Nguồn ngoài

Chem 2444: (Second Semester Organic Chemistry) UConn

Chemistry

Nhà xuất bản: LibreTexts
Nguồn: LibreTexts
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

Đọc trực tuyến Tải PDF (nguồn mở)

Mục lục· 131 mục

01: Structure Determination (Mass Spectrometry IR and UV-Vis Spectroscopy)
1.01: Mass Spectrometry of Small Molecules - Magnetic-Sector Instruments
1.02: Interpreting Mass Spectra
1.03: Mass Spectrometry of Some Common Functional Groups
1.04: Spectroscopy and the Electromagnetic Spectrum
1.05: Infrared Spectroscopy
1.06: Interpreting Infrared Spectra
1.07: Infrared Spectra of Some Common Functional Groups
1.08: Structure Determination in Conjugated Systems- Ultraviolet Spectroscopy
1.09: Interpreting Ultraviolet Spectra- The Effect of Conjugation
1.S: Conjugated Compounds and Ultraviolet Spectroscopy (Summary)
02: Nuclear Magnetic Resonance
2.01: Hydrogen Nuclear Magnetic Resonance
2.02: Using NMR Spectra to Analyze Molecular Structure- The Proton Chemical Shift
2.03: Integration
2.04: Spin-Spin Splitting- The Effect of Nonequivalent Neighboring Hydrogens
2.05: Carbon-13 Nuclear Magnetic Resonance
03: Conjugated Pi-Systems and Aromaticity
3.01: Stability of Conjugated Dienes- Molecular Orbital Theory
3.02: Electrophilic Additions to Conjugated Dienes- Allylic Carbocations
3.03: Kinetic vs. Thermodynamic Control of Reactions
3.04: Naming Aromatic Compounds
3.05: Structure and Stability of Benzene
3.06: Aromaticity and the Huckel 4n 2 Rule
3.07: Aromatic Ions
3.08: Aromatic Heterocycles- Pyridine and Pyrrole
3.09: Polycyclic Aromatic Compounds
3.10: Spectroscopy of Aromatic Compounds
3.S: Benzene and Aromaticity (Summary)
04: Electrophilic Aromatic Substitution Reactions
4.01: Chemistry of Benzene - Electrophilic Aromatic Substitution
4.1.01: Introduction
4.1.02: Electrophilic Aromatic Substitution Reactions - Bromination
4.1.03: Other Aromatic Substitutions
4.1.04: Alkylation and Acylation of Aromatic Rings - The Friedel-Crafts Reaction
4.1.05: Substituent Effects in Substituted Aromatic Rings
4.1.06: An Explanation of Substituent Effects
4.1.07: Trisubstituted Benzenes - Additivity of Effects
4.1.08: Reduction of Aromatic Compounds
4.1.09: Synthesis of Polysubstituted Benzenes
4.1.S: Chemistry of Benzene - Electrophilic Aromatic Substitution (Summary)
05: Reactions at the Allylic and Benzylic Positions
5.01: Reactivity at the Phenylmethyl (Benzyl) Carbon- Benzylic Resonance Stabilization
5.02: Oxidation of Aromatic Compounds
5.03: Benzylic Oxidations and Reductions
06: Aryl Halides and Nucleophilic Aromatic Substitution Reactions
6.01: Nucleophilic Aromatic Substitution
6.02: Preparation of Phenols- Nucleophilic Aromatic Substitution
6.03: Arenediazonium Salts
6.04: Benzyne
07: Review of RedOx Reactions
7.01: Oxidation-Reduction Reactions of Organic Compounds- An Overview
7.02: Reduction Reactions
7.03: Chemoselective Reactions
7.04: Oxidation of Alcohols
7.05: Oxidation of Aldehydes and Ketones
7.06: Oxidation of Alkenes to 12 Diols
08: Reactions of Carboxylic Acid Derivatives
8.01: Structure and Properties of Carboxylic Acids
8.02: Substituent Effects on Acidity
