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AUCHE 252 - Organic Chemistry II

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AUCHE 252 - Organic Chemistry II

Chemistry
Author
Brian Rempel
Publisher
Augustana Faculty, University of Alberta
Source
LibreTexts
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 65 sections
  1. 01: Carbonyl Reactivity
  2. 1.01: Structure of the Carbonyl Group
  3. 1.02: Reactivity of the Carbonyl Group- Mechanisms of Addition
  4. 02: 1H NMR
  5. 2.01: Index of Hydrogen Deficiency (IHD)
  6. 2.02: Nuclear Magnetic Resonance Spectroscopy
  7. 2.03: The Nature of NMR Absorptions
  8. 2.04: Chemical Shifts
  9. 2.05: Chemical Shifts in H NMR Spectroscopy
  10. 2.06: Integration of H NMR Absorptions- Proton Counting
  11. 2.07: Spin-Spin Splitting in H NMR Spectra
  12. 2.08: H NMR Spectroscopy and Proton Equivalence
  13. 2.09: More Complex Spin-Spin Splitting Patterns
  14. 2.10: Uses of H NMR Spectroscopy
  15. 03: Alcohols and Ethers
  16. 3.01: Preparing Ethers
  17. 3.02: Crown Ethers
  18. 3.03: Reactions of Ethers- Acidic Cleavage
  19. 3.04: Cyclic Ethers - Epoxides
  20. 3.05: Reactions of Epoxides- Ring-opening
  21. 3.06: Nomenclature of Alcohols
  22. 3.07: Reactions of Alcohols
  23. 3.08: Conversion of Alcohols to Alkyl Halides with SOCl2 and PBr3
  24. 3.09: Protecting Groups in Organic Synthesis
  25. 04: Redox Reactions
  26. 4.01: Oxidation and Reduction of Organic Compounds - An Overview
  27. 4.02: Nucleophilic Addition of Hydride and Grignard Reagents- Alcohol Formation
  28. 4.03: Oxidation of Alcohols
  29. 05: Aldehydes and Ketones
  30. 5.01: Keto-Enol Tautomerism
  31. 5.02: Reactivity of Enols- The Mechanism of Alpha-Substitution Reactions
  32. 5.03: Alpha Halogenation of Aldehydes and Ketones
  33. 5.04: Reactivity of Enolate Ions
  34. 5.05: Alkylation of Enolate Ions
  35. 5.06: Carbonyl Condensations - The Aldol Reaction
  36. 5.07: Carbonyl Condensations versus Alpha Substitutions
  37. 5.08: Dehydration of Aldol Products - Synthesis of Enones
  38. 5.09: Mixed Aldol Reactions
  39. 5.10: Intramolecular Aldol Reactions
  40. 5.11: Nucleophilic Addition of Water- Hydration
  41. 5.12: Nucleophilic Addition of Alcohols- Acetal Formation
  42. 5.13: Nucleophilic Addition of Amines- Imine and Enamine Formation
  43. 06: Carboxylic Acid Derivatives
  44. 6.01: Nucleophilic Acyl Substitution Reactions
  45. 6.02: Nucleophilic Acyl Substitution Reactions of Carboxylic Acids
  46. 6.03: The Claisen Condensation Reaction
  47. 6.04: Mixed Claisen Condensations
  48. 6.05: Intramolecular Claisen Condensations - The Dieckmann Cyclization
  49. 07: Conjugated Pi Systems
  50. 7.01: Stability of Conjugated Dienes- Molecular Orbital Theory
  51. 7.02: Electrophilic Additions to Conjugated Dienes- Allylic Carbocations
  52. 7.03: Kinetic vs. Thermodynamic Control of Reactions
  53. 7.04: Naming Aromatic Compounds
  54. 7.05: Structure and Stability of Benzene
  55. 7.06: Aromaticity and the Huckel 4n 2 Rule
  56. 7.07: Aromatic Ions
  57. 7.08: Aromatic Heterocycles - Pyridine and Pyrrole
  58. 08: Electrophilic Aromatic Substitutions
  59. 8.01: Introduction
  60. 8.02: Electrophilic Aromatic Substitution Reactions - Bromination
  61. 8.03: Other Aromatic Substitutions
  62. 8.04: Alkylation and Acylation of Aromatic Rings - The Friedel-Crafts Reaction
  63. 8.05: Substituent Effects in Substituted Aromatic Rings
  64. 8.06: An Explanation of Substituent Effects
  65. 8.07: Clemmensen Reduction