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Map: Chemistry (Zumdahl and Decoste)
- Publisher
- LibreTexts
- Source
- LibreTexts
- License
- CC BY-NC-SA
- Language
- EN
- Category
- Basic Sciences
Contents· 242 sections
- 01: Chemical Foundations
- 1.1: Chemistry: An Overview
- 1.2: Chemistry Applications
- 1.3: The Scientific Method
- 1.4: Chemistry in Industry
- 1.5: Polymer Chemistry
- 02: Atoms Molecules and Ions
- 2.01 The Early History of Chemistry
- 2.02 Fundamental Chemical Laws
- 2.03 Dalton's Atomic Theory
- 2.04 Early Experiments to Characterize the Atom
- 2.04: Cannizzaro's Interpretation
- 2.05 The Modern View of Atomic Structure: An Introduction
- 2.06 Molecules and Ions
- 2.07 An Introduction to the Periodic Table
- 2.08 Naming Simple Compounds
- 03: Stoichiometry
- 3.01 Counting by Weighing
- 3.02 The Mole
- 3.03 Molar Mass
- 3.04: Problem Solving Exercises
- 3.05 Percent Composition of Compounds
- 3.06 Determining the Formula of a Compound
- 3.07 Chemical Equations
- 3.08 Balancing Chemical Equations
- 3.09 Stoichiometric Calculations: Amounts of Reactants and Products
- 3.10: Calculations Involving a Limiting Reactant
- 3.11: Complex Problem Solving Approaches
- 04: Types of Chemical Reactions and Solution Stoichiometry
- 4.01 Water the Universal Solvent
- 4.02 The Nature of Aqueous Solutions: Strong and Weak Electrolytes
- 4.03 The Composition of Solutions
- 4.04 Types of Chemical Reactions
- 4.05 Precipitation Reactions
- 4.06 Describing Reactions in Solution
- 4.07: Selective Precipitation
- 4.08 Stoichiometry of Precipitation Reactions
- 4.09 Acid-Base Reactions
- 4.10 Oxidation-Reduction Reactions
- 4.11: Balancing Redox Equations
- 4.12: Redox Titrations
- 05: Gases
- 5.01 Pressure
- 5.02 The Gas Laws of Boyle Charles and Avogadro
- 5.03 The Ideal Gas Law
- 5.04 Gas Stoichiometry
- 5.05 Dalton's Law of Partial Pressures
- 5.06 The Kinetic Molecular Theory of Gases
- 5.07 Effusion and Diffusion
- 5.08: Collisions with Container Walls
- 5.09: Breakdown of Ideal Gas Law: Intermolecular Collisions
- 5.10 Real Gases
- 5.11: Characteristics of Several Real Gases
- 5.12 Chemistry in the Atmosphere
- 6: Chemical Equilibrium
- 6.1: The Equilibrium State
- 6.2: Equilibrium Constants
- 6.3: Equilibrium Expressions Involving Pressures
- 6.4: Activity is an Effective Concetration
- 6.5: Heterogeneous Equilibria
- 6.6: Applications of the Equilibrium Constant
- 6.7: Solving Equilibrium Problems
- 6.8: Le Chatelier's Principle
- 6.9: Equilibria of Real Gases
- 06: Thermochemistry
- 9.1: The Nature of Energy
- 9.2: Enthalpy
- 9.3: Calorimetry
- 9.5: Hess's Law
- 9.6: Standard Enthalpies of Formation
- 9.7: Present Sources of Energy
- 9.8: New Energy Sources
- 7: Acids and Bases
- 7.01 The Nature of Acids and Bases
- 7.02 Acid Strength
- 7.03 The pH Scale
- 7.04 Calculating the pH of Strong Acid Solutions
- 7.05 Calculating the pH of Weak Acid Solutions
- 7.06 Bases
- 7.07 Polyprotic Acids
- 7.08 Acid-Base Properties of Salts
- 7.09: Acid Solutions that Water Contributes p
- 7.10: Strong Acid Solutions that Water Contributes pH
- 7.11: Approaches to Solve Acid-Base Problems
- 07: Atomic Structure and Periodicity
- 12.01 Electromagnetic Radiation
- 12.02 The Nature of Matter
- 12.03 The Atomic Spectrum of Hydrogen
- 12.04 The Bohr Model
- 12.05 The Quantum Mechanical Model of the Atom
- 12.06: Particle in a Box
- 12.07: The Wave Equation for the Hydrogen Atom
- 12.08: The Meaning of the Wavefunction
- 12.09: Orbital Shapes and Energies
- 12.10: Electron Spin and the Pauli Principle
- 12.11 Polyelectronic Atoms
- 12.12: The History of the Periodic Table
- 12.13: The Aufbau Principles and the Periodic Table
- 12.14: The Polyelectronic Model
- 12.15: Periodic Trends in Atomic Properties
- 12.16: The Properties of a Group: The Alkali Metals
- 08: Aqueous Solutions Equilibria
- 8.01: Solutions of Acids or Bases Containing a Common Ion
- 8.02: Buffered Solutions
- 8.03: Exact Treatment of Buffered Solutions
- 8.04: Buffer Capacity
- 8.05: Titrations and pH Curves
- 8.06: Acid-Base Indicators
- 8.07: Titrations of Polyatomic Acids
- 8.08: Solubility Equilibria and the Solubility Product
- 8.09: Precipitation and Qualitative Analysis Complex Ion Equilibria
- 8.10: Complex Ion Equilibria
- 08: Bonding General Concepts
- 13.01: Types of Chemical Bonds
- 13.02 Electronegativity
- 13.03 Bond Polarity and Dipole Moments
- 13.04 Ions: Electron Configurations and Sizes
- 13.05 Formation of Binary Ionic Compounds
