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CHE 267 - Organic Chemistry I

CHE 267 is the first semester of university-level organic chemistry. Study of organic structure, reactions and mechanisms. Includes relationship of structure to function.

Chemistry

Tác giả: Layne Morsch
Nhà xuất bản: University of Illinois Springfield
Nguồn: LibreTexts
Giấy phép: CC BY-NC-SA
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

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Mục lục· 205 mục

Chapters
Chapter 01: Structure and Bonding
1.01: The Periodic Table
1.02: Bonding
1.03: Lewis Structures
1.04: Lewis Structures Continued
1.05: Resonance
1.06: Determining Molecular Shape
1.07: Drawing Organic Structures
1.08: Hybridization
1.09: Hybridization Examples
1.10 Bond Length and Bond Strength
1.11: Electronegativity and Bond Polarity
1.12: Polarity of Molecules
Chapter 02: Acids and Bases
5.1: BrnstedLowry Acids and Bases
5.2: Acid Strength and pKa
5.3: Predicting the Outcome of AcidBase Reactions
5.4: Factors That Determine Acid Strength
5.5: Common Acids and Bases
5.6: Lewis Acids and Bases
Chapter 02: Introduction to Organic Molecules and Functional Groups
2.1: An Overview of Functional Groups
2.2: Intermolecular Forces
2.3: Physical Properties
2.4: Application: Vitamins
2.5: Application of Solubility: Soap
2.6: Application: The Cell Membrane
2.7: Functional Groups and Reactivity
2.8: Biomolecules
Chapter 04: Alkanes
3.01 Alkanes-An Introduction
3.02: Cycloalkanes
3.03: An Introduction to Nomenclature
3.04: Naming Alkanes
3.05: Naming Cycloalkanes
3.06: Common Names
3.07: Physical Properties of Alkanes
3.08: Conformations of Acyclic AlkanesEthane
3.09: Conformations of Butane
3.10: An Introduction to Cycloalkanes
3.11: Cyclohexane
3.12: Substituted Cycloalkanes
313: LipidsPart 1
Chapter 05: Stereochemistry
4.01: The Two Major Classes of Isomers
4.02: Looking Glass ChemistryChiral and Achiral Molecules
4.03: Stereogenic Centers
4.04: Labeling Stereogenic Centers with R or S
4.05: Diastereomers
4.06: Fischer Projections and Meso Compounds
4.07: R and S Assignments in Compounds with Two or More Stereogenic Centers
4.08: Disubstituted Cycloalkanes
4.09: IsomersA Summary
4.10: Physical Properties of Stereoisomers
4.11: Chemical Properties of Enantiomers
Chapter 06: Understanding Organic Reactions
6.01: Writing Equations for Organic Reactions
6.02: Kinds of Organic Reactions
6.03: Drawing Organic Mechanisms
6.05: Thermodynamics
6.06: Enthalpy and Entropy
6.07: Energy Diagrams
6.08: Energy Diagram for a Two-Step Reaction Mechanism
6.08: Kinetics
6.09: Catalysts
6.10: Enzymes
6.99: Bond Dissociation Energy
Chapter 07: Alkyl Halides and Nucleophilic Substitution
7.01: Introduction to Alkyl Halides
7.02: Nomenclature
7.03: Physical Properties
7.04: Interesting Alkyl Halides
7.05: The Polar CarbonHalogen Bond
7.06: General Features of Nucleophilic Substitution
7.07: The Leaving Group
7.08: The Nucleophile
7.09: Two Mechanisms for Nucleophilic Substitution
7.10: The SN2 Mechanism
7.11: Application: Useful SN2 Reactions
7.12: The SN1 Mechanism
7.13: Carbocation Stability
7.14: The Hammond Postulate
7.15: When Is the Mechanism SN1 or SN2
7.16: Vinyl Halides and Aryl Halides
7.17: Introduction to Organic Synthesis
Chapter 08: Alkyl Halides and Elimination Reactions
8.01: General Features of Elimination
8.03: The Mechanisms of Elimination
8.04: The E2 Mechanism
8.05: The Zaitsev Rule
8.06: The E1 Mechanism
8.07: SN1 and E1 Reactions
8.08: Stereochemistry of the E2 Reaction
8.09: E2 Reactions and Alkyne Synthesis
802: AlkenesThe Products of Elimination Reactions
810: When Is the Reaction SN1 SN2 E1 or E2
Chapter 09: Alcohols Ethers and Epoxides
9.01: Introduction
9.02: Structure and Bonding
9.03: Nomenclature
9.04: Physical Properties
9.05: Interesting Alcohols Ethers and Epoxides
