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Kinetics

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Kinetics

Chemistry
Publisher
Pacific Union College
Source
LibreTexts
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 85 sections
  1. 01: Boltzmann
  2. 02: Boltzmann Statistics
  3. 2.01: The Independent-Molecule Approximation
  4. 2.02: The Probability of An Energy Level at Constant N, V, and T
  5. 2.03: The Population Sets of a System at Equilibrium at Constant N, V, and T
  6. 2.04: How can Infinitely Many Probabilities Sum to Unity?
  7. 2.05: The Total Probability Sum at Constant N, V, and T
  8. 2.06: The Most Probable Population Set at Constant N, V, and T
  9. 2.07: The Microstates of a Given Population Set
  10. 2.08: The Probabilities of Microstates that Have the Same Energy
  11. 2.09: The Probabilities of the Population Sets of an Isolated System
  12. 2.10: Entropy and Equilibrium in an Isolated System
  13. 2.11: Thermodynamic Probability and Equilibrium in an Isomerization Reaction
  14. 2.12: The Degeneracy of an Isolated System and Its Entropy
  15. 2.13: The Degeneracy of an Isolated System and its Entropy
  16. 2.14: Effective Equivalence of the Isothermal and Constant-energy Conditions
  17. 2.15: Problems
  18. 03: The Boltzmann Distribution Function
  19. 3.01: Finding the Boltzmann Equation
  20. 3.02: Lagrange's Method of Undetermined Multipliers
  21. 3.03: Deriving the Boltzmann Equation I
  22. 3.04: Deriving the Boltzmann Equation II
  23. 3.05: Partition Functions and Equilibrium - Isomeric Molecules
  24. 3.06: Finding ß and the Thermodynamic Functions for Distinguishable Molecules
  25. 3.07: The Microscopic Model for Reversible Change
  26. 3.08: The Third Law of Thermodynamics
  27. 3.09: The Partition Function for a System of N Molecules
  28. 3.10: Problems
  29. 04: Some Basic Applications of Statistical Thermodynamics
  30. 4.01: Interpreting the Partition Function
  31. 4.02: Conditions under which Integrals Approximate Partition Functions
  32. 4.03: Probability Density Functions from the Energies of Classical-mechanical Models
  33. 4.04: Partition Functions and Average Energies at High Temperatures
  34. 4.05: Energy Levels for a Three-dimensional Harmonic Oscillator
  35. 4.06: Energy and Heat Capacity of the "Einstein Crystal"
  36. 4.07: Applications of Other Entropy Relationships
  37. 4.08: Problems
  38. 05: The Ensemble Treatment
  39. 5.01: Ensembles of N-molecule Systems
  40. 5.02: The Ensemble Entropy and the Value of ß
  41. 5.03: The Thermodynamic Functions of the N-molecule System
  42. 06: The Distribution of Gas Velocities
  43. 6.01: Distribution Functions for Gas-velocity Components
  44. 6.02: Probability Density Functions for Velocity Components in Spherical Coordinates
  45. 6.03: Maxwell's Derivation of the Gas-velocity Probability-density Function
  46. 6.04: The Probability-density Function for Gas Velocities in One Dimension
  47. 6.05: Combining the One-dimensional Probability Density Functions
  48. 6.06: Boyle's Law from the Maxwell-Boltzmann Probability Density
  49. 6.07: Experimental Test of the Maxwell-Boltzmann Probability Density
  50. 6.08: Statistics for Molecular Speeds
  51. 6.09: Pressure Variations for Macroscopic Samples
  52. 6.10: Collisions between Gas Molecules Relative Velocity Coordinates
  53. 6.11: The Probability Density Function for the Relative Velocity
  54. 6.12: The Frequency of Collisions between Unlike Gas Molecules
  55. 6.13: The Rate of Collisions between Unlike Gas Molecules
  56. 6.14: Collisions between like Gas Molecules
  57. 6.15: The Geometry of A Collision between Spherical Molecules
  58. 6.16: The Energy of A Collision between Gas Molecules
  59. 6.17: Problems
  60. 07: Diffusion
  61. 08: Chemical Kinetics
  62. 8.01: Reaction Rates
  63. 8.02: Reaction Order
  64. 8.03: Molecularity of a Reaction
  65. 8.04: More Complex Reactions
  66. 8.05: The Effect of Temperature on Reaction Rates
  67. 8.06: Potential Energy Surfaces
  68. 8.07: Theories of Reaction Rates
  69. 8.08: Isotope Effects in Chemical Reactions
  70. 8.09: Reactions in Solution
  71. 8.10: Fast Reactions in Solution
  72. 8.11: Oscillating Reactions
  73. 8.E: Chemical Kinetics (Exercises)
  74. 09: Enzyme Kinetics
  75. 9.01: General Principles of Catalysis
  76. 9.02: The Equations of Enzyme Kinetics
  77. 9.03: Chymotrypsin- A Case Study
  78. 9.04: Multisubstrate Systems
  79. 9.05: Enzyme Inhibition
  80. 9.06: Allosteric Interactions
  81. 9.07: The Effect of pH on Enzyme Kinetics
  82. 9.08: The Effect of Temperature on Enzyme Kinetics
  83. 9.E: Exercises
  84. Numerical Solutions to Rate Laws
  85. Numerical Solutions