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CHEM 361: Inorganic Chemistry

Chemistry

Tác giả: Lori Ann Watson
Nhà xuất bản: Earlham College
Nguồn: LibreTexts
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

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Mục lục· 175 mục

01: Intro Review and Effective Nuclear Charge
1.01: Introduction to Inorganic Chemistry
1.1.01: What is Inorganic Chemistry
1.1.02: Inorganic vs Organic Chemistry
1.1.03: History of Inorganic Chemistry
1.02: Atomic Structure
1.2.01: Historical Development of Atomic Theory
1.2.1.01: The Periodic Table
1.2.1.02: Discovery of Subatomic Particles and the Bohr Atom
1.2.02: The Schrodinger equation particle in a box and atomic wavefunctions
1.2.2.01: Particle in a Box
1.2.2.02: Quantum Numbers and Atomic Wave Functions
1.2.2.03: Aufbau Principle
1.2.2.04: Shielding
1.2.03: Periodic Properties of Atoms
1.2.3.01: Ionization energy
1.2.3.02: Electron Affinity
1.2.3.03: Covalent and Ionic Radii
1.2.3.04: Hard and Soft Acids and Bases
1.2.3.4.01: Quantitative Measures of Hardness Softness and Acid-Base Interactions from a Hard Soft Acid-Base Principle perspective involve orbital energies and or apportioning acid-base bonding in terms of electrostatic and covalent factors
1.2.3.4.02: Hard-Hard and Soft-Soft preferences may be explained and quantified in terms of electrostatic and covalent and electronic stabilization on the stability of Lewis acid-base adducts
1.03: Simple Bonding Theory
1.3.01: Lewis Electron-Dot Diagrams
1.3.1.01: Resonance
1.3.1.02: Breaking the octet rule with higher electron counts (hypervalent atoms)
1.3.1.03: Formal Charge
1.3.1.04: Lewis fails to predict unusual cases- Boron and Beryllium
1.3.02: Valence Shell Electron-Pair Repulsion
1.3.2.01: Lone Pair Repulsion
1.3.2.02: Multiple Bonds
1.3.2.03: Electronegativity and Atomic Size Effects
1.3.2.04: Ligand Close Packing
1.3.03: Molecular Polarity
1.3.04: Hydrogen Bonding
1.3.05: Valence Bond Theory
1.3.06: Hybrid Atomic Orbitals
02: Molecular Symmetry and Point Groups
2.01: Symmetry Elements and Operations
2.02: Point Groups
2.2.01: Groups of Low and High Symmetry
2.2.02: Other Groups
2.03: Properties and Representations of Groups
2.3.01: Matrices
2.3.02: Representations of Point Groups
2.3.03: Character Tables
2.04: Examples and Applications of Symmetry
2.4.01: Molecular Vibrations
2.4.02: Chirality
03: Molecular Orbital Theory
3.01: Prelude to Molecular Orbital Theory
3.02: Formation of Molecular Orbitals from Atomic Orbitals
3.2.01: Molecular Orbitals from s Orbitals
3.2.02: Molecular Orbitals from p Orbitals
3.2.03: Molecular orbitals from d orbitals
3.2.04: Nonbonding Orbitals and Other Factors
3.03: Homonuclear Diatomic Molecules
3.3.01: Molecular Orbitals
3.3.02: Orbital Mixing
3.3.03: Diatomic Molecules of the First and Second Periods
3.3.04: Photoelectron Spectroscopy
3.04: Heteronuclear Diatomic Molecules
3.4.01: Polar bonds
3.4.02: Ionic Compounds and Molecular Orbitals
3.05: Larger (Polyatomic) Molecules
3.5.01: Bifluoride anion
3.5.02: Carbon Dioxide
3.5.03: HO
3.5.04: NH
3.5.05: CO (Revisted with Projection Operators)
3.5.06: BF
04: d Block Chemistry
4.01: Coordination Chemistry I - Structure and Isomers
4.1.01: History
4.1.02: Nomenclature and Ligands
4.1.03: Isomerism
4.1.04: Coordination Numbers and Structures
4.02: Coordination Chemistry II - Bonding
4.2.01: Evidence for Electronic Structures
4.2.1.01: Thermodynamic Data
4.2.1.02: Magnetic Susceptibility
4.2.1.03: Electronic Spectra
4.2.1.04: Coordination Number and Molecular Shapes
4.2.02: Bonding Theories
4.2.2.01: Crystal Field Theory
4.2.2.1.01: Crystal Field Theory
4.2.2.1.02: Colors of Coordination Complexes
4.2.2.1.03: Crystal Field Stabilization Energy
4.2.2.1.04: Factors That Affect the Magnitude of o