9.06: Preparation of Alcohols Ethers and Epoxides
9.07: General FeaturesReactions of Alcohols Ethers and Epoxides
9.08: Dehydration of Alcohols to Alkenes
9.09: Carbocation Rearrangements
9.10: Dehydration Using (POCl 3) and Pyridine
9.11: Conversion of Alcohols to Alkyl Halides with HX
9.12: Conversion of Alcohols to Alkyl Halides with SOCl2 and PBr3
9.13: TosylateAnother Good Leaving Group
9.14: Reaction of Ethers with Strong Acid
9.15: Reactions of Epoxides
9.16: Application: Epoxides Leukotrienes and Asthma
Chapter 10: Alkenes
10.01: Introduction
10.02: Calculating Degrees of Unsaturation
10.03: Nomenclature
10.04: Physical Properties
10.05: Preparation of Alkenes
10.06: Introduction to Addition Reactions
10.07: HydrohalogenationElectrophilic Addition of HX
10.08: Markovnikovs Rule
10.09: Stereochemistry of Electrophilic Addition of HX
10.10: HydrationElectrophilic Addition of Water
10.11: HalogenationAddition of Halogen
10.12: Stereochemistry of Halogenation
10.13: HydroborationOxidation
10.14: Interesting Alkenes
10.15: Lipids—Part 2
10.16: Keeping Track of Reactions
Chapter 11: Alkynes
11.01: Introduction
11.02: Nomenclature
11.03: Physical Properties
11.04: Interesting Alkynes
11.05: Preparation of Alkynes
11.06: Introduction to Alkyne Reactions
11.07: Addition of Hydrogen Halides
11.08: Addition of Halogen
11.09: Addition of Water
11.10: HydroborationOxidation of Alkynes
11.11: Reaction of Acetylide Anions
11.12: Synthesis
Chapter 12: Oxidation and Reduction
12.01: Introduction
12.02: Reducing Agents
12.03: Reduction of Alkenes
12.04: Application: Hydrogenation of Oils
12.05: Reduction of Alkynes
12.06: The Reduction of Polar CX Bonds
12.07: Oxidizing Agents
12.08: Epoxidation
12.09: Dihydroxylation
12.10: Oxidative Cleavage of Alkenes
12.11: Oxidative Cleavage of Alkynes
12.12: Oxidation of Alcohols
Chapter 13: Benzene and Aromatic Compounds
13.01 Background of Aromaticity
13.02 The Structure of Benzene
13.03 Nomenclature of Benzene Derivatives
13.04 Spectroscopic Properties
13.05 Interesting Aromatic Compounds
13.06 Benzenes Unusual Stability
13.07 The Criteria for AromaticityHuckels Rule
13.08 Examples of Aromatic Compounds
13.09 What Is the Basis of Huckels Rule
13.10 The Inscribed Polygon Method for Predicting Aromaticity
Chapter 20: Introduction to Carbonyl Chemistry Organometallic Reagents Oxidation and Reduction
20.01: Introduction
20.02: General Reactions of Carbonyl Compounds
20.03: A Preview of Oxidation and Reduction
20.04: Reduction of Aldehydes and Ketones
20.05: The Stereochemistry of Carbonyl Reduction
20.06: Enantioselective Carbonyl Reductions
20.07: Reduction of Carboxylic Acids and Their Derivatives
20.08: Oxidation of Aldehydes
20.09: Organometallic Reagents
20.10: Reaction of Organometallic Reagents with Aldehydes and Ketones
20.11: Retrosynthetic Analysis of Grignard Products
20.12: Protecting Groups
20.13: Reaction of Organometallic Reagents with Carboxylic Acid Derivatives
20.14: Reaction of Organometallic Reagents with Other Compounds
20.17: Synthesis
2015: ,-Unsaturated Carbonyl Compounds
2016: SummaryThe Reactions of Organometallic Reagents
Chapter 21: Aldehydes and KetonesNucleophilic Addition
21.01: Introduction
21.02: Nomenclature
21.03: Physical Properties
21.04: Spectroscopic Properties
21.05: Interesting Aldehydes and Ketones
21.06: Preparation of Aldehydes and Ketones
21.10: The Wittig Reaction
21.15: Acetals as Protecting Groups
21.16: Cyclic Hemiacetals
21.17: An Introduction to Carbohydrates
2107: Reactions of Aldehydes and KetonesGeneral Considerations
2108: Nucleophilic Addition of H and RA Review
2109: Nucleophilic Addition of CN
2111: Addition of 1 Amines
2112: Addition of 2 Amines
2113: Addition of H2OHydration
2114: Addition of AlcoholsAcetal Formation
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