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EM 4300: Inorganic Chemistry

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EM 4300: Inorganic Chemistry

Topics in inorganic chemistry, including molecular structure and bonding, symmetry, ionic structure and bonding, inorganic reactions, including acid base and oxidation-reduction reactions, coordination chemistry and bioinorganic chemistry.

Chemistry
Author
Larry Mink
Publisher
CSU San Bernardino
Source
LibreTexts
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 143 sections
  1. 01: Atomic Structure
  2. 1.01: Historical Development of Atomic Theory
  3. 1.02: The quantum-mechanical model of the atom
  4. 1.03: Periodic Properties of Atoms
  5. 1.04: Concept Review Questions Chapter 1
  6. 1.05: Homework Problems Chapter 1
  7. 02: Symmetry and Group Theory
  8. 2.01: Symmetry Elements and Operations
  9. 2.02: Point Groups
  10. 2.03: Matrix Representations of Symmetry Operations and Character Tables
  11. 2.04: Concept Review Questions Chapter 2
  12. 2.05: Homework Problems Chapter 2
  13. 03: Review of Chemical Bonding
  14. 3.01: Prelude to Chemical Bonding
  15. 3.02: Valence Bond Theory- Lewis Dot Structures the Octet Rule Formal Charge Resonance and the Isoelectronic Principle
  16. 3.03: The Shapes of Molecules (VSEPR Theory) and Orbital Hybridization
  17. 3.04: Bond Polarity and Bond Strength
  18. 3.05: Discussion Questions
  19. 3.06: Problems
  20. 3.07: References
  21. 04: Molecular Orbital Theory
  22. 4.01: Prelude to Molecular Orbital Theory
  23. 4.02: Constructing Molecular Orbitals from Atomic Orbitals
  24. 4.03: Orbital Symmetry
  25. 4.04: and orbitals
  26. 4.05: Diatomic Molecules
  27. 4.06: Orbital Filling
  28. 4.07: Periodic Trends in Bonding
  29. 4.08: Three-center Bonding
  30. 4.09: Building up the MOs of More Complex Molecules- NH P
  31. 4.10: Homology of and orbitals in MO diagrams
  32. 4.11: Chains and Rings of -Conjugated Systems
  33. 4.12: Discussion Questions
  34. 4.13: Problems
  35. 4.14: References
  36. 05: Coordination Chemistry I - Structures and Isomers
  37. 5.01: History
  38. 5.02: Nomenclature
  39. 5.03: Coordination Numbers and Structures
  40. 5.04: Isomerism
  41. 5.05: Concept Review Questions Chapter 5
  42. 5.06: Homework Problems Chapter 5
  43. 06: Coordination Chemistry III - Bonding
  44. 6.01: 7.1 Bonding in Coordination Compounds
  45. 6.02: Concept Review Questions Chapter 7
  46. 6.03: Homework Problems Chapter 7
  47. 07: Metals and Alloys- Structure Bonding Electronic and Magnetic Properties
  48. 7.01: Prelude to Metals and Alloys
  49. 7.02: Unit Cells and Crystal Structures
  50. 7.03: Bravais Lattices
  51. 7.04: Crystal Structures of Metals
  52. 7.05: Bonding in Metals
  53. 7.06: Conduction in Metals
  54. 7.07: Atomic Orbitals and Magnetism
  55. 7.08: Ferro- Ferri- and Antiferromagnetism
  56. 7.09: Hard and Soft Magnets
  57. 7.10: Discussion Questions
  58. 7.11: Problems
  59. 7.12: References
  60. 08: Metals and Alloys - Mechanical Properties
  61. 8.01: Defects in Metallic Crystals
  62. 8.02: Work Hardening Alloying and Annealing
  63. 8.03: Malleability of Metals and Alloys
  64. 8.04: Iron and Steel
  65. 8.05: Amorphous Alloys
  66. 8.06: Discussion Questions
  67. 8.07: Problems
  68. 8.08: References
  69. 09: Ionic and Covalent Solids - Structures
  70. 9.01: Prelude to Ionic and Covalent Solids - Structures
