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Chem 107A: Physical Chemistry for Life Scientists

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Chem 107A: Physical Chemistry for Life Scientists

Introductory development of classical and statistical thermodynamics including equilibrium processes and solutions of both non-electrolytes and electrolytes. The thermodynamic basis of electrochemistry and membrane potentials.

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Mục lục· 58 mục
  1. 1: Introduction to Physical Chemistry
  2. 1.1: Nature of Physical Chemistry
  3. 1.2: Units
  4. 1.3: Atomic Mass Molecular Mass and the Chemical Mole
  5. 2: Properties of Gases
  6. 2.1: Some Definitions
  7. 2.2: An Operational Definition of Temperature
  8. 2.3: Ideal Gases
  9. 2.4: Real Gases
  10. 2.5: Condensation of Gases and the Critical State
  11. 2.6: Kinetic Theory of Gases
  12. 2.7: The Maxwell Distribution Laws
  13. 2.8: Molecular Collisions and the Mean Free Path
  14. 2.9: Graham's Laws of Diffusion and Effusion
  15. 3: First Law of Thermodynamics
  16. 3.1: Work and Heat
  17. 3.2: The First Law of Thermodynamics
  18. 3.4: Gas Expansions
  19. 3.5: Calorimetry
  20. 3.6: Thermochemistry
  21. 3.7: Bond Energies and Bond Enthalpies
  22. 4: Second Law of Thermodynamics
  23. 4.01: Spontaneous Processes
  24. 4.02: Entropy
  25. 4.03: The Second Law of Thermodynamics
  26. 4.04: Entropy Changes
  27. 4.05: The Third Law of Thermodynamics
  28. 4.06: Gibbs Energy
  29. 4.07: Standard Molar Gibbs Energy of Formation (\(\Delta{f^o}\))
  30. 4.08: Dependence of Gibbs Energy on Temperature and Pressure
  31. 4.09: Phase Equilibria
  32. 4.10: Thermodynamics of Rubber Elasticity
  33. 5: Solutions
  34. 5.01: Concentration Units
  35. 5.02: Partial Molar Quantities
  36. 5.03: The Thermodynamics of Mixing
  37. 5.04: Binary Mixtures of Volatile Liquids
  38. 5.05: Real Solutions
  39. 5.06: Colligative Properties
  40. 5.07: Electrolyte Solutions
  41. 5.08: Ionic Activity
  42. 5.09: Colligative Properties of Electrolyte Solutions
  43. 5.10: Biological Membranes
  44. 6: Chemical Equilibrium
  45. 6.1: Chemical Equilibrium in Gaseous Systems
  46. 6.2: Reactions in Solutions
  47. 6.3: Heterogeneous Equilibria
  48. 6.4: The Influence of Temperature, Pressure, and Catalysts on the Equilibrium Constant
  49. 6.5: Binding of Ligands and Metal Ions to Macromolecules
  50. 6.6: Bioenergetics
  51. 7: Electrochemistry
  52. 7.1: Electrochemical Cells
  53. 7.2: Single Electrode Potentials
  54. 7.3: Thermodynamics of Electrochemical Cells
  55. 7.4: Types of Electrochemical Cells
  56. 7.5: Applications of EMF Measurements
  57. 7.6: Biological Oxidation
  58. 7.7: Membrane Potential