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CHEM 341- Physical Chemistry I

Nguồn ngoài

CHEM 341- Physical Chemistry I

Tác giả
Daniel Albert
Nhà xuất bản
Millersville University
Nguồn
LibreTexts
Ngôn ngữ
EN
Danh mục
Khoa học cơ bản
Mục lục· 139 mục
  1. 01: Introduction to Physical Chemistry using Gases
  2. 1.01: Prior Knowledge of Chemistry Math and Physics
  3. 1.02: Integrating Macroscopic Microscopic and Mathematical Approaches
  4. 1.03: The Ideal Gas Law
  5. 1.04: The Kinetic Molecular Theory of Gases
  6. 1.05: Kinetic Energy
  7. 1.06: Ideal Gas Law as a Model
  8. 1.07: Real Gases
  9. 1.08: Equations of State
  10. 1.E: Gases (Exercises)
  11. 1.S: Gases (Summary)
  12. 02: The Basics of Thermodynamics
  13. 2.01: The System and the Surroundings
  14. 2.02: Pressure and Molar Volume
  15. 2.03: Temperature
  16. 2.04: The Zeroth Law of Thermodynamics
  17. 2.05: Work and Energy
  18. 2.06: Heat and Energy
  19. 2.07: Temperature vs. Heat - What's the difference
  20. 2.E: The Basics (Exercises)
  21. 2.S: The Basics (Summary)
  22. 03: First Law of Thermodynamics
  23. 3.01: Prelude to Thermodynamics
  24. 3.02: Work and Heat
  25. 3.03: Reversible and Irreversible Pathways
  26. 3.04: Calorimetry
  27. 3.05: Temperature Dependence of Enthalpy
  28. 3.06: Reaction Enthalpies
  29. 3.07: Lattice Energy and the Born-Haber Cycle
  30. 3.E: First Law of Thermodynamics (Exercises)
  31. 3.S: First Law of Thermodynamics (Summary)
  32. 04: Putting the First Law to Work
  33. 4.01: Prelude to Putting the First Law to Work
  34. 4.02: Total and Exact Differentials
  35. 4.03: Compressibility and Expansivity
  36. 4.04: The Joule Experiment
  37. 4.05: The Joule-Thomson Effect
  38. 4.06: Useful Definitions and Relationships
  39. 4.E: Putting the First Law to Work (Exercises)
  40. 4.S: Putting the First Law to Work (Summary)
  41. 05: The Second Law
  42. 5.01: Why Nature Requires Another Law of Thermodynamics
  43. 5.02: Introduction to the Second Law
  44. 5.03: Efficiency of Energy Generation
  45. 5.04: Heat Engines and the Carnot Cycle
  46. 5.05: Entropy
  47. 5.06: Calculating Entropy Changes
  48. 5.07: Comparing the System and the Surroundings
  49. 5.08: Entropy and Disorder
  50. 5.09: The Third Law of Thermodynamics
  51. 5.10: Adiabatic Compressibility
  52. 5.11: Efficiencies of Engines and Refrigerators
  53. 5.12: Vortex Tubes
  54. 5.E: The Second Law (Exercises)
  55. 5.S: The Second Law (Summary)
  56. 06: Putting the Second Law to Work
  57. 6.01: Free Energy Functions
  58. 6.02: Combining the First and Second Laws - Maxwell's Relations
  59. 6.03: A G and Maximum Work
  60. 6.04: Volume Dependence of Helmholtz Energy
  61. 6.05: Pressure Dependence of Gibbs Energy
  62. 6.06: Temperature Dependence of A and G
  63. 6.07: When Two Variables Change at Once
  64. 6.08: The Difference between Cp and Cv
  65. 6.E: Putting the Second Law to Work (Exercises)
  66. 6.S: Putting the Second Law to Work (Summary)
  67. 07: Mixtures and Solutions
  68. 7.01: Thermodynamics of Mixing
  69. 7.02: Partial Molar Volume
  70. 7.03: Chemical Potential
  71. 7.04: The Gibbs-Duhem Equation
  72. 7.05: Non-ideality in Gases - Fugacity
  73. 7.06: Colligative Properties
  74. 7.07: Solubility
  75. 7.08: Non-ideality in Solutions - Activity
  76. 7.E: Mixtures and Solutions (Exercises)
  77. 7.S: Mixtures and Solutions (Summary)
  78. 08: Phase Equilibrium
  79. 8.01: Prelude to Phase Equilibrium
  80. 8.02: Single Component Phase Diagrams
  81. 8.03: Criterion for Phase Equilibrium
  82. 8.04: The Clapeyron Equation
  83. 8.05: The Clausius-Clapeyron Equation
  84. 8.06: Phase Diagrams for Binary Mixtures
  85. 8.07: Liquid-Vapor Systems - Raoults Law
  86. 8.08: Non-ideality - Henry's Law and Azeotropes
  87. 8.09: Solid-Liquid Systems - Eutectic Points
  88. 8.10: Cooling Curves
  89. 8.E: Phase Equilibrium (Exercises)
  90. 8.S: Phase Equilibrium (Summary)
  91. 09: Chemical Equilibria
  92. 9.01: Prelude to Chemical Equilibria
  93. 9.02: Chemical Potential
  94. 9.03: Activities and Fugacities
  95. 9.04: Pressure Dependence of Kp - Le Chatelier's Principle
  96. 9.05: Degree of Dissociation
  97. 9.06: Temperature Dependence of Equilibrium Constants - the van t Hoff Equation
  98. 9.07: The Dumas Bulb Method for Measuring Decomposition Equilibrium
  99. 9.08: Acid-Base Equilibria
  100. 9.09: Buffers
  101. 9.10: Solubility of Ionic Compounds
  102. 9.E: Chemical Equilibria (Exercises)
  103. 9.S: Chemical Equilibria (Summary)
  104. 10: Electrochemistry
  105. 10.01: Electricity
  106. 10.02: The connection to G
  107. 10.03: Half Cells and Standard Reduction Potentials
  108. 10.04: Entropy of Electrochemical Cells
  109. 10.05: Concentration Cells
  110. 10.E: Electrochemistry (Exercises)
  111. 10.S: Electrochemistry (Summary)
  112. 11: Chemical Kinetics I
  113. 11.01: Reaction Rate
  114. 11.02: Measuring Reaction Rates
  115. 11.03: Rate Laws
  116. 11.04: 0th order Rate Law
  117. 11.05: 1st order rate law
  118. 11.06: 2nd order Rate Laws
  119. 11.07: The Method of Initial Rates
  120. 11.08: The Method of Half-Lives
  121. 11.09: Temperature Dependence
  122. 11.10: Collision Theory
  123. 11.11: Transition State Theory
  124. 11.E: Chemical Kinetics I (Exercises)
  125. 11.S: Chemical Kinetics I (Summary)
  126. 12: Chemical Kinetics II
  127. 12.01: Reaction Mechanisms
  128. 12.02: Concentration Profiles for Some Simple Mechanisms
  129. 12.03: The Connection between Reaction Mechanisms and Reaction Rate Laws
  130. 12.04: The Rate Determining Step Approximation
  131. 12.05: The Steady-State Approximation
  132. 12.06: The Equilibrium Approximation
  133. 12.07: The Lindemann Mechanism
  134. 12.08: The Michaelis-Menten Mechanism
  135. 12.09: Chain Reactions
  136. 12.10: Catalysis
  137. 12.11: Oscillating Reactions
  138. 12.E: Chemical Kinetics II (Exercises)
  139. 12.S: Chemical Kinetics II (Summary)