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CHEM322: Inorganic Chemistry

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CHEM322: Inorganic Chemistry

Chemistry
Author
Amanda Reig
Publisher
Ursinus College
Source
LibreTexts
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 184 sections
  1. 01: Atomic Structure
  2. 1.01: Historical Development of Atomic Theory
  3. 1.1.01: Early Experiments of Atomic Theory
  4. 1.1.02: Discovery of Subatomic Particles
  5. 1.1.03: Quantization of Energy and Bohr Model of the Atom
  6. 1.1.04: Wave-Particle Duality
  7. 1.02: Electronic Structure of the Atom
  8. 1.2.01: Wave Quantization and Particle in a Box
  9. 1.2.02: The Schrodinger Equation
  10. 1.2.03: Quantum Numbers and Atomic Wave Functions
  11. 1.03: Multi-Electron Atoms
  12. 1.3.01: Orbital Energies
  13. 1.3.02: Shielding
  14. 1.3.03: Aufbau Principle
  15. 1.3.04: Slater's Rules
  16. 1.04: Periodic Properties of the Elements
  17. 1.4.01: Effective Nuclear Charge
  18. 1.4.02: Ionization energy
  19. 1.4.03: Electron Affinity
  20. 1.4.04: Covalent and Ionic Radii
  21. 1.4.05: Lanthanide Contraction
  22. 1.4.06: The Uniqueness Principle
  23. 1.05: Unit 1 Practice Problems
  24. 02: Molecular Structure
  25. 2.01: Chemical Bonding
  26. 2.1.01: Types of Chemical Bonds
  27. 2.1.02: Electronegativity and the Bonding Continuum
  28. 2.1.03: Polarizability and Percent Ionic Character
  29. 2.02: Lewis Structures and Molecular Shape
  30. 2.2.01: Lewis Electron-Dot Diagrams
  31. 2.2.02: Formal Charge
  32. 2.2.03: Resonance
  33. 2.2.04: Expanded Octets
  34. 2.2.05: Limitation of Lewis Theory
  35. 2.2.06: Valence Shell Electron-Pair Repulsion
  36. 2.2.07: Lone Pair Repulsion
  37. 2.2.08: Multiple Bonds
  38. 2.2.09: Electronegativity and Atomic Size Effects
  39. 2.2.10: Molecular Polarity
  40. 03: Molecular Symmetry
  41. 3.01: Symmetry Elements and Operations LOs
  42. 3.1.01: Definitions and Examples
  43. 3.02: Point Groups
  44. 3.2.01: Molecular Point Groups
  45. 3.2.02: Assigning Point Groups
  46. 3.2.03: Chirality
  47. 3.03: Unit 3 Practice Problems
  48. 04: Group Theory
  49. 4.01: Groups
  50. 4.1.01: Properties of Groups
  51. 4.02: Representations and Character Tables
  52. 4.2.01: Matrices
  53. 4.2.02: Representations of Point Groups
  54. 4.2.03: Character Tables
  55. 4.03: Application to Vibrational Spectroscopy
  56. 4.3.01: Molecular Vibrations
  57. 4.04: Unit 4 Practice Problems
  58. 05: Molecular Orbitals
  59. 5.01: Valence Bond Theory
  60. 5.1.01: The Shapes of Molecules (VSEPR Theory) and Orbital Hybridization
  61. 5.02: Linear Combination of Atomic Orbitals
  62. 5.2.01: Formation of Molecular Orbitals from Atomic Orbitals
  63. 5.2.02: Molecular Orbitals from s Orbitals
  64. 5.2.03: Molecular Orbitals from p Orbitals
  65. 5.2.04: Molecular orbitals from d orbitals
  66. 5.2.05: Nonbonding Orbitals and Other Factors
  67. 5.03: Diatomic MO Diagrams
  68. 5.3.01: Homonuclear Diatomic Molecules
  69. 5.3.1.01: Molecular Orbitals
  70. 5.3.1.02: Orbital Mixing
  71. 5.3.1.03: Diatomic Molecules of the First and Second Periods
  72. 5.3.1.04: Photoelectron Spectroscopy
  73. 5.3.02: Heteronuclear Diatomic Molecules
  74. 5.3.2.01: Orbital ionization energies
  75. 5.3.2.02: Polar bonds
  76. 5.3.2.03: Ionic Compounds and Molecular Orbitals
  77. 5.04: Polyatomic MO Diagrams
  78. 5.4.01: Ligand Group Orbitals and Generator Functions
  79. 5.4.02: Polyatomic Molecules
  80. 5.4.2.01: Bifluoride anion
  81. 5.4.2.02: Carbon Dioxide
  82. 5.4.2.03: HO
  83. 5.4.2.04: NH
  84. 5.4.03: Why is BeH Linear and HO Bent
  85. 5.05: Pi Bonding and Hypervalency
  86. 5.5.01: BF
  87. 5.5.02: Expanded Octets and Molecular Orbitals
  88. 06: Solid State Chemistry
  89. 6.01: Solid State Structures
  90. 6.1.01: Cubic Lattices and Close Packing
  91. 6.1.02: Ionic Radii and Radius Ratios
  92. 6.02: Crystalline Solids
  93. 6.2.01: Types of Crystalline Solids