4.2.2.1.05: Jahn-Teller Distortions
4.2.2.1.06: Magnetic Moments of Transition Metals
4.2.2.1.07: Magnetism
4.2.2.1.08: Thermodynamics and Structural Consequences of d-Orbital Splitting
4.2.2.02: Ligand Field Theory
4.03: Ligand Exchange Reactions (Thermodynamics)
4.3.01: Associative Ligand Substitution
4.3.02: Dissociative Ligand Substitution
4.04: Electronic Spectra of Coordination Compounds
05: Solid State Chemistry
5.01: Prelude to Metals and Alloys
5.02: Unit Cells and Crystal Structures
5.03: Crystal Structures of Metals
5.3.01: Conduction in Metals
5.04: Atomic Orbitals and Magnetism
5.4.01: Ferro- Ferri- and Antiferromagnetism
5.4.02: Hard and Soft Magnets
5.4.03: Defects in Metallic Crystals
5.05: X-ray Crystallography
5.5.01: Miller Indices (hkl)
5.5.02: Powder X-ray Diffraction
5.06: Prelude to Ionic and Covalent Solids - Structures
5.6.01: Close-packing and Interstitial Sites
5.6.02: Structures Related to NaCl and NiAs
5.6.03: Tetrahedral Structures
5.6.04: Layered Structures and Intercalation Reactions
5.6.05: Spinel Perovskite and Rutile Structures
5.07: Ionic Radii and Radius Ratios
5.08: Energetics of Crystalline Solids- The Ionic Model
5.8.01: Born-Haber Cycles for NaCl and Silver Halides
5.8.02: Lattice Energies and Solubility
5.8.03: Kapustinskii Equation
5.09: Electronic Properties of Materials - Superconductors and Semiconductors
5.9.01: Prelude to Electronic Properties of Materials - Superconductors and Semiconductors
5.9.02: Superconductors
5.9.03: Periodic Trends- Metals Semiconductors and Insulators
5.9.04: Semiconductors- Band Gaps Colors Conductivity and Doping
5.9.05: Semiconductor p-n Junctions
5.9.06: Diodes LEDs and Solar Cells
5.9.07: References
06: Organometallic Chemistry
6.01: 18 Valence Electron Rule
6.02: Synthesis and Stability
6.2.01: Transition Metal Alkyl Complexes
6.2.02: Metal-Carbenes
6.2.03: Metal Hydrides
6.2.04: Metal Carbonyls
6.2.05: Metal Phosphines
6.2.06: Complexes of bound Ligands
6.2.6.01: Metal Alkene Complexes
6.2.6.02: Metal Allyl and Diene Complexes
6.2.6.03: Metal Cyclopentadienyl Complexes
6.03: Reaction Mechanisms
6.3.01: Oxidative Addition and Reductive Elimination
6.3.02: Insertion and Elimination Reactions
6.3.03: Nucleophilic and Electrophilic Addition and Abstraction
6.04: Applications
6.4.01: Homogeneous Catalysis - I
6.4.02: Homogeneous Catalysis - II
6.4.03: Catalytic Applications of Organometallic Compounds- Alkene Metathesis
07: Bioinorganic Chemistry
7.01: Biological Significance of Iron Zinc Copper Molybdenum Cobalt Chromium Vanadium and Nickel
7.02: Introduction to Amino Acids and Proteins
7.03: Overview of Hemoglobin and Myoglobin
7.3.01: Myoglobin Hemoglobin and their Ligands
7.3.02: Oxygen Transport by the Proteins Myoglobin and Hemoglobin
7.04: Ferrodoxins Hydrogenases and Nitrogenases - Metal-Sulfide Proteins
7.4.01: Iron-sulfur Proteins and Models
7.4.02: Iron-sulfur Proteins and Models (Part 2)
7.4.03: Iron-sulfur Proteins and Models (Part 3)
7.4.04: Iron-sulfur Proteins and Models (Part 4)
7.05: The Reaction Pathways of Zinc Enzymes and Related Biological Catalysts
7.5.01: About Carbonic Anhydrase
7.5.02: Catalytic Mechanism
7.5.03: Metal Substitution
7.06: Metals in Medicine
7.6.01: Metal Deficiency and Disease
7.6.02: Toxic Effects of Metals
7.6.03: Aspects of Platinum Binding to DNA
7.6.04: Survey of Metals Used for Diagnosis and Chemotherapy
7.6.05: Platinum Anticancer Drugs- A Case Study
7.6.06: Mapping the Major Adducts ofcis-andtrans-DDP on DNA Sequence Specificity
7.6.07: Structure of Platinum-DNA Complexes
7.6.08: Site-specifically Platinated DNA (154)
7.6.09: Bioinorganic Chemistry of Platinum Anticancer Drugs- How Might They Work
7.6.10: Bioinorganic Chemistry of Platinum Anticancer Drugs How Might They Work (Part 2)
7.6.11: Design of New Inorganic Anticancer Drugs