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Chem 400: General Chemistry I
This is the Textmap constructed to follow the organization of Nivaldo Tro's "Chemistry: A Molecular Approach" general chemistry textbook.
- Publisher
- Sacramento City College
- Source
- LibreTexts
- License
- CC BY-NC-SA
- Language
- EN
- Category
- Basic Sciences
Contents· 260 sections
- 01: Matter, Measurement, and Problem Solving
- 1.1: Atoms and Molecules
- 1.2: The Scientific Approach to Knowledge
- 1.3: The Classification of Matter
- 1.4: Physical and Chemical Changes and Properties
- 1.5: Energy: A Fundamental Part of Physical and Chemical Change
- 1.6: The Units of Measurement
- 1.7: The Reliability of a Measurement
- 1.8: Solving Chemical Problems
- 1.E: Matter, Measurement, and Problem Solving (Exercises)
- 02: Atoms and ElementsEdit section
- 2.1: Brownian Motion: Evidence for Atoms
- 2.2: Early Ideas about the Building Blocks of Matter
- 2.3: Modern Atomic Theory and the Laws That Led to It
- 2.4: The Discovery of the Electron
- 2.5 The Structure of The Atom
- 2.6 Subatomic Particles: Protons, Neutrons, and Electrons in Atoms
- 2.7 Finding Patterns: The Periodic Law and the Periodic Table
- 2.8 Atomic Mass: The Average Mass of an Element’s Atoms
- 2.9 Molar Mass: Counting Atoms by Weighing Them
- 2.E : Atoms and Elements (Exercises)
- 03: Molecules, Compounds and Chemical Equations
- 3.01: Hydrogen, Oxygen, and Water
- 3.02: Chemical Bonds
- 3.03: Representing Compounds: Chemical Formulas and Molecular Modelspounds: Chemical Formulas and Molecular Models
- 3.04: An Atomic-Level Perspective of Elements and Compounds
- 3.05: Ionic Compounds: Formulas and Names
- 3.06: Molecular Compounds: Formulas and Names
- 3.07: Formula Mass and The Mole Concept for Compounds
- 3.08: Composition of Compounds
- 3.10: Determining a Chemical Formula from Experimental Data
- 3.11: Writing and Balancing Chemical Equations
- 3.12: Organic Compounds
- 3.E: Molecules, Compounds and Chemical Equations (Exercises)
- 04: Chemical Reactions and Aqueous Reactions
- 4.1: Global Warming and the Combustion of Fossil Fuels
- 4.2 Reaction Stoichiometry: How Much Carbon Dioxide?
- 4.3 Limiting Reactant, Theoretical Yield, and Percent Yield
- 4.4: Solution Concentration and Solution Stoichiomentry
- 4.5: Types of Aqueous Solutions and Solubility
- 4.6: Precipitation Reactions
- 4.7: Representing Aqueous Reactions: Molecular, Ionic, and Complete Ionic Equations
- 4.8: Acid-Base and Gas-Evolution Reactions
- 4.9: Oxidation-Reduction Reactions
- 05: Gases
- 5.02: Pressure: The Result of Particle Collisions
- 5.03: The Simple Gas Laws: Boyle’s Law, Charles’s Law and Avogadro’s Law
- 5.04: The Ideal Gas Law
- 5.05: Applications of the Ideal Gas Law: Molar Volume, Density and Molar Mass of a Gas
- 5.06: Mixtures of Gases and Partial Pressures
- 5.07: Gases in Chemical Reactions: Stoichiometry Revisited
- 5.08: Kinetic Molecular Theory: A Model for Gases
- 5.09: Mean Free Path, Diffusion, and Effusion of Gases
- 5.10: Real Gases: The Effects of Size and Intermolecular Forces
- 5.E: Gases (Exercises)
- 11.01: Water from Wells: Atmospheric Pressure at Work
- 06: Thermochemistry
- 6.01: Light the Furnace: The Nature of Energy and Its Transformations
- 6.02: The First Law of Thermodynamics
- 6.02: The Nature of Energy
- 6.03: Quantifying Heat and Work
- 6.04: Measuring ΔE for Chemical Reactions: Constant-Volume Calorimetry
- 6.05: Enthalpy: The Heat Evolved in a Chemical Reaction at Constant Pressure
- 6.06" Constant Pressure Calorimetry: Measuring DHrxn
- 6.07 Relationships Involving DHrxn
- 6.08: Enthalpies of Reaction from Standard Heats of Formation
- 6.09 Energy Use and The Environment
- 07: The Quantum-Mechanical Model of the Atom
- 7.1: Schrödinger's Cat
- 7.2: The Nature of Light
- 7.3: Atomic Spectroscopy and The Bohr Model
- 7.4: The Wavelength Nature of Matter
- 7.5: Quantum Mechanics and The Atom
- 7.6: The Shape of Atomic Orbitals
- 7.E: The Quantum-Mechanical Model of the Atom (Exercises)
- 08: Periodic Properties of the Elements
- 8.1: Nerve Signal Transmission
