Nguồn ngoài

Thermodynamics and Chemistry

Thermodynamics and Chemistry is designed primarily as a textbook for a one-semester course in classical chemical thermodynamics at the graduate or undergraduate level.

Physical and Theoretical Chemistry Textbook Maps Chemistry

Tác giả: Howard DeVoe
Nhà xuất bản: University of Maryland
Nguồn: LibreTexts
Giấy phép: CC BY
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

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Mục lục· 131 mục

01: Introduction
1.01: Units
1.02: Quantity Calculus
1.03: Dimensional Analysis
1.04: Chapter 1 Problem
02: Systems and Their Properties
2.01: The System Surroundings and Boundary
2.02: Phases and Physical States of Matter
2.03: Some Basic Properties and Their Measurement
2.04: The State of the System
2.05: Processes and Paths
2.06: The Energy of the System
2.07: Chapter 2 Problems
03: The First Law
3.01: Heat Work and the First Law
3.02: Spontaneous Reversible and Irreversible Processes
3.03: Heat Transfer
3.04: Deformation Work
3.05: Applications of Expansion Work
3.06: Work in a Gravitational Field
3.07: Shaft Work
3.08: Electrical Work
3.09: Irreversible Work and Internal Friction
3.10: Reversible and Irreversible Processes- Generalities
3.11: Chapter 3 Problems
04: The Second Law
4.01: Types of Processes
4.02: Statements of the Second Law
4.03: Concepts Developed with Carnot Engines
4.04: Derivation of the Mathematical Statement of the Second Law
4.05: Irreversible Processes
4.06: Applications
4.07: Summary
4.08: The Statistical Interpretation of Entropy
4.09: Chapter 4 Problems
05: Thermodynamic Potentials
5.01: Total Differential of a Dependent Variable
5.02: Total Differential of the Internal Energy
5.03: Enthalpy Helmholtz Energy and Gibbs Energy
5.04: Closed Systems
5.05: Open Systems
5.06: Expressions for Heat Capacity
5.07: Surface Work
5.08: Criteria for Spontaneity
5.09: Chapter 5 Problems
06: The Third Law and Cryogenics
6.01: The Zero of Entropy
6.02: Molar Entropies
6.03: Cryogenics
6.04: Chapter 6 Problem
07: Pure Substances in Single Phases
7.01: Volume Properties
7.02: Internal Pressure
7.03: Thermal Properties
7.04: Heating at Constant Volume or Pressure
7.05: Partial Derivatives with Respect to (T) (p) and (V)
7.06: Isothermal Pressure Changes
7.07: Standard States of Pure Substances
7.08: Chemical Potential and Fugacity
7.09: Standard Molar Quantities of a Gas
7.10: Chapter 7 Problems
08: Phase Transitions and Equilibria of Pure Substances
8.01: Phase Equilibria
8.02: Phase Diagrams of Pure Substances
8.03: Phase Transitions
8.04: Coexistence Curves
8.05: Chapter 8 Problems
09: Mixtures
9.01: Composition Variables
9.02: Partial Molar Quantities
9.03: Gas Mixtures
9.04: Liquid and Solid Mixtures of Nonelectrolytes
9.05: Activity Coefficients in Mixtures of Nonelectrolytes
9.06: Evaluation of Activity Coefficients
9.07: Activity of an Uncharged Species
9.08: Mixtures in Gravitational and Centrifugal Fields
9.09: Chapter 9 Problems
10: Electrolyte Solutions
10.01: Single-ion Quantities
10.02: Solution of a Symmetrical Electrolyte
10.03: Electrolytes in General
10.04: The Debye-Huckel Theory
10.05: Derivation of the Debye-Huckel Theory
10.06: Mean Ionic Activity Coefficients from Osmotic Coefficients
10.07: Chapter 10 Problems
11: Reactions and Other Chemical Processes
11.01: Mixing Processes
11.02: The Advancement and Molar Reaction Quantities
11.03: Molar Reaction Enthalpy
11.04: Enthalpies of Solution and Dilution
11.05: Reaction Calorimetry
11.06: Adiabatic Flame Temperature
11.07: Gibbs Energy and Reaction Equilibrium
11.08: The Thermodynamic Equilibrium Constant
11.09: Effects of Temperature and Pressure on Equilibrium Position
11.10: Chapter 11 Problems
12: Equilibrium Conditions in Multicomponent Systems
12.01: Effects of Temperature
12.02: Solvent Chemical Potentials from Phase Equilibria
12.03: Binary Mixture in Equilibrium with a Pure Phase
12.04: Colligative Properties of a Dilute Solution
12.05: Solid-Liquid Equilibria
12.06: Liquid-Liquid Equilibria
12.07: Membrane Equilibria
12.08: Liquid-Gas Equilibria
12.09: Reaction Equilibria
12.10: Evaluation of Standard Molar Quantities
12.11: Chapter 12 Problems
13: The Phase Rule and Phase Diagrams
13.01: The Gibbs Phase Rule for Multicomponent Systems
13.02: Phase Diagrams- Binary Systems
13.03: Phase Diagrams- Ternary Systems
13.04: Chapter 13 Problems
14: Galvanic Cells
14.01: Cell Diagrams and Cell Reactions
14.02: Electric Potentials in the Cell
14.03: Molar Reaction Quantities of the Cell Reaction
14.04: The Nernst Equation
14.05: Evaluation of the Standard Cell Potential
14.06: Standard Electrode Potentials
14.07: Chapter 14 Problems
15: Appendices
15.01: Appendix A- Definitions of the SI Base Units
15.02: Appendix B- Physical Constants
15.03: Appendix C- Symbols for Physical Quantities
15.04: Appendix D- Miscellaneous Abbreviations and Symbols
15.05: Appendix E- Calculus Review
15.06: Appendix F- Mathematical Properties of State Functions
15.07: Appendix G- Forces Energy and Work
15.08: Appendix H- Standard Molar Thermodynamic Properties
15.09: Appendix I- Answers to Selected Problems