Nguồn ngoài

CHEM 4210: Inorganic Chem II

Course provides a systematic survey of the descriptive chemistry of the elements, building on the theories presented in CHEM 4200.

Chemistry

Tác giả: Tasneem Siddiquee
Nhà xuất bản: Tennessee State University
Nguồn: LibreTexts
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

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Mục lục· 299 mục

01: Basic Inorganic Concepts
1.01: Introduction to Inorganic Chemistry
1.1.01: What is Inorganic Chemistry
1.1.02: Inorganic vs Organic Chemistry
1.1.03: History of Inorganic Chemistry
1.1.04: Perspectives
1.1.05: Practice problems
1.02: Atomic Structure
1.2.01: Historical Development of Atomic Theory
1.2.1.01: The Periodic Table
1.2.1.02: Discovery of Subatomic Particles and the Bohr Atom
1.2.02: The Schrodinger equation particle in a box and atomic wavefunctions
1.2.2.01: Particle in a Box
1.2.2.02: Quantum Numbers and Atomic Wave Functions
1.2.2.03: Aufbau Principle
1.2.2.04: Shielding
1.2.03: Periodic Properties of Atoms
1.2.3.01: Ionization energy
1.2.3.02: Electron Affinity
1.2.3.03: Covalent and Ionic Radii
1.2.04: Problems (do we want this here)
1.03: Simple Bonding Theory
1.3.01: Lewis Electron-Dot Diagrams
1.3.1.01: Resonance
1.3.1.02: Breaking the octet rule with higher electron counts (hypervalent atoms)
1.3.1.03: Formal Charge
1.3.1.04: Lewis Fails to Predict Unusual Cases - Boron and Beryllium
1.3.02: Valence Shell Electron-Pair Repulsion
1.3.2.01: Lone Pair Repulsion
1.3.2.02: Multiple Bonds
1.3.2.03: Electronegativity and Atomic Size Effects
1.3.2.04: Ligand Close Packing
1.3.03: Molecular Polarity
1.3.04: Hydrogen Bonding
1.3.05: Problems (do we want this here)
1.04: Symmetry and Group Theory
1.4.01: Symmetry Elements and Operations
1.4.02: Point Groups
1.4.2.01: Groups of Low and High Symmetry
1.4.2.02: Other Groups
1.4.03: Properties and Representations of Groups
1.4.3.01: Matrices
1.4.3.02: Representations of Point Groups
1.4.3.03: Character Tables
1.4.04: Examples and Applications of Symmetry
1.4.4.01: Chirality
1.4.4.02: Molecular Vibrations
1.4.P: Problems (under construction)
02: d-Block Metal Chemistry- General Considerations
2.01: Prelude to Coordination Chemistry I - Structure and Isomers
2.02: History
2.03: Nomenclature and Ligands
2.04: Isomerism
2.05: Coordination Numbers and Structures
2.06: Coordination Frameworks
2.P: Problems
03: d-Block Metal Chemistry- Coordination Complexes
3.01: Evidence for Electronic Structures
3.1.01: Thermodynamic Data
3.1.02: Magnetic Susceptibility
3.1.03: Electronic Spectra
3.1.04: Coordination Number and Molecular Shapes
3.02: Bonding Theories
3.2.01: Crystal Field Theory
3.03: Ligand Field Theory
3.3.01: Ligand Field Theory - Molecular Orbitals for an Octahedral Complex
3.3.02: Orbital Splitting and Electron Spin
3.3.03: Ligand Field Stabilization Energy
3.3.04: Tetrahedral Complexes
3.3.05: Square-Planar Complexes
3.04: Angular Overlap
3.4.01: Sigma Bonding in the Angular Overlap Model
3.4.02: Pi Acceptors in the Angular Overlap Model
3.4.03: Pi Donors in the Angular Overlap Model
3.4.04: The Spectrochemical Series
3.4.05: The Magnitude of Parameters e e and
3.4.06: The Magnetochemical Series
3.05: The Jahn-Teller Effect
3.06: Four- and Six-Coordinate Preferences
3.07: Other Shapes
3.P: Problems
04: d-Block Metal Chemistry
4.01: Properties of Transition Metals
4.1.01: A Brief Survey of Transition-Metal Chemistry
4.1.02: Electron Configuration of Transition Metals
4.1.03: General Trends among the Transition Metals
4.1.04: Introduction to Transition Metals I
4.1.05: Introduction to Transition Metals II
4.1.06: Metallurgy
