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Organometallic Chemistry

Organometallic (OM) chemistry is the study of compounds containing, and reactions involving, metal-carbon bonds. The metal-carbon bond may be transient or temporary, but if one exists during a reaction or in a compound of interest, we’re squarely in the domain of organometallic chemistry. Despite the denotational importance of the M-C bond, bonds between metals and the other common elements of organic chemistry also appear in OM chemistry: metal-nitrogen, metal-oxygen, metal-ha

Inorganic Chemistry Chemistry

Tác giả: Michael Evans
Nhà xuất bản: Georgia Tech
Nguồn: LibreTexts
Giấy phép: CC BY-NC-SA
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

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Mục lục· 35 mục

01: Introduction to Organometallic Chemistry
1.01: Resources for Organometallic Chemistry
1.02: What is Organometallic Chemistry
02: Organometallic Ligands
2.01: Carbenes
2.02: Carbon Monoxide
2.03: Complexes
2.04: Dative Ligands of N O and S
2.05: Metal Alkyls
2.06: Metal Hydrides
2.07: N-heterocyclic Carbenes
2.08: Odd-numbered Systems
2.09: Phosphines
2.10: Systems
03: Structural Fundamentals
3.01: Ligand Field Theory and Frontier Molecular Orbital Theory
3.02: Open Coordination Site
3.03: Periodic Trends of the Transition Metals
3.04: Predicting the Geometry of Organometallic Complexes
3.05: Simplifying the Organometallic Complex (Part 1)
3.06: Simplifying the Organometallic Complex (Part 2)
3.07: Simplifying the Organometallic Complex (Part 3)
04: Fundamentals of Organometallic Chemistry
4.01: -Elimination Reactions
4.02: Associative Ligand Substitution
4.03: Dissociative Ligand Substitution Reactions
4.04: Ligand substitution
4.05: Migratory Insertion- 12-Insertions
4.06: Migratory Insertion- Introduction and CO Insertions
4.07: Oxidative Addition- General Ideas
4.08: Oxidative Addition of Non-polar Reagents
4.09: Oxidative Addition of Polar Reagents
4.10: Quirky Ligand Substitutions
4.11: Reductive Elimination- General Ideas
4.12: The trans cis Effects and Influences