  71. 9.02: Close-packing and Interstitial Sites
  72. 9.03: Structures Related to NaCl and NiAs
  73. 9.04: Tetrahedral Structures
  74. 9.05: Layered Structures and Intercalation Reactions
  75. 9.06: Bonding in TiS MoS and Pyrite Structures
  76. 9.07: Spinel Perovskite and Rutile Structures
  77. 9.08: Discussion Questions
  78. 9.09: Problems
  79. 9.10: References
  80. 10: Ionic and Covalent Solids - Energetics
  81. 10.01: Ionic Radii and Radius Ratios
  82. 10.02: Structure Maps
  83. 10.03: Energetics of Crystalline Solids- The Ionic Model
  84. 10.04: Born-Haber Cycles for NaCl and Silver Halides
  85. 10.05: Kapustinskii Equation
  86. 10.06: Discovery of Noble Gas Compounds
  87. 10.07: Stabilization of High and Low Oxidation States
  88. 10.08: Alkalides and Electrides
  89. 10.09: Resonance Energy of Metals
  90. 10.10: Prelude to Ionic and Covalent Solids - Energetics
  91. 10.11: The Strange Case of the Alkali Oxides
  92. 10.12: Lattice Energies and Solubility
  93. 10.13: Discussion Questions
  94. 10.14: Problems
  95. 10.15: References
  96. 11: Electronic Properties of Materials - Superconductors and Semiconductors
  97. 11.01: Prelude to Electronic Properties of Materials - Superconductors and Semiconductors
  98. 11.02: Metal-Insulator Transitions
  99. 11.03: Superconductors
  100. 11.04: Periodic Trends- Metals Semiconductors and Insulators
  101. 11.05: Semiconductors- Band Gaps Colors Conductivity and Doping
  102. 11.06: Semiconductor p-n Junctions
  103. 11.07: Diodes LEDs and Solar Cells
  104. 11.08: Amorphous Semiconductors
  105. 11.09: Discussion Questions
  106. 11.10: Problems
  107. 11.11: References
  108. 12: Physical Techniques in Inorganic Chemistry
  109. 13: Coordination Chemistry IV - Electronic Spectra
  110. 13.01: Microstates and Terms
  111. 13.02: Term splitting in ligand fields selection rules Tanabe-Sugano diagrams. Metal to ligand and ligand to metal transitions
  112. 13.03: Concept Review Questions Chapter 8
  113. 13.04: Homework Problems Chapter 8
  114. 14: Coordination Chemistry V - Reactions and Mechanisms
  115. 14.01: Substitution Reactions and their Mechanisms
  116. 14.02: Concept Review Questions Chapter 9
  117. 14.03: Homework Problems Chapter 9
  118. 15: Acid-Base Chemistry
  119. 15.01: Prelude to Acid-Base Chemistry
  120. 15.02: Brnsted and Lewis Acids and Bases
  121. 15.03: Hard and Soft Acids and Bases
  122. 15.04: The Electrostatic-Covalent (ECW) Model for Acid-Base Reactions
  123. 15.05: Frustrated Lewis Pairs
  124. 15.06: Discussion Questions
  125. 15.07: Problems
  126. 15.08: References
  127. 16: Redox Stability and Redox Reactions
  128. 16.01: Prelude to Redox Stability and Redox Reactions
  129. 16.02: Balancing Redox Reactions
  130. 16.03: Electrochemical Potentials
  131. 16.04: Latimer and Frost Diagrams
  132. 16.05: Redox Reactions with Coupled Equilibria
  133. 16.06: Pourbaix Diagrams
  134. 16.07: Discussion Questions
  135. 16.08: Problems
  136. 16.09: References
  137. 17: Transition-Metal Storage Transport and Biomineralization
  138. 17.01: Biological Significance of Iron Zinc Copper Molybdenum Cobalt Chromium Vanadium and Nickel
  139. 17.02: Biological Systems of Metal Storage
  140. 17.03: Chemical Properties Relative to Storage and Transport
  141. 17.04: Iron Biomineralization
  142. 17.05: Transport of Iron
  143. 17.06: Transport of Zinc Copper Vanadium Chromium Molybdenum and Cobalt