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Structure & Reactivity IV: Reactivity in Organic, Biological and Inorganic Chemistry 2
Kinetics, Substitution Reactions in Organic and Inorganic Chemistry, Addition and Elimination Reactions Involving Alkenes and Aromatics
- Author
- Chris Schaller
- Publisher
- College of Saint Benedict/Saint John's University
- Source
- LibreTexts
- License
- CC BY-NC
- Language
- EN
- Category
- Basic Sciences
Contents· 83 sections
- 01: Reaction Kinetics
- 1.01: Introduction- Reaction Kinetics
- 1.02: Reaction Rates
- 1.03: Activation Barriers
- 1.04: Collisions and Phase
- 1.05: Collisions and Concentration
- 1.06: Rate Laws
- 1.07: Elementary Reactions
- 1.08: Catalysis
- 1.09: Solutions to Selected Problems
- 02: Mathematical Tools in Reaction Kinetics
- 2.01: Determination of Activation Parameters
- 2.02: The Rate Law Takes Different Forms
- 2.03: Determining the Rate Law Experimentally
- 2.04: Elementary Reactions and the Rate Law
- 2.05: Enzyme Kinetics and Inhibition
- 2.06: Characterization- The Mathematics Behind Enzyme Kinetics
- 2.07: Potential Energy Surfaces
- 2.08: Kinetic Isotope Effects
- 2.09: Linear Free Energy Relationships
- 2.10: Solutions to Selected Problems
- 03: Ligand Substitution in Coordination Complexes
- 3.01: Introduction to Substitution
- 3.02: Mechanistic Possibilities
- 3.03: Associative Mechanism and Kinetics
- 3.04: Dissociative Mechanism and Kinetics
- 3.05: Activation Parameters
- 3.06: Some Reasons for Differing Mechanisms
- 3.07: The Trans Effect
- 3.08: Solutions to Selected Problems
- 04: Aliphatic Nucleophilic Substitution
- 4.01: Introduction to Aliphatic Nucleophilic Substitution
- 4.02: Mechanism of Aliphatic Nucleophilic Substitution
- 4.03: Aliphatic Nucleophilic Substitution - Rate Laws
- 4.04: Stereochemistry
- 4.05: Regiochemistry
- 4.06: Structural Factors Influencing the Mechanism
- 4.07: Solvent Effects
- 4.08: Nucleophilicity
- 4.09: Enolate Nucleophiles
- 4.10: Leaving Group Formation
- 4.11: Addition to Strained Rings - Epoxides
- 4.12: Elimination
- 4.13: Regiochemistry in Elimination
- 4.14: Stereochemistry in Elimination
- 4.15: Factors Influencing the Elimination Mechanism
- 4.16: Nucleophilic Substitution in Synthesis - Alcohols and Ethers
- 4.17: Nucleophilic Substitution in Synthesis- Amines
- 4.18: Nucleophilic Substitution at Silicon
- 4.19: Extra Problems with Nucleophilic Substitution and Elimination
- 4.20: Solutions to Selected Problems
- 05: Oxidative Addition and Reductive Elimination
- 5.01: Introduction
- 5.02: Reaction Overview
- 5.03: Polar Oxidative Addition
- 5.04: Concerted Oxidative Addition
- 5.05: Oxidative Addition in Action- Catalytic Hydrogenation
- 5.06: Coupling Reactions in Organic Synthesis
- 5.07: Solutions to Selected Problems
- 06: Electrophilic Addition to Alkenes
- 6.01: Introduction to Electrophilic Addition
- 6.02: Cations in Electrophilic Addition
- 6.03: Solvent Participation in Electrophilic Addition
- 6.04: Stabilized Cations in Electrophilic Addition
- 6.05: Addition to Coordinated Alkenes
- 6.06: Insertion at Coordinated Alkenes
- 6.07: Concerted Addition to Alkenes
- 6.08: Epoxidation
- 6.09: Cyclopropanation
- 6.10: Alkene Oxidations
- 6.11: Alkene Polymerisation
- 6.12: Alkene Polymerisation- Living Cationic Methods
- 6.13: Ziegler-Natta Polymerization
- 6.14: Solutions for Selected Problems.
- 07: Electrophilic Aromatic Substitution
- 7.01: Introduction to Electrophilic Aromatic Substitution
- 7.02: Mechanism of Electrophilic Aromatic Substitution
- 7.03: Formation of the Electrophile
- 7.04: Activation and Deactivation
- 7.05: Directing Effects
- 7.06: Solutions to Selected Problems
- 08: Organic Synthesis
- 8.01: Road Maps in Total Synthesis of Natural Products