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Organic Chemistry II

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Organic Chemistry II

This Libretext is for the second semester of organic chemistry at Providence College. The course materials have been adapted from the lecture notes I have accumulated over the years and Organic Chemistry, 5th edition, by Maitland Jones, Jr. and Stephen Fleming. Course topics include radical reactions, conjugation, aromaticity, aromatic substitution, carbonyl addition, carbonyl substitution, and reactions of enolates.

Chemistry
Author
Seann Mulcahy
Publisher
Providence College
Source
LibreTexts
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 43 sections
  1. 12: Radical Reactions
  2. 12.01: Radical Intermediates
  3. 12.02: Radical Reactions
  4. 12.03: Organometallics
  5. 13: Conjugation
  6. 13.01: Allyl System
  7. 13.02: Dienes
  8. 13.03: Diels-Alder reaction
  9. 13.04: Diels-Alder Regio- and Stereoselectivity
  10. 14: Aromaticity
  11. 14.01: Conjugation vs. Aromaticity
  12. 14.02: Frost's Circle
  13. 14.03: Heteroaromaticity
  14. 15: Aromatic Substitution
  15. 15.01: Electrophilic Aromatic Substitution
  16. 15.02: Regioselectivity in Electrophilic Aromatic Substitution
  17. 15.03: Multiple Substituents and Heteroaromatic Rings
  18. 15.04: Nucleophilic Aromatic Substitution
  19. 15.05: Other Reactions of Aromatics
  20. 16: Nucleophilic Addition to Carbonyls
  21. 16.01: Nucleophilic Addition to the Carbonyl Group
  22. 16.02: Irreversible Nucleophilic Addition
  23. 16.03: Reversible Nucleophilic Addition
  24. 16.04: Acetal Formation
  25. 16.05: Nucleophilic Addition Under Neutral Conditions
  26. 16.06: 5.6 Alcohol Oxidation
  27. 17: Nucleophilic Acyl Substitution
  28. 17.01: Nucleophilic Acyl Substitution
  29. 17.02: Reactions via Carbonyl Substitution
  30. 17.03: Double Nucleophilic Acyl Substitution
  31. 17.04: Super Leaving Groups
  32. 17.05: Nitriles
  33. 17.06: 6.6 Named Reactions
  34. 18: Enols and Enolates
  35. 18.01: Enols and Enolates
  36. 18.02: Consequences of Tautomerization
  37. 18.03: Molecular Orbital Description of Enolates
  38. 19: Reactions of Enolates
  39. 19.01: Reactions of Enolates with Aldehydes and Ketones
  40. 19.02: Reactions of Enolates with Esters and Anhydrides
  41. 19.03: Reactions of Enolates with Alkyl Halides
  42. 19.04: Reactions of Enolates with ()()-Unsaturated Carbonyls
  43. 19.05: Retrosynthesis with Enolates