  94. 6.2.02: Alloys and Intermetallics
  95. 6.2.03: The Imperfect Solid State
  96. 6.03: X-Ray Crystallography of Solids
  97. 6.3.01: Miller Indices (hkl)
  98. 6.3.02: X-rays and X-ray Diffraction
  99. 6.3.03: Powder X-ray Diffraction
  100. 6.04: Energetics of Ionic Solids
  101. 6.4.01: Lattice Enthlapies of Ionic Solids
  102. 6.4.02: Born Haber Cycles
  103. 6.4.03: Lattice Energies and Solubility
  104. 6.4.04: Theoretical Lattice Energy Calculations
  105. 6.4.05: Kapustinskii Equation
  106. 6.05: Band Theory and Conductivity
  107. 6.5.01: Bonding in Metals and Semicondoctors
  108. 6.5.02: The Fermi Level
  109. 6.5.03: Semiconductors- Band Gaps Colors Conductivity and Doping
  110. 6.5.04: Periodic Trends- Metals Semiconductors and Insulators
  111. 6.5.05: Semiconductor p-n Junctions
  112. 6.5.06: Diodes LEDs and Solar Cells
  113. 6.5.07: Superconductors
  114. 07: Acid-Base and Donor-Acceptor Chemistry
  115. 7.01: Acid Base Chemistry
  116. 7.1.01: Arrhenius Model
  117. 7.1.02: Brnsted-Lowry Model
  118. 7.1.03: Metal Ions as Acids
  119. 7.1.04: Autoionization and Solvent Leveling
  120. 7.1.05: Lewis Model and Frontier Orbitals
  121. 7.02: Hard Soft Acid Base Theory
  122. 7.2.01: Hard and Soft Acids and Bases
  123. 7.2.02: Applications of Hard Soft Acid Base Theory
  124. 7.2.03: Theoretical Interpretation of HSAB Theory
  125. 7.03: Unit 7 Practice Problems
  126. 08: Electronic Structure of Coordination Complexes
  127. 8.01: Introduction to Coordination Complexes
  128. 8.1.01: What are Coordination Complexes
  129. 8.1.02: History of Coordination Complexes
  130. 8.1.03: Nomenclature and Ligands
  131. 8.1.04: Coordination Numbers and Structures
  132. 8.1.05: Isomerism
  133. 8.02: Crystal Field Theory
  134. 8.2.01: Crystal Field Theory
  135. 8.2.02: Crystal Field Stabilization Energy
  136. 8.2.03: Non-octahedral Complexes
  137. 8.03: Crystal Field Theory and Magnetism
  138. 8.3.01: Jahn-Teller Distortions
  139. 8.3.02: Magnetism
  140. 8.3.03: Magnetic Moments of Transition Metals
  141. 8.3.04: Ferro- Ferri- and Antiferromagnetism
  142. 8.04: Ligand Field Theory
  143. 8.4.01: Ligand Field Theory
  144. 8.4.02: The Spectrochemical Series
  145. 8.4.03: Factors That Affect Ligand Field Splitting
  146. 8.4.04: Octahedral vs. Tetrahedral Geometries
  147. 8.05: Absorption Spectroscopy of Coordination Complexes
  148. 8.5.01: Absorption of Light
  149. 8.5.02: Colors of Coordination Complexes
  150. 8.5.03: Charge-Transfer Spectra
  151. 8.06: Tanabe Sugano Diagrams
  152. 8.6.01: Tanabe-Sugano Diagrams
  153. 8.6.02: Selection Rules
  154. 8.6.03: Applications of Tanabe-Sugano Diagrams
  155. 8.6.04: Tetrahedral Complexes
  156. 09: Reactions of Coordination Complexes
  157. 9.01: Substitution Reactions
  158. 9.1.01: Review of Reaction Thermodynamics and Kinetics
  159. 9.1.02: Introduction to Substitution Reactions
  160. 9.1.03: Ligand Substitution Mechanisms
  161. 9.1.04: Some Reasons for Differing Mechanisms
  162. 9.1.4.01: Dissociation
  163. 9.1.4.02: Associative Mechanisms
  164. 9.1.05: Thermodynamic Stability and Chelate Effect
  165. 9.1.06: Kinetic Lability
  166. 9.1.07: The Trans Effect
  167. 9.02: RedOx Reactions
  168. 9.2.01: Redox Mechanisms
  169. 9.2.02: Inner Sphere Electron Transfer
  170. 9.2.03: Outer Sphere Electron Transfer
  171. 9.03: Unit 9 Practice Problems
  172. 10: Organometallic Chemistry
  173. 10.01: Organometallic Complexes
  174. 10.1.01: Introduction to Organometallic Chemistry
  175. 10.1.02: Ligand Nomenclature and Classification
  176. 10.1.03: Survey of Common Organometallic Ligands
  177. 10.1.04: Electron Counting and the 18 Electron Rule
  178. 10.02: Organometallic Reactions
  179. 10.2.01: Ligand Dissociation and Substitution
  180. 10.2.02: Oxidative Addition
  181. 10.2.03: Reductive Elimination
  182. 10.2.04: Migratory Insertion- 12-Insertions
  183. 10.2.05: -Elimination Reactions
  184. 10.2.06: Organometallic Catalysts