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Fundamental Organic Chemistry I

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Fundamental Organic Chemistry I

Chemistry
Publisher
LibreTexts
Source
LibreTexts
Language
EN
Category
Basic Sciences
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Contents· 120 sections
  1. 01: Intro to Chemical Structure and Resonance
  2. 1.01: Drawing Chemical Structures
  3. 1.02: Electron-Dot Model of Bonding - Lewis Structures
  4. 1.03: VSPER Theory- The Effect of Lone Pairs
  5. 1.04: Electronegativity and Bond Polarity (Review)
  6. 1.05: Resonance
  7. 1.06: Molecular Orbitals and Covalent Bonding
  8. 1.07: Hybrid Orbitals- Bonding in Complex Molecules and Practice Problems
  9. 02: Alkanes
  10. 2.01: Chemical Properties of Alkanes
  11. 2.02: Physical Properties of Alkanes
  12. 2.03: Nomenclature of Alkanes
  13. 2.04: Nomenclature of Cycloalkanes
  14. 2.05: Practice - Alkane Nomenclature
  15. 2.06: Ethane Conformers
  16. 2.07: Gibbs Free Energy (review)
  17. 2.08: Enthalpy Changes in Reactions
  18. 2.09: Entropy Changes in Chemical Reactions
  19. 2.10: Activation Energy and Rate
  20. 03: Acids Bases and Arrow Pushing
  21. 3.01: Acids and Bases - The Brønsted-Lowry Definition
  22. 3.02: Acids and Bases - The Lewis Definition
  23. 3.03: Classification of Reagents as Electrophiles and Nucleophiles. Acids and Bases
  24. 3.04: Using Curved Arrows in Polar Reaction Mechanisms
  25. 3.05: Acid Strength and (pK a)
  26. 3.06: A Summary of the Factors that Determine Acid Strength
  27. 3.07: Organic Acids and Bases
  28. 04: Introduction to Alkenes
  29. 4.01: The (pi) Bond
  30. 4.02: Nomenclature of Alkenes
  31. 4.03: Degree of Unsaturation
  32. 4.04: Electrophilic Addition Reactions of Alkenes
  33. 4.05: Carbocation Structure and Stability
  34. 4.06: Carbocation Rearrangements
  35. 4.07: Markovnikov Addition
  36. 05: Addition Reactions of Alkenes
  37. 5.01: Electrophilic Addition of Hydrogen Halides
  38. 5.02: Addition of Strong Brnsted Acids
  39. 5.03: Electrophilic Addition of Halogens to Alkenes
  40. 5.04: Hydration of Alkenes
  41. 5.05: Formation of alcohols from alkenes
  42. 5.06: Catalytic Hydrogenation
  43. 5.07: Hydration- Oxymercuration-Demercuration
  44. 5.08: Hydration- Hydroboration-Oxidation
  45. 5.09: Oxidative Cleavage of Alkenes
  46. 5.10: Free Radicals
  47. 5.11: Addition of Radicals to Alkenes
  48. 5.12: Anti-Markovnikov Product Formation
  49. 5.13: Homolytic Cleavage and Bond Dissociation Energies
  50. 5.14: Polymerization of Alkenes
  51. 06: Principles of Stereochemistry
  52. 6.01: Chirality and Stereoisomers
  53. 6.02: R-S Sequence Rules
  54. 6.03: Optical Activity
  55. 6.04: Optical Activity - more detail
  56. 6.05: Racemic Mixtures and the Resolution of Enantiomers
  57. 6.06: Diastereomers
  58. 6.07: Diastereomers - more detail
  59. 6.08: Meso Compounds
  60. 07: Cyclic Compounds - Stereochemistry of Reactions
  61. 7.01: Ring Strain and the Structure of Cycloalkanes
  62. 7.02: Cycloalkanes and Ring Strain
  63. 7.03: Cyclohexane Conformations
  64. 7.04: Conformations of Monosubstituted Cyclohexanes
  65. 7.05: Conformations of Disubstituted Cyclohexanes
  66. 7.06: Polycyclic Alkanes
  67. 7.07: Carbocyclic Products in Nature
  68. 7.08: Steroids
  69. 08: Introduction to Alkyl Halides Alcohols Ethers Thiols and Sulfides
  70. 8.01: Alkyl Halides
  71. 8.02: Haloalkanes
  72. 8.2.01: Alkyl Halide Occurrence
  73. 8.03: Nomenclature of Alcohols
  74. 8.3.01: Nomenclature of Alcohols
  75. 8.04: Thiols (Mercaptans)
  76. 8.05: Nomenclature of Ethers
  77. 8.06: Solvents
  78. 8.6.01: Boiling Points
  79. 8.6.02: Solvent-Solutes
  80. 8.07: Acidity of Alcohols and Phenols
  81. 8.08: Grignard and Organolithium Reagents
  82. 8.09: Grignard Reagents
  83. 09: The Chemistry of Alkyl Halides
  84. 9.01: An Overview of Nucleophilic Substitution
  85. 9.02: Elimination Reactions
  86. 9.03: Rate Laws in Nucleophilic Substitution
  87. 9.04: Reaction Rates and Rate Laws
  88. 9.05: The SN2 Reaction
  89. 9.06: E2 Elimination
  90. 9.07: SN1 Reaction
  91. 9.7.01: 6.06.1 Kinetics, Stereochemistry and Energy Diagram
  92. 9.08: E1 Eliminations
  93. 9.09: Comparison of SN2 and SN1
  94. 9.10: Comparing E1 and E2
  95. 9.11: Determining SN2, SN¬1, E2 or E1
  96. 9.12: Carbenes
  97. 9.13: Cyclopropane Synthesis
  98. 10: The Chemistry of Alcohols and Thiols
  99. 10.01: Dehydration Reactions of Alcohols
  100. 10.02: Reactions of Alcohols with Hydrohalic Acids
  101. 10.03: Converting an Alcohol to a Sulfonate Ester
  102. 10.04: Oxidation and Reduction in Organic Chemistry
  103. 10.05: Oxidation of Alcohols
  104. 10.06: The Formation of Carboxylic Acids
  105. 10.07: Nicotinamide Adenine Dinucleotide (NAD)
  106. 10.08: Dehydrogenases
  107. 10.09: Prochirality
  108. 10.10: Thiols and Sulfides
  109. 10.11: Nucleophilicity of Sulfur Compounds
  110. 10.12: Redox Reactions of Thiols and Disulfides
  111. 10.13: An Introduction to Organic Synthesis
  112. 11: The Chemistry of Ethers Epoxides Glycols and Sulfides
  113. 11.01: Williamson Ether Synthesis
  114. 11.02: Synthesis of Epoxides
  115. 11.03: Acidic Cleavage of Ethers
  116. 11.04: Opening of Epoxides
  117. 11.05: Dihydroxylation of Alkenes
  118. 11.06: Periodate cleavage of 1,2-diols (glycols)
  119. 11.07: Epoxidation
  120. 11.08: Sharpless Epoxidation