4.1.6.01: An Introduction to the Chemistry of Metal Extraction
4.1.6.02: The Extraction of Copper
4.1.6.03: The Extraction of Iron
4.1.6.3.01: Iron Production
4.1.6.04: The Extraction of Silver
4.1.6.4.01: Preparation and uses of Silver chloride and Silver nitrate
4.1.07: Oxidation States of Transition Metals
4.1.08: Transition Metals in Biology
4.02: Transition Metals
4.2.01: Chemistry of Actinium
4.2.02: Chemistry of Lanthanum
4.2.03: Chemistry of Scandium
4.2.04: Chemistry of Yttrium
4.2.05: Group 3 Elemental Properties
4.03: Transition Metals
4.3.01: Group 4 Elemental Properties
4.3.02: Chemistry of Hafnium
4.3.03: Chemistry of Rutherfordium
4.3.04: Chemistry of Titanium
4.3.05: Chemistry of Zirconium
4.04: Transition Metals
4.4.01: Chemistry of Dubnium
4.4.02: Chemistry of Niobium
4.4.03: Chemistry of Tantalum
4.4.04: Chemistry of Vanadium
4.4.05: Group 5 Elemental Properties
4.05: Transition Metals
4.5.01: Chemistry of Chromium
4.5.1.01: Chemistry of Chromium
4.5.1.02: Potassium Chromium Sulfate
4.5.02: Chemistry of Molybdenum
4.5.2.01: Molybdenum Disulfide
4.5.03: Chemistry of Seaborgium
4.5.04: Chemistry of Tungsten
4.06: Transition Metals
4.6.01: Chemistry of Bohrium
4.6.02: Chemistry of Manganese
4.6.2.01: Chemistry of Manganese
4.6.03: Chemistry of Rhenium
4.6.04: Chemistry of Technetium
4.07: Transition Metals
4.7.01: Chemistry of Hassium
4.7.02: Chemistry of Iron
4.7.2.01: Iron in Humans
4.7.03: Chemistry of Osmium
4.7.04: Chemistry of Ruthenium
4.08: Transition Metals
4.8.01: Chemistry of Cobalt
4.8.02: Chemistry of Iridium
4.8.03: Chemistry of Meitnerium
4.8.04: Chemistry of Rhodium
4.09: Transition Metals
4.9.01: Chemistry of Darmstadtium
4.9.02: Chemistry of Nickel
4.9.03: Chemistry of Palladium
4.9.04: Chemistry of Platinum
4.10: Transition Metals
4.10.01: Chemistry of Copper
4.10.02: Chemistry of Gold
4.10.03: Chemistry of Roentgenium
4.10.04: Chemistry of Silver
4.10.4.01: Silver Chloride
4.10.4.02: Silver Nitrate
4.11: Transition Metals
4.11.01: Chemistry of Cadmium
4.11.1.01: Cadmium Sulfide
4.11.02: Chemistry of Copernicium
4.11.03: Chemistry of Mercury
4.11.04: Chemistry of Zinc
05: Reactions of Complexes
5.01: Introduction to Reactions of Metal Complexes
5.02: Substitutions Reactions
5.2.01: Introduction to Substitution Reactions
5.2.02: Inert and Labile Complexes
5.2.03: Mechanistic Possibilities
5.03: Kinetics Hint at the Reaction Mechanism
5.3.01: Rate Law for Dissociative Mechanisms
5.3.02: Rate Laws for Interchange Mechanisms
5.3.03: Rate Law for Associative Mechanisms
5.3.04: Preassociation Complexes
5.3.05: Activation Parameters
5.3.06: Some Reasons for Differing Mechanisms
5.04: Experimental Evidence in Octahedral Substitutions
5.4.01: Dissociation
5.4.02: Linear Free Energy Relationships
5.4.03: Associative Mechanisms
5.4.04: The conjugate base mechanism
5.4.05: The Kinetic Chelate Effect
5.05: Stereochemistry of Octahedral Reactions
5.5.01: Substitution in trans-en octahedral complexes
5.5.02: Substitution in cis-en octahedral complexes
5.5.03: Isomerization of Chelate Rings
5.06: Substitutions in Square Planar Complexes
5.6.01: Kinetics and Stereochemistry of Square Planar Reactions
5.6.02: Evidence for Associative Reactions
5.07: The Trans Effect
5.08: Redox Mechanisms
5.8.01: Outer Sphere Electron Transfer
5.8.02: Inner Sphere Electron Transfer
5.09: Reactions of Coordinated Ligands
5.9.01: Metal-catalyzed Hydrolysis
5.9.02: Template Reactions
5.9.03: Electrophilic Substitutions
06: Catalysis
6.01: Introduction to Organometallic Chemistry
6.02: Nomenclature Ligands and Classification
6.03: Electron Counting in Organometallic Complexes
6.3.01: The 18 Electron Rule
