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CHM 118: Advanced General Chemistry

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CHM 118: Advanced General Chemistry

This course is for students with a very strong background in chemistry. The elementary theories of stoichiometry, atomic structure, bonding, structure, energetics and reactions are quickly reviewed. The major portions of the course involve a detailed analysis of atomic theory and bonding from an orbital concept, an examination of the concepts behind thermodynamic arguments in chemical systems, and an investigation of chemical reactions and kinetics.

Chemistry
Author
Alexandra Strom
Publisher
Smith College
Source
LibreTexts
Language
EN
Category
Basic Sciences
Read online Download PDF (open licence)
Contents· 133 sections
  1. 01: Radioactivity and Nuclear Chemistry
  2. 1.01: The Discovery of Radioactivity
  3. 1.02: Types of Radioactivity
  4. 1.03: The Valley of Stability- Predicting the Type of Radioactivity
  5. 1.04: Detecting Radioactivity
  6. 1.05: The Discovery of Fission- The Atomic Bomb and Nuclear Power
  7. 1.06: Converting Mass to Energy- Mass Defect and Nuclear Binding Energy
  8. 1.07: Nuclear Fusion - The Power of the Sun
  9. 1.08: Nuclear Transmutation and Transuranium Elements
  10. 1.09: The Effects of Radiation on Life
  11. 1.10: Radioactivity in Medicine and Other Applications
  12. 1.11: Key Terms
  13. 1.12: Key Equations
  14. 1.13: Summary
  15. 1.14: Exercises
  16. 02: Chemical Bonding and Molecular Geometry
  17. 2.01: Introduction
  18. 2.02: Ionic Bonding
  19. 2.03: Covalent Bonding
  20. 2.04: Lewis Symbols and Structures
  21. 2.05: Introduction to Formal Charges and Resonance
  22. 2.06: Molecular Structure and Polarity
  23. 2.07: Key Terms
  24. 2.08: Key Equations
  25. 2.09: Summary
  26. 2.10: Exercises
  27. 03: Advanced Theories of Covalent Bonding
  28. 3.01: Introduction
  29. 3.02: Molecular Orbital Theory
  30. 3.03: Valence Bond Theory
  31. 3.04: Hybrid Atomic Orbitals
  32. 3.05: Multiple Bonds formed between Hybridized Atoms
  33. 3.06: Resonance
  34. 3.07: Rules for Resonance Forms
  35. 3.08: Resonance Effects on Hybridization and Bonding
  36. 3.09: Hybridized Orbital Energy Diagrams
  37. 3.10: Key Terms
  38. 3.11: Summary
  39. 3.12: Exercises
  40. 04: Thermochemistry
  41. 4.01: Introduction
  42. 4.02: Energy Basics
  43. 4.03: Calorimetry
  44. 4.04: Enthalpy
  45. 4.05: Strengths of Ionic and Covalent Bonds
  46. 4.06: Key Terms
  47. 4.07: Key Equations
  48. 4.08: Summary
  49. 4.09: Exercises
  50. 05: Thermodynamics
  51. 5.01: Introduction
  52. 5.02: Spontaneity
  53. 5.03: Entropy
  54. 5.04: The Second and Third Laws of Thermodynamics
  55. 5.05: Free Energy
  56. 5.06: Key Terms
  57. 5.07: Key Equations
  58. 5.08: Summary
  59. 5.09: Exercises
  60. 06: Fundamental Equilibrium Concepts
  61. 6.01: Introduction
  62. 6.02: Chemical Equilibria
  63. 6.03: Equilibrium Constants
  64. 6.04: Shifting Equilibria - Le Chateliers Principle
  65. 6.05: Equilibrium Calculations
  66. 6.06: Free Energy Equilibria
  67. 6.07: Key Terms
  68. 6.08: Key Equations
  69. 6.09: Summary
  70. 6.10: Exercises
  71. 07: Acid-Base Equilibria
  72. 7.01: Introduction
  73. 7.02: Brnsted-Lowry Acids and Bases
  74. 7.03: pH and pOH
  75. 7.04: Relative Strengths of Acids and Bases
  76. 7.05: Hydrolysis of Salt
  77. 7.06: Polyprotic Acids
  78. 7.07: Buffers
  79. 7.08: Acid-Base Titrations
  80. 7.09: Key Terms
  81. 7.10: Key Equations
  82. 7.11: Summary
  83. 7.12: Exercises
  84. 08: Kinetics
  85. 8.01: Introduction
  86. 8.02: Chemical Reaction Rates
  87. 8.03: Factors Affecting Reaction Rates
  88. 8.04: Rate Laws
  89. 8.05: Integrated Rate Laws
  90. 8.06: Collision Theory
  91. 8.07: Reaction Mechanisms
  92. 8.08: Catalysis
  93. 8.09: Key Terms
  94. 8.10: Key Equations
  95. 8.11: Summary
  96. 8.12: Exercises
  97. 09: Electrochemistry
  98. 9.01: Introduction
  99. 9.02: Review of Redox Chemistry
  100. 9.03: Galvanic Cells
  101. 9.04: Electrode and Cell Potentials
  102. 9.05: Potential Free Energy and Equilibrium
  103. 9.06: Batteries and Fuel Cells
  104. 9.07: Corrosion
  105. 9.08: Electrolysis
  106. 9.09: Key Terms
  107. 9.10: Key Equations
  108. 9.11: Summary
  109. 9.12: Exercises
  110. 10: Appendices
  111. 10.01: Appendix A- The Periodic Table
  112. 10.02: Appendix B- Essential Mathematics
  113. 10.03: Appendix C- Units and Conversion Factors
  114. 10.04: Appendix D- Fundamental Physical Constants
  115. 10.05: Appendix E- Water Properties
  116. 10.06: Appendix F- Composition of Commercial Acids and Bases
  117. 10.07: Appendix G- Standard Thermodynamic Properties for Selected Substances
  118. 10.08: Appendix H- Ionization Constants of Weak Acids
  119. 10.09: Appendix I- Ionization Constants of Weak Bases
  120. 10.10: Appendix J- Solubility Products
  121. 10.11: Appendix K- Formation Constants for Complex Ions
  122. 10.12: Appendix L- Standard Electrode (Half-Cell) Potentials
  123. 10.13: Appendix M- Half-Lives for Several Radioactive Isotopes
  124. 10.14: Answer Keys
  125. 10.14.01: Chapter 1 - Radioactivity and Nuclear Chemistry
  126. 10.14.02: Chapter 2 - Chemical Bonding and Molecular Geometry
  127. 10.14.03: Chapter 3 - Advanced Theories of Covalent Bonding
  128. 10.14.04: Chapter 4 - Thermochemistry
  129. 10.14.05: Chapter 5 - Thermodynamics
  130. 10.14.06: Chapter 6 - Fundamental Equilibrium Concepts
  131. 10.14.07: Chapter 7 - Acid-Base Equilibria
  132. 10.14.08: Chapter 8 - Kinetics
  133. 10.14.09: Chapter 9 - Electrochemistry