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CHEM 4110: Advanced Inorganic Chemistry

Chemistry

Author: author
Publisher: Catherine McCusker
Source: LibreTexts
License: CC BY-NC-SA
Language: EN
Category: Basic Sciences

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Contents· 235 sections

01: Introduction to Inorganic Chemistry
1.01: What is Inorganic Chemistry
1.02: History of Inorganic Chemistry
1.03: Perspectives
1.04: Practice problems
02: Atomic Structure
2.01: Historical Development of Atomic Theory
2.1.01: The Periodic Table
2.1.02: Discovery of Subatomic Particles and the Bohr Atom
2.02: The Schrodinger Equation and Atomic Wavefunctions
2.03: Aufbau Principle
2.3.01: Shielding
2.3.02: The Aufbau Process
2.3.03: Electron Configuration of Transition Metals
2.04: Periodic Properties of Atoms
2.4.01: Ionization energy
2.4.02: Electron Affinity
2.4.03: Covalent and Ionic Radii
2.05: Problems
03: Simple Bonding Theories
3.01: Lewis Electron-Dot Diagrams
3.1.01: Formal Charge
3.1.02: Resonance
3.1.03: Breaking the Octet rule in Hypervalent Atoms
3.1.04: Breaking the Octet Rule in Hypovalent Atoms
3.02: The Shapes of Molecules (VSEPR Theory) and Orbital Hybridization
3.2.01: Multiple Bonds
3.2.02: Electronegativity and Atomic Size Effects
3.03: Bond Polarity and Bond Strength
3.04: Molecular Polarity
04: Symmetry and Group Theory
4.01: Symmetry Elements and Operations
4.02: Point Groups
4.2.01: Groups of Low and High Symmetry
4.2.02: Other Groups
4.03: Properties and Representations of Groups
4.3.01: Matrices
4.3.02: Representations of Point Groups
4.04: Character Tables
4.05: Examples and Applications of Symmetry
05: Molecular Orbitals
5.01: Formation of Molecular Orbitals from Atomic Orbitals
5.1.01: Molecular Orbitals from s Orbitals
5.1.02: Molecular Orbitals from p Orbitals
5.1.03: Molecular orbitals from d orbitals
5.1.04: Nonbonding Orbitals and Other Factors
5.02: Homonuclear Diatomic Molecules
5.2.01: Molecular Orbitals
5.2.02: Orbital Mixing
5.2.03: Diatomic Molecules of the First and Second Periods
5.2.04: Heteronuclear Diatomic Molecules
5.2.4.01: Orbital ionization energies
5.2.4.02: Polar bonds
5.03: Larger (Polyatomic) Molecules
5.3.01: Bifluoride anion
5.3.02: Carbon Dioxide
5.3.03: HO
5.3.04: NH
5.3.05: BF
5.04: BeH is Linear and HO is Bent
5.05: Photoelectron Spectroscopy
5.06: Complexes with Multiple Metal-Metal Bonds
5.07: Problems
06: Coordination Chemistry - Structure and Isomers
6.01: Prelude to Coordination Chemistry I - Structure and Isomers
6.02: Nomenclature and Ligands
6.03: Isomerism
6.04: Coordination Numbers and Structures
6.05: Coordination Frameworks
6.06: Problems
07: Coordination Chemistry - Bonding
7.01: Evidence for Electronic Structures
7.02: Bonding Theories Overview
7.03: Crystal Field Theory
7.04: Ligand Field Theory
7.05: The Jahn-Teller Effect
7.06: Four- and Six-Coordinate Preferences
08: Coordination Chemistry - Spectroscopy
8.01: Absorption of Light
8.02: Types of Transition and Selection Rules for Transition Metal Complexes
8.03: Term States and Symbols for Multielectron Atoms
8.3.01: Finding Microstates and Term Symbols
8.3.02: Spin-Orbit Coupling
8.04: Ligand Field Transitions
8.05: Charge Transfer Transitions
