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OIT: CHE 332 - Organic Chemistry II

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OIT: CHE 332 - Organic Chemistry II

Chemistry
Publisher
LibreTexts
Source
LibreTexts
License
CC BY-NC-SA
Language
EN
Category
Basic Sciences
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Contents· 127 sections
  1. 1: Fall term review sections
  2. 1: Introduction to Organic Structure and Bonding I
  3. 1.0: Prelude to Atoms Electron Configurations and Lewis Structures
  4. 1.1: Drawing Organic Structures
  5. 1.2: Functional groups and organic nomenclature
  6. 1.3: Structures of some important biomolecules
  7. 1.3.0: Introduction to Amino Acids and Proteins
  8. 1.3.1: Introduction to carbohydrate structure
  9. 1.3.2: Introduction to Lipid Structure
  10. 1.3.3: Introduction to nucleic acid (DNA and RNA) structure
  11. 1.4: Solutions to Chapter 1 Exercises
  12. 1.E: Problems for Chapter 1
  13. 1.0: Solutions to selected Chapter 1 problems
  14. 2: Introduction to Organic Structure and Bonding II
  15. 2.0: Prelude to Organic Structure and Bonding II
  16. 2.1: Valence Bond Theory
  17. 2.2: Molecular orbital theory- conjugation and aromaticity
  18. 2.3: Resonance
  19. 2.4: Non-covalent interactions
  20. 2.5: Physical properties of organic compounds
  21. 2.6: Solutions to Chapter 2 exercises
  22. 2.P: Problems for Chapter 2
  23. 1.0: Solutions to selected chapter 2 problems
  24. 3: Conformations and Stereochemistry
  25. 3.0: Prelude to Conformations and Stereochemistry
  26. 3.1: Conformations of open-chain organic molecules
  27. 3.2: Conformations of cyclic organic molecules
  28. 3.3: Chirality and stereoisomers
  29. 3.4: Naming chiral centers- the R and S system
  30. 3.5: Optical Activity
  31. 3.6: Compounds with multiple chiral centers
  32. 3.7: Meso Compounds
  33. 3.8: Fischer and Haworth projections
  34. 3.9: Stereochemistry of alkenes
  35. 3.10: Stereochemistry in biology and medicine
  36. 3.11: Prochirality
  37. 3.12: Solutions to Chapter 3 exercises
  38. 3.P: Problems for Chapter 3
  39. 4: Structure Determination I- UV-Vis and Infrared Spectroscopy Mass Spectrometry
  40. 4.0: Prelude to Structure Determination I
  41. 4.1: Introduction to molecular spectroscopy
  42. 4.2: Mass Spectrometry
  43. 4.3: Infrared spectroscopy
  44. 4.4: Ultraviolet and visible spectroscopy
  45. 4.P: Problems for Chapter 4
  46. 6: Overview of Organic Reactivity
  47. 6.0: Prelude to Organic Reactivity
  48. 6.1: A First Look at Some Organic Reaction Mechanism
  49. 6.2: A Quick Review of Thermodynamics and Kinetics
  50. 6.3: Catalysis
  51. 6.4: Comparing Biological Reactions to Laboratory Reactions
  52. 6.E: Overview of Organic Reactivity (Exercises)
  53. 6.S: Overview of Organic Reactivity (Summary)
  54. 7: Acid-base Reactions (portions)
  55. 7.0: Prelude to Acid-base Reactions
  56. 7.1: Overview of Acid-Base Reactions
  57. 7.2: The Acidity Constant
  58. 7: Acid-base Reactions
  59. 7.0: Prelude to Acid-base Reactions
  60. 7.1: Overview of Acid-Base Reactions
  61. 7.2: The Acidity Constant
  62. 7.3: Structural Effects on Acidity and Basicity
  63. 7.4: Acid-base Properties of Phenols