- 13.06 Partial Ionic Character of Covalent Bonds
- 13.07 The Covalent Chemical Bond: A Model
- 13.08 Covalent Bond Energies and Chemical Reactions
- 13.09 The Localized Electron Bonding Model
- 13.10: Lewis Structures
- 13.11: Resonance
- 13.12: Exceptions to the Octet Rule
- 13.13: Molecular Structure: The VSEPR Model
- 8: Equilibria in Aqueous Solutions
- 16.1 Spontaneous Processes and Entropy
- 16.2 Entropy and the Second Law of Thermodynamics
- 16.3 The Effect of Temperature on Spontaneity
- 16.4 Free Energy
- 16.5 Entropy Changes in Chemical Reactions
- 16.6 Free Energy and Chemical Reactions
- 16.7 The Dependence of Free Energy on Pressure
- 16.8 Free Energy and Equilibrium
- 16.9 Free Energy and Work
- 09: Covalent Bonding Orbitals
- 14.01: Hybridization and the Localized Electron Model
- 14.02: The Molecular Orbital Model
- 14.03: Bonding in Homonuclear Diatomic Molecules
- 14.04: Bonding in Heteronuclear Diatomic Molecules
- 14.05: Combining the Localized Electron and Molecular Orbital Models
- 14.06: Orbitals are Human Inventions
- 14.07: Introduction to Molecular Spectroscopy
- 14.08: Electronic Spectroscopy
- 14.09: Vibrational Spectroscopy
- 14.10: Rotational Spectroscopy
- 14.11: Nuclear Magnetic Resonance Spectroscopy
- 10: Entropy Gibbs Energy and Spontaneity
- 10.01: Spontaneous Processes
- 10.02: Isothermal Expansions and Compressions of Ideal Gases
- 10.03: Definition of Entropy
- 10.04: Entropy and Physical Changes
- 10.05: Entropy and the Second Law of Thermodynamics
- 10.06: The Effect of Temperature on Spontaneity
- 10.07: Gibbs (Free) Energy
- 10.08: Entropy Changes in Chemical Reactions
- 10.09: Gibbs Energy and Reactions
- 10.10: The Dependence of Free Energy on Pressure
- 10.11: Gibbs Energy and Equilibrium
- 10.12: Free Energy and Work
- 11: Electrochemistry
- 11.1: Galvanic Cells
- 11.2: Standard Reduction Potential
- 11.3: Cell Potential Electrical Work and Gibbs Energy
- 11.4: Dependence of Cell Potential on Concentration
- 11.5: Batteries
- 11.6: Corrosion
- 11.7: Electrolysis
- 11.8: Commercial Electrolytic Processes
- 15: Chemical Kinetics
- 15.1: Reaction Rates
- 15.2 Rate Laws: An Introduction
- 15.3: Determining the Form of the Rate Law
- 15.4: The Integrated Rate Law
- 15.5: Rate Laws: A Summary
- 15.6: Reaction Mechanisms
- 15.7: The Steady-State Approximation
- 15.8: A Model for Chemical Kinetics
- 15.9: Catalysis
- 16: Liquids and Solids
- 16.01: Intermolecular Forces
- 16.02: The Liquid State
- 16.03: An Introduction to Structures and Types of Solids
- 16.04: Structure and Bonding in Metals
- 16.05: Carbon and Silicon: Network Atomic Solids
- 16.06: Molecular Solids
- 16.07: Ionic Solids
- 16.08: Structures of Ionic Solids
- 16.09: Lattice Defects
- 16.10: Vapor Pressure and Changes of State
- 16.11: Phase Diagrams
- 16.12: Nanotechnology
- 16.E: Exercises
- 17: Solutions
- 17.1: Solution Composition
- 17.2: The Energies of Solution Formation
- 17.3: Factors Affecting Solubility
- 17.4: The Vapor Pressures of Solutions
- 17.5: Boiling-Point Elevation and Freezing-Point Depression
- 17.7: Colligative Properties of Electrolyte Solutions
- 17.7: Osmotic Pressure
- 17.8: Colloids
- 18: The Representative Elements
- 18.01: A Survey of the Representative Elements
- 18.02: Group 1A Metals
- 18.03: The Chemistry of Hydrogen
- 18.04: Group 2A Elements
- 18.05: Group 3A Elements
- 18.06: Group 4A Elements
- 18.07: The Group 5A Elements
- 18.08: The Chemistry of Nitrogen
- 18.09: The Chemistry of Phosphorus
- 18.10: The Group 6A Elements
- 18.11: The Chemistry of Oxygen
- 18.12: The Chemistry of Sulfur
- 18.13: The Group 7A Elements
- 18.14: The Group 8A Elements
- 19: Transition Metals and Coordination Chemistry
- 19.1: The Transition Metals: A Survey
- 19.2: The First-Row Transition Metals
- 19.3: Coordination Compounds
- 19.4: Isomerism
- 19.5: Bonding in Complex Ions
- 19.6: The Crystal Field Model
- 19.7: Molecular Orbital Model
- 19.8: The Biologic Importance of Coordination Complexes
- 20: The Nucleus A Chemists View
- 20.1: Nuclear Stability and Radioactive Decay
- 20.2: Radioactive Kinetics
- 20.3: Nuclear Transformations
- 20.4: Detections and Applications of Radioactivity
- 20.5: Thermodynamic Stability of Nuclei
- 20.6: Nuclear Fission and Fusion
- 20.7: Effects of Radiation on Matter
- 21: Organic and Biological Chemistry
- 21.1: Alkanes: Saturated Hydrocarbons
- 21.2: Alkenes and Alkynes
- 21.3: Aromatic Hydrocarbons
- 21.4: Hydrocarbon Derivatives
- 21.5: Polymers
- 21.6: Natural Polymers