8.5.01: Applications of Charge-Transfer
09: Coordination Chemistry - Reactions and Mechanisms
9.01: Thermodynamic Data
9.02: Introduction to Reactions of Metal Complexes
9.03: Substitutions Reactions
9.3.01: Introduction to Substitution Reactions
9.3.02: Inert and Labile Complexes
9.3.03: Mechanistic Possibilities
9.04: Kinetics Hint at the Reaction Mechanism
9.4.01: Rate Law for Dissociative Mechanisms
9.4.02: Rate Laws for Interchange Mechanisms
9.4.03: Rate Law for Associative Mechanisms
9.4.04: Preassociation Complexes
9.4.05: Activation Parameters
9.4.06: Some Reasons for Differing Mechanisms
9.05: Experimental Evidence in Octahedral Substitutions
9.5.01: Dissociation
9.5.02: Linear Free Energy Relationships
9.5.03: Associative Mechanisms
9.5.04: The conjugate base mechanism
9.5.05: The Kinetic Chelate Effect
9.06: Stereochemistry of Octahedral Reactions
9.6.01: Substitution in trans-en octahedral complexes
9.6.02: Substitution in cis-en octahedral complexes
9.6.03: Isomerization of Chelate Rings
9.07: Substitutions in Square Planar Complexes
9.7.01: Kinetics and Stereochemistry of Square Planar Reactions
9.7.02: Evidence for Associative Reactions
9.08: The Trans Effect
9.09: Redox Mechanisms
9.9.01: Inner Sphere Electron Transfer
9.9.02: Outer Sphere Electron Transfer
10: Organometallic Chemistry
10.01: Introduction to Organometallic Chemistry
10.02: Nomenclature Ligands and Classification
10.2.01: Survey of Organometallic Ligands
10.2.1.01: Carbon Monoxide (Carbonyl Complexes)
10.2.1.02: Ligands similar to CO
10.2.1.03: Hydrides and Dihydrogen Complexes
10.2.02: Bonding between Metal Atoms and Organic Pi Systems
10.2.2.01: Linear Systems
10.2.2.02: Cyclic systems
10.2.2.03: Odd-numbered Systems
10.2.2.04: Fullerene Complexes
10.2.03: Metal-Carbon Bonds
10.2.3.01: Metal Alkyls
10.2.3.02: Carbenes
10.2.3.03: Carbyne (Alkylidyne) Complexes
10.2.3.04: Carbido and Cumulene Complexes
10.2.3.05: Carbon Wires- Polyyne and Polyene Bridges
10.03: Electron Counting in Organometallic Complexes
10.3.01: The 18 Electron Rule
10.3.02: Simplifying the Organometallic Complex by Deconstruction
10.04: Characterization of Organometallic Complexes
10.05: Organometallic Reactions and Catalysis
10.5.01: Reactions Involving Gain or Loss of Ligands
10.5.1.01: Ligand Dissociation and Substitution
10.5.1.02: Oxidative Addition
10.5.1.03: Reductive Elimination
10.5.1.04: Sigma Bond Metathasis
10.5.1.05: Application of Pincer Ligands
10.5.02: Reactions Invloving Modification of Unsaturated Ligands
10.5.2.01: Introduction to Insertion
10.5.2.02: CO Insertions (Alkyl Migration)
10.5.2.03: Migratory Insertion-12-Insertions
10.5.2.04: -Elimination Reactions
10.5.2.05: Abstraction and Addition
10.06: Heterogeneous Catalysts
10.6.01: Ziegler-Natta Polymerizations
10.6.02: Water-Gas Shift Reaction
10.07: Organometallic Catalysts
10.7.01: Catalytic Deuteration
10.7.02: Hydroformylation
10.7.03: Monsanto Acetic Acid Process
10.7.04: Wacker (Smidt) Process
10.7.05: Hydrogenation by Wilkinson's Catalyst
10.7.06: Olefin Metathesis
10.08: Problems
10.8.01: Concept Review Questions Chapter 12
10.8.02: Homework Problems Chapter 12
11: Bioinorganic Chemistry
11.01: Biological Significance of Iron Zinc Copper Molybdenum Cobalt Chromium Vanadium and Nickel