  64. 7.5: Acid-base properties of nitrogen-containing functional groups
  65. 7.6: Carbon Acids
  66. 7.7: Polyprotic Acids
  67. 7.8: Effects of enzyme microenvironment on acidity and basicity
  68. 7.E: Acid-base Reactions (Exercises)
  69. 7.S: Acid-base Reactions (Summary)
  70. 8: Nucleophilic Substitution Reactions
  71. 8.0: Prelude to Nucleophilic Substitution Reactions
  72. 8.1: Two Mechanistic Models for Nucleophilic Substitution
  73. 8.2: Nucleophiles
  74. 8.3: Electrophiles
  75. 8.4: Leaving Groups
  76. 8.5: Regiochemistry of SN1 Reactions with Allylic Electrophiles
  77. 8.6: SN1 or SN2 Predicting the Mechanism
  78. 8.7: Biological Nucleophilic Substitution Reactions
  79. 8.8: Nucleophilic substitution in the Lab
  80. 8.E: Nucleophilic Substitution Reactions (Exercises)
  81. 8.S: Nucleophilic Substitution Reactions (Summary)
  82. 9: Phosphate Transfer Reactions
  83. 9.0: Prelude to Phosphate Transfer Reactions
  84. 9.1: Overview of Phosphate Groups
  85. 9.2: Phosphate Transfer Reactions - An Overview
  86. 9.3: ATP The Principal Phosphate Group Donor
  87. 9.4: Phosphorylation of Alcohols
  88. 9.5: Phosphorylation of Carboxylates
  89. 9.6: Hydrolysis of Organic Phosphates
  90. 9.7: Phosphate Diesters in DNA and RNA
  91. 9.8: The Organic Chemistry of Genetic Engineering
  92. 9.9: NMR of phosphorylated compounds
  93. 9.E: Phosphate Transfer Reactions (Exercise)
  94. 9.S: Phosphate Transfer Reactions (Summary)
  95. 10: Nucleophilic Carbonyl Addition Reactions
  96. 10.0: Prelude to Nucleophilic Carbonyl Addition Reactions
  97. 10.1: Nucleophilic Additions to Aldehydes and Ketones - An Overview
  98. 10.2: Hemiacetals Hemiketals and Hydrates
  99. 10.3: Acetals and Ketals
  100. 10.4: N-glycosidic Bonds
  101. 10.5: Imines
  102. 10.6: A Look Ahead - Addition of Carbon and Hydride Nucleophiles to Carbonyls
  103. 10.E: Nucleophilic Carbonyl Addition Reactions (Exercises)
  104. 10.S: Nucleophilic Carbonyl Addition Reactions (Summary)
  105. 11: Nucleophilic Acyl Substitution Reactions
  106. 11.0: Prelude to Nucleophilic Acyl Substitution Reactions
  107. 11.1: Carboxylic Acid Derivatives
  108. 11.2: The Nucleophilic Acyl Substitution Mechanism
  109. 11.3: Acyl Phosphates
  110. 11.4: The Relative Reactivity of Carboxylic Acid Derivatives
  111. 11.5: Acyl Phosphates
  112. 11.6: Hydrolysis of Thioesters Esters and Amides
  113. 11.7: Protein Synthesis on the Ribosome
  114. 11.8: Nucleophilic Substitution at Activated Amides and Carbamides
  115. 11.9: Nucleophilic Acyl Substitution Reactions in the Laboratory
  116. 11.E: Nucleophilic Acyl Substitution Reactions (Exercises)
  117. 11.S: Nucleophilic Acyl Substitution Reactions (Summary)
  118. 11.Z: A Look Ahead - Acyl Substitution Reactions with a Carbanion or Hydride Ion Nucleophile
  119. 12: Reactions at the -Carbon Part I
  120. 12.0: Prelude to Reactions at the -carbon part I
  121. 12.1: Review of Acidity at the -Carbon
  122. 12.2: Isomerization at the -Carbon
  123. 12.3: Aldol Addition
  124. 12.4: -Carbon Reactions in the Synthesis Lab - Kinetic vs. Thermodynamic Alkylation Products
  125. 12.5: Nitrosation
  126. 12.E: Reactions at the -Carbon Part I (Exercises)
  127. 12.S: Reactions at the -Carbon Part I (Summary)