6.3.02: Simplifying the Organometallic Complex by Deconstruction
6.04: Survey of Organometallic Ligands
6.4.01: Carbon Monoxide (Carbonyl Complexes)
6.4.02: Ligands similar to CO
6.4.03: Hydrides and Dihydrogen Complexes
6.05: Bonding between Metal Atoms and Organic Pi Systems
6.5.01: Linear Systems
6.5.02: Cyclic systems
6.5.03: Odd-numbered Systems
6.5.04: Fullerene Complexes
6.06: Metal-Carbon Bonds
6.6.01: Metal Alkyls
6.6.02: Carbenes
6.6.03: Carbyne (Alkylidyne) Complexes
6.6.04: Carbido and Cumulene Complexes
6.6.05: Carbon Wires- Polyyne and Polyene Bridges
6.07: Characterization of Organometallic Complexes
07: Organometallic Reactions and Catalysis
7.01: Reactions Involving Gain or Loss of Ligands
7.1.01: Ligand Dissociation and Substitution
7.1.02: Oxidative Addition
7.1.03: Reductive Elimination
7.1.04: Sigma Bond Metathasis
7.1.05: Application of Pincer Ligands
7.02: Reactions Invloving Modification of Unsaturated Ligands
7.2.01: Introduction to Insertion
7.2.02: CO Insertions (Alkyl Migration)
7.2.03: Migratory Insertion-12-Insertions
7.2.04: -Elimination Reactions
7.2.05: Abstraction and Addition
7.03: Organometallic Catalysts
7.3.01: Catalytic Deuteration
7.3.02: Hydroformylation
7.3.03: Monsanto Acetic Acid Process
7.3.04: Wacker (Smidt) Process
7.3.05: Hydrogenation by Wilkinson's Catalyst
7.3.06: Olefin Metathesis
7.04: Heterogeneous Catalysts
7.4.01: Ziegler-Natta Polymerizations
7.4.02: Water-Gas Shift Reaction
7.05: Problems
7.5.01: Concept Review Questions Chapter 12
7.5.02: Homework Problems Chapter 12
08: Lanthanides and Actinides
8.01: The Lanthanides
8.1.01: Lanthanides- Properties and Reactions
8.1.1.01: Lanthanide Contraction
8.1.02: Chemistry of Cerium
8.1.03: Chemistry of Dysprosium
8.1.04: Chemistry of Europium
8.1.05: Chemistry of Gadolinium
8.1.5.01: Gadolinium(III) Chloride
8.1.06: Chemistry of Holmium
8.1.07: Chemistry of Lutetium
8.1.08: Chemistry of Neodymium
8.1.09: Chemistry of Praseodymium
8.1.10: Chemistry of Promethium
8.1.11: Chemistry of Samarium
8.1.12: Chemistry of Terbium
8.1.13: Chemistry of Thulium
8.1.14: Chemistry of Ytterbium
8.1.15: Chemistry of Yttrium
8.02: The Actinides
8.2.01: General Properties and Reactions of The Actinides
8.2.02: Chemistry of Americium
8.2.03: Chemistry of Berkelium
8.2.04: Chemistry of Californium
8.2.05: Chemistry of Curium
8.2.06: Chemistry of Einsteinium
8.2.07: Chemistry of Fermium
8.2.08: Chemistry of Lawrencium
8.2.09: Chemistry of Mendelevium
8.2.10: Chemistry of Neptunium
8.2.11: Chemistry of Nobelium
8.2.12: Chemistry of Plutonium
8.2.13: Chemistry of Protoactinium
8.2.14: Chemistry of Thorium
8.2.15: Chemistry of Uranium
09: Inorganic Materials and Nanotechnology
9.01: Electronic Properties of Materials - Superconductors and Semiconductors
9.1.01: Prelude to Electronic Properties of Materials - Superconductors and Semiconductors
9.1.02: Metal-Insulator Transitions
9.1.03: Superconductors
9.1.04: Periodic Trends- Metals Semiconductors and Insulators
9.1.05: Semiconductors- Band Gaps Colors Conductivity and Doping
9.1.06: Semiconductor p-n Junctions
9.1.07: Diodes LEDs and Solar Cells
9.1.08: Amorphous Semiconductors
9.1.09: Discussion Questions
9.1.10: Problems
9.1.11: References
9.02: Basic Science of Nanomaterials
9.2.01: Prelude to Basic Science of Nanomaterials
9.2.02: Physics and Length Scales- Cavity Laser Coulomb Blockade Nanoscale Magnets
9.2.03: Semiconductor Quantum Dots
9.2.04: Synthesis of Semiconductor Nanocrystals
9.2.05: Surface Energy
9.2.06: Nanoscale Metal Particles
9.2.07: Applications of Nanomaterials
9.2.08: Discussion Questions
9.2.09: Problems
9.2.10: References