
Nguồn ngoài
Chemical Principles
Study of the essential principles of chemistry including atomic and molecular science, states of matter, thermodynamics, chemical equilibrium, and reaction kinetics, which constitutes the foundation of modern chemistry.
- Tác giả
- Ta-Wei Li
- Nhà xuất bản
- National Yang Ming Chiao Tung University
- Nguồn
- LibreTexts
- Giấy phép
- CC BY-SA
- Ngôn ngữ
- EN
- Danh mục
- Khoa học cơ bản
Mục lục· 93 mục
- 01: Electronic Structure of Atoms
- 1.01: The Wave Nature of Light
- 1.02: Quantized Energy and Photons
- 1.03: Line Spectra and the Bohr Model
- 1.04: The Wave Behavior of Matter
- 1.05: Quantum Mechanics and Wavefunctions
- 1.06: The Schrodinger Wave Equation for the Hydrogen Atom
- 1.07: Many-Electron Atoms - Penetration and Shielding
- 1.08: Electron Configurations
- 1.09: Electron Configurations and the Periodic Table
- 1.E: Electronic Structure of Atoms (Exercises)
- 1.S: Electronic Structure of Atoms (Summary)
- 02: Periodic Properties of the Elements
- 2.01: Development of the Periodic Table
- 2.02: Shielding and Effective Nuclear Charge
- 2.03: Sizes of Atoms and Ions
- 2.04: Ionization Energy
- 2.05: Electron Affinities
- 2.E: Periodic Properties of the Elements (Exercises)
- 2.S: Periodic Properties of the Elements (Summary)
- 03: Basic Concepts of Chemical Bonding
- 3.01: Chemical Bonds Lewis Symbols and the Octet Rule
- 3.02: Ionic Bonding
- 3.03: Covalent Bonding
- 3.04: Bond Polarity and Electronegativity
- 3.05: Drawing Lewis Structures
- 3.06: Resonance Structures
- 3.07: Exceptions to the Octet Rule
- 3.08: Strength of Covalent Bonds
- 3.E: Basic Concepts of Chemical Bonding (Exercises)
- 3.S: Basic Concepts of Chemical Bonding (Summary)
- 04: Molecular Geometry and Bonding Theories
- 4.01: Molecular Shapes
- 4.02: The VSEPR Model
- 4.03: Molecular Shape and Molecular Polarity
- 4.04: Covalent Bonding and Orbital Overlap
- 4.05: Hybrid Orbitals
- 4.06: Multiple Bonds
- 4.07: Molecular Orbitals
- 4.08: Second-Row Diatomic Molecules
- 4.E: Exercises
- 4.S: Molecular Geometry and Bonding Theories (Summary)
- 05: Gases
- 5.01: Characteristics of Gases
- 5.02: Pressure
- 5.03: The Gas Laws
- 5.04: The Ideal Gas Equation
- 5.05: Further Applications of the Ideal-Gas Equations
- 5.06: Gas Mixtures and Partial Pressures
- 5.07: Kinetic-Molecular Theory
- 5.08: Molecular Effusion and Diffusion
- 5.09: Real Gases - Deviations from Ideal Behavior
- 5.E: Exercises
- 5.S: Gases (Summary)
- 06: Fundamentals of Thermochemistry (Heat and Enthalpy)
- 6.01: Systems States and Processes
- 6.02: Heat as a Mechanism to Transfer Energy
- 6.03: Work as a Mechanism to Transfer Energy
- 6.04: The First Law of Thermodynamics
- 6.05: Heat Capacity and Calorimetry
- 6.06: Molecules as Energy Carriers and Converters
- 6.07: Heats of Reactions - U and H
- 6.08: Indirect Determination of H - Hess's Law
- 6.09: Standard Enthalpies of Formation
- 6.E: Fundamentals of Thermochemistry (Exercises)
- 07: Principles of Thermodynamics (Entropy and Gibbs Energy)
- 7.01: The Nature of Spontaneous Processes
- 7.02: Entropy and Spontaneity - A Molecular Statistical Interpretation
- 7.03: Entropy and Heat - Experimental Basis of the Second Law of Thermodynamics
- 7.04: Entropy Changes and Spontaneity
- 7.05: Entropy Changes in Reversible Processes
- 7.06: Quantum States Microstates and Energy Spreading
- 7.07: The Third Law of Thermodynamics
- 7.08: Gibbs Energy
- 7.E: Principles of Thermodynamics (Exercises)
- 08: Chemical Equilibrium
- 8.01: The Nature of Chemical Equilibrium
- 8.02: The Empirical Law of Mass Action
- 8.03: Thermodynamic Description of the Equilibrium State
- 8.04: The Law of Mass Action for Related and Simultaneous Equilibria
- 8.05: Gas-Phase and Heterogeneous Reaction Equilibria
- 8.06: The Direction of Change in Chemical Reactions- Empirical Description
- 8.07: The Direction of Change in Chemical Reactions - Thermodynamic Explanation
- 8.08: Distribution between Immiscible Phases - Extraction and Separation Processes
- 8.E: Chemical Equilibrium (Exercises)
- 09: Electrochemistry
- 9.01: Electrochemical Cells
- 9.02: The Gibbs Free Energy and Cell Voltage
- 9.03: Concentration Effects and the Nernst Equation
- 9.04: Batteries and Fuel Cells
- 9.05: Corrosion and Its Prevention
- 9.06: A Deeper Look- Electrolysis of Water and Aqueous Solutions
- 9.E: Electrochemistry (Exercises)