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Analytical Chemistry 2.0

Analytical chemistry spans nearly all areas of chemistry but involves the development of tools and methods to measure physical properties of substances and apply those techniques to the identification of their presence (qualitative analysis) and quantify the amount present (quantitative analysis) of species in a wide variety of settings.

Chemistry

Tác giả: David Harvey
Nhà xuất bản: DePauw University
Nguồn: LibreTexts
Giấy phép: CC BY-NC-SA
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

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Mục lục· 141 mục

01: Front Matter
1.1: TitlePage
1.2: InfoPage
1.3: Table of Contents
02: Introduction to Analytical Chemistry
2.1: What is Analytical Chemistry?
2.2: The Analytical Perspective
2.3: Common Analytical Problems
2.4: Introduction to Analytical Chemistry (Exercises)
2.5: Introduction to Analytical Chemistry (Summary)
03: Basic Tools of Analytical Chemistry
3.1: Measurements in Analytical Chemistry
3.2: Concentration
3.3: Stoichiometric Calculations
3.4: Basic Equipment
3.5: Preparing Solutions
3.6: Spreadsheets and Computational Software
3.7: The Laboratory Notebook
3.8: Basic Tools of Analytical Chemistry (Exercises)
3.9: Basic Tools of Analytical Chemistry (Summary)
04: The Vocabulary of Analytical Chemistry
4.1: Analysis, Determination, and Measurement
4.2: Techniques, Methods, Procedures, and Protocols
4.3: Classifying Analytical Techniques
4.4: Selecting an Analytical Method
4.5: Developing the Procedure
4.6: Protocols
4.7: The Importance of Analytical Methodology
4.8: The Vocabulary of Analytical Chemistry (Exercises)
4.9: The Vocabulary of Analytical Chemistry (Summary)
05: Evaluating Analytical Data
5.01: Characterizing Measurements and Results
5.02: Characterizing Experimental Errors
5.03: Propagation of Uncertainty
5.04: The Distribution of Measurements and Results
5.05: Statistical Analysis of Data
5.06: Statistical Methods for Normal Distributions
5.07: Detection Limits
5.08: Using Excel and R to Analyze Data
5.09: Evaluating Analytical Data (Exercises)
5.10: Evaluating Analytical Data (Summary)
06: Standardizing Analytical Methods
6.1: Analytical Standards
6.2: Calibrating the Signal
6.3: Determining the Sensitivity
6.4: Linear Regression and Calibration Curves
6.5: Blank Corrections
6.6: Using Excel and R for a Regression Analysis
6.7: Standardizing Analytical Methods (Exercises)
6.8: Standardizing Analytical Methods (Summary)
07: Equilibrium Chemistry
7.01: Reversible Reactions and Chemical Equilibria
7.02: Thermodynamics and Equilibrium Chemistry
7.03: Manipulating Equilibrium Constants
7.04: Equilibrium Constants for Chemical Reactions
7.05: Le Châtelier’s Principle
7.06: Ladder Diagrams
7.07: Solving Equilibrium Problems
7.08: Buffer Solutions
7.09: Activity Effects
7.10: Using Excel and R to Solve Equilibrium Problems
7.11: Some Final Thoughts on Equilibrium Calculations
7.12: Equilibrium Chemistry (Exercises)
7.13: Equilibrium Chemistry (Summary)
08: Collecting and Preparing Samples
8.01: The Importance of Sampling
8.02: Designing a Sampling Plan
8.03: Implementing the Sampling Plan
8.04: Separating the Analyte from Interferents
8.05: General Theory of Separation Efficiency
8.06: Classifying Separation Techniques
8.07: Liquid–Liquid Extractions
8.08: Separation Versus Preconcentration
8.09: Collecting and Preparing Samples (Exercises)
8.10: Collecting and Preparing Samples (Summary)
09: Gravimetric Methods
9.1: Overview of Gravimetric Methods
9.2: Precipitation Gravimetry
9.3: Volatilization Gravimetry
9.4: Particulate Gravimetry
9.5: Gravimetric Methods (Exercises)
9.6: Gravimetric Methods (Summary)
10: Titrimetric Methods
10.1: Overview of Titrimetry
10.2: Acid–Base Titrations
10.3: Complexation Titrations
10.4: Redox Titrations
10.5: Precipitation Titrations
10.6: Titrimetric Methods (Exercises)
10.7: Titrimetric Methods (Summary)
11: Spectroscopic Methods
11.01: Overview of Spectroscopy
11.02: Spectroscopy Based on Absorption
11.03: UV
Vis and IR Spectroscopy
11.04: Atomic Absorption Spectroscopy
11.05: Emission Spectroscopy
11.06: Photoluminescence Spectroscopy
11.07: Atomic Emission Spectroscopy
11.08: Spectroscopy Based on Scattering
11.09: Spectroscopic Methods (Exercises)
11.10: Spectroscopic Methods (Summary)
12: Electrochemical Methods
12.1: Overview of Electrochemistry
12.2: Potentiometric Methods
12.3: Coulometric Methods
12.4: Voltammetric Methods
12.5: Electrochemical Methods (Exercises)
12.6: Electrochemical Methods (Summary)
13: Chromatographic
13.1: Overview of Analytical Separations
13.2: General Theory of Column Chromatography
13.3: Optimizing Chromatographic Separations
13.4: Gas Chromatography
13.5: High-Performance Liquid Chromatography
13.6: Other Forms of Liquid Chromatography
13.7: Electrophoresis
13.8: Chromatographic and Electrophoretic Methods (Exercises)
13.9: Chromatographic and Electrophoretic Methods (Summary)
14: Kinetic Methods
14.1: Kinetic Methods Versus Equilibrium Methods
14.2: Chemical Kinetics
14.3: Radiochemistry
14.4: Flow Injection Analysis
14.5: Kinetic Methods (Exercises)
14.6: Kinetic Methods (Summary)
15: Developing a Standard Method
15.1: Optimizing the Experimental Procedure
15.2: Verifying the Method
15.3: Validating the Method as a Standard Method
15.4: Using Excel and R for an Analysis of Variance
15.5: Developing a Standard Method (Exercises)
15.6: Developing a Standard Method (Summary)
16: Quality Assurance
16.1: The Analytical Perspective—Revisited
16.2: Quality Control
16.3: Quality Assessment
16.4: Evaluating Quality Assurance Data
16.5: Quality Assurance (Exercises)
17: Additional Resources
18: Back Matter