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Organic Chemistry I

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Organic Chemistry I

This Libretext is for the first semester of organic chemistry at Providence College. The course materials have been adapted from the lecture notes I have accumulated over the years and Organic Chemistry, 5th edition, by Maitland Jones, Jr. and Stephen Fleming. Course topics include organic structure and bonding, nomenclature, conformational analysis, structure elucidation, stereochemistry, substitution and elimination reactions, and reactions of alkenes and alkynes.

Chemistry
Publisher
LibreTexts
Source
LibreTexts
License
CC BY-NC-SA
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 60 sections
  1. 01: Introduction to Organic Chemistry
  2. 1.01: Line Angle Notation as the Language of Chemical Structure
  3. 1.02: Using Chemical Arrows
  4. 1.03: Resonance
  5. 1.04: Acids and Bases
  6. 1.05: Guiding Principles of Organic Chemistry
  7. 02: Bonding in Organic Molecules
  8. 2.01: Lewis and Valence Bond Models
  9. 2.02: Molecular Orbital Theory
  10. 2.03: Bonding in Symmetrical Hydrocarbons
  11. 2.04: Bonding in Unsymmetrical Systems
  12. 03: Simple Hydrocarbons
  13. 3.01: Nomenclature
  14. 3.02: Conformations of Acyclic Hydrocarbons
  15. 3.03: Conformations of Substituted Hydrocarbons
  16. 04: Rings
  17. 4.01: Cyclohexane Ring Conformations
  18. 4.02: A-values and Equilibrium Ratios
  19. 4.03: Converting Between Chair Conformations
  20. 4.04: Other Ring Conformations
  21. 4.05: 4.5 Fused Ring Systems
  22. 05: Analytical Methods for Structure Elucidation
  23. 5.01: The Physics of Nuclear Magnetic Resonance Spectroscopy
  24. 5.02: 5.2 Determining the Number of Signals in NMR Spectroscopy
  25. 5.03: Factors That Influence NMR Chemical Shift
  26. 5.04: Infrared Spectroscopy
  27. 5.05: Mass Spectrometry
  28. 06: Alkenes
  29. 6.01: Cahn-Ingold-Prelog Convention
  30. 6.02: Bonding Stereoisomerism and Stability
  31. 6.03: Electrophilic Addition
  32. 6.04: Acid-Catalyzed Hydration
  33. 07: Stereochemistry
  34. 7.01: The Fundamentals
  35. 7.02: Chirality
  36. 7.03: Absolute Configuration
  37. 7.04: Fisher Projections
  38. 7.05: Determining Numbers of Stereoisomers
  39. 7.06: Creating Chiral Centers
  40. 7.07: Resolution
  41. 08: Substitution Reactions
  42. 8.01: Substituted Alkanes
  43. 8.02: Polarity Acidity and Solubility
  44. 8.03: The Basics of Determining Mechanism
  45. 8.04: Nucleophilic Substitution - 1st Order
  46. 8.05: Nucleophilic Substitution - 2nd Order
  47. 8.06: Converting Alcohols into Better Leaving Groups
  48. 8.07: Peculiarities in Substitution Chemistry
  49. 09: Elimination Reactions
  50. 9.01: First Order Eliminations
  51. 9.02: Second Order Eliminations
  52. 9.03: Rearrangement of Carbocations
  53. 10: Addition Reactions of Alkenes
  54. 10.01: Hydrogenation
  55. 10.02: Concerted Cycloadditions
  56. 10.03: Polymerization Reactions
  57. 11: Synthesis and Reactivity of Alkynes
  58. 11.01: Synthesis of Alkynes
  59. 11.02: Alkyne Reduction and Electrophilic Addition
  60. 11.03: Cycloaddition Reactions of Alkynes