8.03: Preparing Carboxylic Acids
8.04: Nucleophilic Acyl Substitution Reactions
8.05: Nucleophilic Acyl Substitution Reactions of Carboxylic Acids
8.06: Chemistry of Acid Halides
8.07: Chemistry of Acid Anhydrides
8.08: Chemistry of Esters
8.09: Chemistry of Amides
8.10: Spectroscopy of Carboxylic Acid Derivatives
09: Ch. 9- Reactions of Ketones and Aldehydes
9.01: Naming the Aldehydes and Ketones
9.02: Structure of the Carbonyl Group
9.03: Spectroscopic Properties of Aldehydes and Ketones
9.04: Reactivity of the Carbonyl Group- Mechanisms of Addition
9.05: Addition of Water to Form Hydrates
9.06: Addition of Alcohols to Form Hemiacetals and Acetals
9.07: Acetals as Protecting Groups
9.08: Nucleophilic Addition of Ammonia and Its Derivatives
9.09: Deoxygenation of the Carbonyl Group
9.10: Addition of Hydrogen Cyanide to Give Cyanohydrins
9.11: Addition of Phosphorus Ylides- The Wittig Reaction
9.12: Nucleophilic Addition of Hydride and Grignard Reagents- Alcohol Formation
9.13: Nucleophilic Addition of Amines- Imine and Enamine Formation
9.14: Nucleophilic Addition of Hydrazine - The Wolff-Kishner Reaction
10: Reactions at the Alpha-Carbon (Alpha Substitutions)
10.01: Keto-Enol Tautomerism
10.02: Reactivity of Enols- The Mechanism of Alpha-Substitution Reactions
10.03: Alpha Halogenation of Aldehydes and Ketones
10.04: Alpha Bromination of Carboxylic Acids
10.05: Acidity of Alpha Hydrogen Atoms- Enolate Ion Formation
10.06: Reactivity of Enolate Ions
10.07: Alkylation of Enolate Ions
10.08: Carbonyl Condensations - The Aldol Reaction
10.09: Dehydration of Aldol Products - Synthesis of Enones
10.10: The Claisen Condensation Reaction
10.11: Mixed Claisen Condensations
10.12: Conjugate Carbonyl Additions - The Michael Reaction
10.13: The Robinson Annulation Reaction
11: Chemistry of Amines
11.01: Naming Amines
11.02: Structure and Properties of Amines
11.03: Basicity of Amines
11.04: Basicity of Arylamines
11.05: Synthesis of Amines
11.06: Reactions of Amines
11.07: Heterocyclic Amines
11.08: Quaternary Ammonium Salts- Hofmann Elimination
12: Carbohydrates and Sugars
12.01: Classification of Carbohydrates
12.02: Fischer Projections
12.03: D L Sugars
12.04: Configurations of Aldoses
12.05: Anomers
13: Nucleic Acids
13.01: Biosynthesis of Proteins- Nucleic Acids
13.02: Nucleotides and Nucleic Acids
13.03: Base Pairing in DNA - The Watson-Crick Model
14: Amino Acids
14.01: Structure and Properties of Amino Acids
14.02: Synthesis of Amino Acids- A Combination of Amine and Carboxylic Acid Chemistry
14.03: Determination of Primary Structure- Amino Acid Sequencing
14.04: Amino Acids the Henderson-Hasselbalch Equation and Isoelectric Points
15: Coupling Reactions
15.01: Organometallic Coupling Reactions
15.02: 12- and 14-Additions of Organometallic Reagents
16: Pericyclic Reactions
16.01: Molecular Orbitals and Orbital Symmetry
16.02: Cycloaddition Reactions
16.03: The Diels-Alder Cycloaddition Reaction
16.04: Characteristics of the Diels-Alder Reaction
16.05: An Electrocyclic Reaction of the Benzene Ring- The Claisen Rearrangement
16.06: Sigmatropic Rearrangements