11.02: Introduction to Amino Acids and Proteins
11.03: Overview of Hemoglobin and Myoglobin
11.3.01: Myoglobin Hemoglobin and their Ligands
11.3.02: Oxygen Transport by the Proteins Myoglobin and Hemoglobin
11.04: Ferrodoxins Hydrogenases and Nitrogenases - Metal-Sulfide Proteins
11.4.01: Iron-sulfur Proteins and Models
11.4.02: Iron-sulfur Proteins and Models (Part 2)
11.4.03: Iron-sulfur Proteins and Models (Part 3)
11.4.04: Iron-sulfur Proteins and Models (Part 4)
11.05: The Reaction Pathways of Zinc Enzymes and Related Biological Catalysts
11.5.01: About Carbonic Anhydrase
11.5.02: Catalytic Mechanism
11.5.03: Metal Substitution
11.06: Metals in Medicine
11.6.01: Metal Deficiency and Disease
11.6.02: Toxic Effects of Metals
11.6.03: Aspects of Platinum Binding to DNA
11.6.04: Survey of Metals Used for Diagnosis and Chemotherapy
11.6.05: Platinum Anticancer Drugs- A Case Study
11.6.06: Mapping the Major Adducts ofcis-andtrans-DDP on DNA Sequence Specificity
11.6.07: Structure of Platinum-DNA Complexes
11.6.08: Site-specifically Platinated DNA (154)
11.6.09: Bioinorganic Chemistry of Platinum Anticancer Drugs- How Might They Work
11.6.10: Bioinorganic Chemistry of Platinum Anticancer Drugs How Might They Work (Part 2)
11.6.11: Design of New Inorganic Anticancer Drugs
12: Applications- Photophysics and Photochemistry
12.01: Electronically Excited Molecules
12.02: Photochemical Processes
12.2.01: Dexter Energy Transfer
12.2.02: Fluorescence Resonance Energy Transfer
12.03: Laser Fundamentals
12.04: Atmospheric Photochemistry- Ozone
12.05: Applications of Photochemistry- Photoredox Catalysis
13: Applications - Nanomaterials
13.01: Prelude to Basic Science of Nanomaterials
13.02: Physics and Length Scales- Cavity Laser Coulomb Blockade Nanoscale Magnets
13.03: Semiconductor Quantum Dots
13.04: Synthesis of Semiconductor Nanocrystals
13.05: Surface Energy
13.06: Nanoscale Metal Particles
13.07: Applications of Nanomaterials
13.08: Discussion Questions
13.09: Problems
13.10: References
14: Appendix
14.01: Advanced Group Theory
14.1.01: The Exploitation of Symmetry Can Help Simplify Numerical Calculations
14.1.02: Symmetry Elements and Operations Define the Point Groups
14.1.03: Symmetry Operations Define Groups
14.1.04: Symmetry Operations as Matrices
14.1.05: Molecules can be Represented by Reducible Representations
14.1.06: Character Tables Summarize the Properties of a Point Group
14.1.07: Characters of Irreducible Representations
14.1.08: Using Symmetry to Solve Secular Determinants
14.1.09: Generating Operators
14.1.10: Molecular Motions of a Molecule can be Represented by a Reducible Reperesentation
14.1.11: Reducible Representations are Comprised of Irreducible Representations
14.1.12: Normal Modes of Vibrations Describe how Molecules Vibrate
14.1.13: Symmetry of Vibrations Describes their Spectroscopic Behavior
14.1.14: Symmetry Adapted Linear Combinations are the Sum over all Basis functions
14.1.15: Molecular Orbitals can be Constructed on the Basis of Symmetry
14.1.E: Group Theory - The Exploitation of Symmetry (Exercises)
14.1.T: Character Tables
14.1.T: Correlation Tables
14.02: Derivation of Laporte Rule
14.03: Periodic Table
14.04: Character Tables
14.05: Tanabe-Sugano Diagrams