
Nguồn ngoài
CHEM 341- Physical Chemistry I
- Tác giả
- Daniel Albert
- Nhà xuất bản
- Millersville University
- Nguồn
- LibreTexts
- Ngôn ngữ
- EN
- Danh mục
- Khoa học cơ bản
Mục lục· 139 mục
- 01: Introduction to Physical Chemistry using Gases
- 1.01: Prior Knowledge of Chemistry Math and Physics
- 1.02: Integrating Macroscopic Microscopic and Mathematical Approaches
- 1.03: The Ideal Gas Law
- 1.04: The Kinetic Molecular Theory of Gases
- 1.05: Kinetic Energy
- 1.06: Ideal Gas Law as a Model
- 1.07: Real Gases
- 1.08: Equations of State
- 1.E: Gases (Exercises)
- 1.S: Gases (Summary)
- 02: The Basics of Thermodynamics
- 2.01: The System and the Surroundings
- 2.02: Pressure and Molar Volume
- 2.03: Temperature
- 2.04: The Zeroth Law of Thermodynamics
- 2.05: Work and Energy
- 2.06: Heat and Energy
- 2.07: Temperature vs. Heat - What's the difference
- 2.E: The Basics (Exercises)
- 2.S: The Basics (Summary)
- 03: First Law of Thermodynamics
- 3.01: Prelude to Thermodynamics
- 3.02: Work and Heat
- 3.03: Reversible and Irreversible Pathways
- 3.04: Calorimetry
- 3.05: Temperature Dependence of Enthalpy
- 3.06: Reaction Enthalpies
- 3.07: Lattice Energy and the Born-Haber Cycle
- 3.E: First Law of Thermodynamics (Exercises)
- 3.S: First Law of Thermodynamics (Summary)
- 04: Putting the First Law to Work
- 4.01: Prelude to Putting the First Law to Work
- 4.02: Total and Exact Differentials
- 4.03: Compressibility and Expansivity
- 4.04: The Joule Experiment
- 4.05: The Joule-Thomson Effect
- 4.06: Useful Definitions and Relationships
- 4.E: Putting the First Law to Work (Exercises)
- 4.S: Putting the First Law to Work (Summary)
- 05: The Second Law
- 5.01: Why Nature Requires Another Law of Thermodynamics
- 5.02: Introduction to the Second Law
- 5.03: Efficiency of Energy Generation
- 5.04: Heat Engines and the Carnot Cycle
- 5.05: Entropy
- 5.06: Calculating Entropy Changes
- 5.07: Comparing the System and the Surroundings
- 5.08: Entropy and Disorder
- 5.09: The Third Law of Thermodynamics
- 5.10: Adiabatic Compressibility
- 5.11: Efficiencies of Engines and Refrigerators
- 5.12: Vortex Tubes
- 5.E: The Second Law (Exercises)
- 5.S: The Second Law (Summary)
- 06: Putting the Second Law to Work
- 6.01: Free Energy Functions
- 6.02: Combining the First and Second Laws - Maxwell's Relations
- 6.03: A G and Maximum Work
- 6.04: Volume Dependence of Helmholtz Energy
- 6.05: Pressure Dependence of Gibbs Energy
- 6.06: Temperature Dependence of A and G
- 6.07: When Two Variables Change at Once
- 6.08: The Difference between Cp and Cv
- 6.E: Putting the Second Law to Work (Exercises)
- 6.S: Putting the Second Law to Work (Summary)
- 07: Mixtures and Solutions
- 7.01: Thermodynamics of Mixing
- 7.02: Partial Molar Volume
- 7.03: Chemical Potential
- 7.04: The Gibbs-Duhem Equation
- 7.05: Non-ideality in Gases - Fugacity
- 7.06: Colligative Properties
- 7.07: Solubility
- 7.08: Non-ideality in Solutions - Activity
- 7.E: Mixtures and Solutions (Exercises)
- 7.S: Mixtures and Solutions (Summary)
- 08: Phase Equilibrium
- 8.01: Prelude to Phase Equilibrium
- 8.02: Single Component Phase Diagrams
- 8.03: Criterion for Phase Equilibrium
- 8.04: The Clapeyron Equation
- 8.05: The Clausius-Clapeyron Equation
- 8.06: Phase Diagrams for Binary Mixtures
- 8.07: Liquid-Vapor Systems - Raoults Law
- 8.08: Non-ideality - Henry's Law and Azeotropes
- 8.09: Solid-Liquid Systems - Eutectic Points
- 8.10: Cooling Curves
- 8.E: Phase Equilibrium (Exercises)
- 8.S: Phase Equilibrium (Summary)
- 09: Chemical Equilibria
- 9.01: Prelude to Chemical Equilibria
- 9.02: Chemical Potential
- 9.03: Activities and Fugacities
- 9.04: Pressure Dependence of Kp - Le Chatelier's Principle
- 9.05: Degree of Dissociation
- 9.06: Temperature Dependence of Equilibrium Constants - the van t Hoff Equation
- 9.07: The Dumas Bulb Method for Measuring Decomposition Equilibrium
- 9.08: Acid-Base Equilibria
- 9.09: Buffers
- 9.10: Solubility of Ionic Compounds
- 9.E: Chemical Equilibria (Exercises)
- 9.S: Chemical Equilibria (Summary)
- 10: Electrochemistry
- 10.01: Electricity
- 10.02: The connection to G
- 10.03: Half Cells and Standard Reduction Potentials
- 10.04: Entropy of Electrochemical Cells
- 10.05: Concentration Cells
- 10.E: Electrochemistry (Exercises)
- 10.S: Electrochemistry (Summary)
- 11: Chemical Kinetics I
- 11.01: Reaction Rate
- 11.02: Measuring Reaction Rates
- 11.03: Rate Laws
- 11.04: 0th order Rate Law
- 11.05: 1st order rate law
- 11.06: 2nd order Rate Laws
- 11.07: The Method of Initial Rates
- 11.08: The Method of Half-Lives
- 11.09: Temperature Dependence
- 11.10: Collision Theory
- 11.11: Transition State Theory
- 11.E: Chemical Kinetics I (Exercises)
- 11.S: Chemical Kinetics I (Summary)
- 12: Chemical Kinetics II
- 12.01: Reaction Mechanisms
- 12.02: Concentration Profiles for Some Simple Mechanisms
- 12.03: The Connection between Reaction Mechanisms and Reaction Rate Laws
- 12.04: The Rate Determining Step Approximation
- 12.05: The Steady-State Approximation
- 12.06: The Equilibrium Approximation
- 12.07: The Lindemann Mechanism
- 12.08: The Michaelis-Menten Mechanism
- 12.09: Chain Reactions
- 12.10: Catalysis
- 12.11: Oscillating Reactions
- 12.E: Chemical Kinetics II (Exercises)
- 12.S: Chemical Kinetics II (Summary)