- 8.2: The Development of the Periodic Table
- 8.3: Electron Configurations: How Electrons Occupy Orbitals
- 8.4: Electron Configurations, Valence Electrons, and the Periodic Table
- 8.5: The Explanatory Power of the Quantum-Mechanical Model
- 8.6: Periodic Trends in the Size of Atoms and Effective Nuclear Charge
- 8.7: Ions- Configurations, Magnetic Properties, Radii, and Ionization Energy
- 8.8: Electron Affinities and Metallic Character
- 8.9: Examples of Periodic Chemical Behavior
- 8.E: Periodic Properties of the Elements (Exercises)
- 09: Chemical Bonding I: Drawing Lewis Structures
- 9.01: Bonding Models and AIDS Drugs
- 9.02: Types of Chemical Bonds
- 9.03: Representing Valance Electrons with Dots
- 9.04: Ionic Bonding
- 9.05: Covalent Bonding: Lewis Structure
- 9.06: Electronegativity and Bond Polarity
- 9.07: Lewis Structures
- 9.08: Resonance and Formal Charge
- 9.09: Exceptions to the Octet Rule
- 9.10: Bond Energies and Bond Lengths
- 9.11: Bonding in Metals
- 9.E: Chemical Bonding I (Exercises)
- 10: Chemical Bonding II: Molecular Shapes, Valance Bond Theory, and Molecular Orbital Theory
- 10.1: Artificial Sweeteners
- 10.2: VSEPR Theory: The Five Basic Shapes
- 10.3: VSPER Theory: The Effect of Lone Pairs
- 10.4: VSPER Theory: Predicting Molecular Geometries
- 10.5: Molecular Shape and Polarity
- 10.6: Valence Bond Theory: Orbital Overlap as a Chemical Bond
- 10.7: Valence Bond Theory: Hybridization of Atomic Orbitals
- 10.8: Molecular Orbital Theory: Electron Delocalization
- 11: Liquids, Solids, and Intermolecular Forces
- 11.01: Water in Zero Gravity
- 11.02: Solids, Liquids, and Gases: A Molecular Comparison
- 11.03: Intermolecular Forces: The Forces that Hold Condensed Phases Together
- 11.04: Intermolecular Forces in Action: Surface Tension, Viscosity, and Capillary Action
- 11.05: Vaporization and Vapor Pressure
- 11.06: Sublimation and Fusion
- 11.07: Heating Curve for Water
- 11.08: Phase Diagrams
- 11.09: Water: An Extraordinary Substance
- 12: Solids and Modern Materials
- 12.1: Discovery of Graphene
- 12.2: X-Ray Crystallography
- 12.3: Unit Cells and Basic Structures
- 12.4: The Fundamental Types of Crystalline Solids
- 12.5: The Structure of Ionic Solids
- 12.6: Network Covalent Atomic Solids: Carbon and Silicates
- 12.7: Ceramics, Cement, and Glass
- 12.8: Crystalline Solids: Band Theory
- 12.9: Polymers and Plastics
- 13: Solutions
- 13.1: Thirsty Solutions: Why You Should Not Drink Seawater
- 13.2: Types of Solutions and Solubility
- 13.3: Energetics of Solution Formation
- 13.4: Solution Equilibrium and Factors Affecting Solubility
- 13.5: Expressing Solution Concentration
- 13.6: Colligative Properties: Freezing Point Depression, Boiling Point Elevation, and Osmosis
- 13.7: The Colligative Properties of Strong Electrolyte Solutions
- 13.8: Colloids
- 13.E: Solutions (Exercises)
- 14: Chemical Kinetics
- 14.1: Catching Lizards
- 14.2: Rate of a Chemical Reaction
- 14.3: The Rate Law: The Effect of Concentration on Reaction Rate
- 14.4: The Integrated Rate Law: The Dependence of Concentration on Time
- 14.5: The Effect of Temperature on Reaction Rate
- 14.6: Reaction Mechanisms
- 14.7: Catalysis
- 15: Chemical Equilibrium
- 15.1: Fetal Hemoglobin and Equilibrium
- 15.2: The Concept of Dynamic Equilibrium
- 15.3: The Equilibrium Constant (K)
- 15.4: Expressing the Equilibrium Constant in Terms of Pressure
- 15.5: Calculating the Equilibrium Constant From Measured Equilibrium Concentrations
- 15.5: Heterogenous Equilibria: Reactions Involving Solids and Liquids
- 15.7: The Reaction Quotient: Predicting the Direction of Change
- 15.8: Finding Equilibrium Concentrations
- 15.9: Le Châtelier’s Principle: How a System at Equilibrium Responds to Disturbances
- 16: Acids and Bases
- 16.01: Heartburn
- 16.02: The Nature of Acids and Bases
- 16.03: Definitions of Acids and Bases
- 16.04: Acid Strength and the Acid Dissociation Constant (Ka)
- 16.05: Autoionization of Water and pH
- 16.06: Finding the [H3O ] and pH of Strong and Weak Acid Solutions
- 16.07: Base Solutions
- 16.08: The Acid-Base Properties of Ions and Salts
