177. 9.07: Magnetism
  178. 9.08: Metals Tetrahedral and Octahedral
  179. 9.09: Non-octahedral Complexes
  180. 9.10: Octahedral vs. Tetrahedral Geometries
  181. 9.11: Orgel Diagrams
  182. 9.11.01: Qualitative Orgel Diagrams
  183. 9.12: Tanabe-Sugano Diagrams
  184. 9.13: Thermodynamics and Structural Consequences of d-Orbital Splitting
  185. 10: Ligand Field Theory
  186. 10.01: Ligand Field Theory Fundamentals
  187. 11: Spectroscopic Techniques
  188. 11.01: Fundamentals of Electron Absorption Spectroscopy
  189. 11.02: Basics of Spectroscopy
  190. 11.2.01: Breakdown of EM Radiation
  191. 11.03: Electronic Spectroscopy
  192. 11.04: Vibrational Spectroscopy
  193. 11.05: X-ray Spectroscopy
  194. 11.5.01: Extended X-ray Absorption Fine Structure (EXAFS)
  195. 11.5.02: X-ray Absorption Near Edge Structure (XANES)
  196. 11.5.03: X-ray Absorption Spectroscopy (XAS)
  197. 11.06: Magnetic Resonance Spectroscopies
  198. 11.6.01: NMR Animations
  199. 11.6.1.01: Basic Concepts
  200. 11.6.1.1.01: Magnetic Resonance Imaging
  201. 11.6.1.02: pi Pulses
  202. 11.6.1.03: Pulsed NMR Introduction
  203. 11.6.1.04: Spin Echo