- 16.09: Polyprotic Acids
- 16.10: Acid Strength and Molecular Structure
- 16.11: Lewis Acids and Bases
- 16.12: Acid rain
- 17: Aqueous Ionic Equilibrium
- 17.1: The Danger of Antifreeze
- 17.2: Buffers: Solutions That Resist pH Change
- 17.3: Buffer Effectiveness: Buffer Capacity and Buffer Range
- 17.4: Titrations and pH Curves
- 17.5: Solubility Equilibria and the Solubility Product Constant
- 17.6: Precipitation
- 17.7: Qualitative Chemical Analysis
- 17.8: Complex Ion Equilibria
- 17.E: Aqueous Ionic Equilibrium (Exercises)
- 18: Gibbs Energy and Thermodynamics
- 18.01: Nature’s Heat Tax: You Can’t Win and You Can’t Break Even
- 18.02: Spontaneous and Nonspontaneous Processes
- 18.03: Entropy and the Second Law of Thermodynamics
- 18.04: Entropy Changes Associate with State Changes
- 18.05: Heat Transfer and Changes in the Entropy of the Surroundings
- 18.06: Gibbs Energy
- 18.07: Entropy Changes in Chemical Reactions
- 18.08: Gibbs Energy Changes in Chemical Reactions
- 18.09: Gibbs Energy Changers for Non-Standard States
- 18.10: Gibbs Energy and Equilibrium
- 19: Electrochemistry
- 19.1: Pulling the Plug on the Power Grid
- 19.2: Balancing Oxidation-Reduction Equations
- 19.3: Voltaic (or Galvanic) Cells: Generating Electricity from Spontaneous Chemical Reactions
- 19.4: Standard Reduction Potentials
- 19.5: Cell Potential, Gibbs Energy, and the Equilibrium Constant
- 19.6: Cell Potential and Concentration
- 19.7: Batteries: Using Chemistry to Generate Electricity
- 19.8: Electrolysis: Driving Non-spontaneous Chemical Reactions with Electricity
- 19.9: Corrosion: Undesirable Redox Reactions
- 20: Radioactivity and Nuclear Chemistry
- 20.01: Diagnosing Appendicitis
- 20.02: The Discovery of Radioactivity
- 20.03: Types of Radioactivity
- 20.04: The Valley of Stability: Predicting the Type of Radioactivity
- 20.05: Detecting Radioactivity
- 20.06: The Kinetics of Radioactive Decay and Radiometric Dating
- 20.07: The Discovery of Fission: The Atomic Bomb and Nuclear Power
- 20.08: Converting Mass to Energy: Mass Defect and Nuclear Binding Energy
- 20.09: Nuclear Fusion: The Power of the Sun
- 20.10: Nuclear Transmutation and Transuranium Elements
- 20.11: The Effects of Radiation on Life
- 20.12: Radioactivity in Medicine and Other Applications
- 21: Organic Chemistry
- 21.01: Fragrances and Odor
- 21.02: Carbon: Why It Is Unique
- 21.03: Hydrocarbons: Compounds Containing Only Carbon and Hydrocarbon
- 21.04: Alkanes: Saturated Hydrocarbons
- 21.05: Alkenes and Alkynes
- 21.06: Hydrocarbon Reactions
- 21.07: Aromatic Hydrocarbons
- 21.08: Functional Groups
- 21.09: Alcohols
- 21.10: Aldehydes and Ketones
- 21.11: Carboxylic Acids and Esters
- 21.12: Ethers
- 21.13: Amines
- 22: Biochemistry
- 22.1: Diabetes and the Synthesis of Human Insulin
- 22.2: Lipids
- 22.3: Carbohydrates
- 22.4: Proteins and Amino Acids
- 22.5: Protein Structure
- 22.6: Nucleic Acids: Blueprints for Proteins
- 22.7: DNA Replication, the Double Helix, and Protein Synthesis
- 23: Chemistry of the Nonmetals
- 23.1: Insulated Nanowires
- 23.2: The Main-Group Elements: Bonding and Properties
- 23.3: The Most Common Matter: Silicates
- 23.4: Boron and Its Amazing Structures
- 23.5: Carbon, Carbides, and Carbonates
- 23.6: Nitrogen and Phosphorus: Essential Elements for Life
- 23.7: Oxygen
- 23.8: Sulfur: A Dangerous and Useful Element
- 23.9: Halogens: Reactive Chemicals with High Electronegativity
- 23.E: Chemistry of the Nonmetals (Exercises)
- 24: Metals and Metallurgy
- 24.1: Vanadium: A Problem and an Opportunity
- 24.2: The General Properties and Natural Distribution of Metals
- 24.3: Metallurgical Processes
- 24.4: Metal Structures and Alloys
- 24.5: Sources, Properties, and Products of Some of the 3d Transition Metals
- 25: Transition Metals and Coordination Compounds
- 25.1: The Colors of Rubies and Emeralds
- 25.2: Properties of Transition Metals
- 25.3: Coordination Compounds
- 25.4: Structure and Isomerization
- 25.5: Bonding in Coordinate Compounds
- 25.6: Applications of Coordination Compounds
- 25.E: Transition Metals and Coordination Compounds (Exercises)