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Organic Chemistry I
This Libretext is for the first semester of organic chemistry at Providence College. The course materials have been adapted from the lecture notes I have accumulated over the years and Organic Chemistry, 5th edition, by Maitland Jones, Jr. and Stephen Fleming. Course topics include organic structure and bonding, nomenclature, conformational analysis, structure elucidation, stereochemistry, substitution and elimination reactions, and reactions of alkenes and alkynes.
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Mục lục· 60 mục
- 01: Introduction to Organic Chemistry
- 1.01: Line Angle Notation as the Language of Chemical Structure
- 1.02: Using Chemical Arrows
- 1.03: Resonance
- 1.04: Acids and Bases
- 1.05: Guiding Principles of Organic Chemistry
- 02: Bonding in Organic Molecules
- 2.01: Lewis and Valence Bond Models
- 2.02: Molecular Orbital Theory
- 2.03: Bonding in Symmetrical Hydrocarbons
- 2.04: Bonding in Unsymmetrical Systems
- 03: Simple Hydrocarbons
- 3.01: Nomenclature
- 3.02: Conformations of Acyclic Hydrocarbons
- 3.03: Conformations of Substituted Hydrocarbons
- 04: Rings
- 4.01: Cyclohexane Ring Conformations
- 4.02: A-values and Equilibrium Ratios
- 4.03: Converting Between Chair Conformations
- 4.04: Other Ring Conformations
- 4.05: 4.5 Fused Ring Systems
- 05: Analytical Methods for Structure Elucidation
- 5.01: The Physics of Nuclear Magnetic Resonance Spectroscopy
- 5.02: 5.2 Determining the Number of Signals in NMR Spectroscopy
- 5.03: Factors That Influence NMR Chemical Shift
- 5.04: Infrared Spectroscopy
- 5.05: Mass Spectrometry
- 06: Alkenes
- 6.01: Cahn-Ingold-Prelog Convention
- 6.02: Bonding Stereoisomerism and Stability
- 6.03: Electrophilic Addition
- 6.04: Acid-Catalyzed Hydration
- 07: Stereochemistry
- 7.01: The Fundamentals
- 7.02: Chirality
- 7.03: Absolute Configuration
- 7.04: Fisher Projections
- 7.05: Determining Numbers of Stereoisomers
- 7.06: Creating Chiral Centers
- 7.07: Resolution
- 08: Substitution Reactions
- 8.01: Substituted Alkanes
- 8.02: Polarity Acidity and Solubility
- 8.03: The Basics of Determining Mechanism
- 8.04: Nucleophilic Substitution - 1st Order
- 8.05: Nucleophilic Substitution - 2nd Order
- 8.06: Converting Alcohols into Better Leaving Groups
- 8.07: Peculiarities in Substitution Chemistry
- 09: Elimination Reactions
- 9.01: First Order Eliminations
- 9.02: Second Order Eliminations
- 9.03: Rearrangement of Carbocations
- 10: Addition Reactions of Alkenes
- 10.01: Hydrogenation
- 10.02: Concerted Cycloadditions
- 10.03: Polymerization Reactions
- 11: Synthesis and Reactivity of Alkynes
- 11.01: Synthesis of Alkynes
- 11.02: Alkyne Reduction and Electrophilic Addition
- 11.03: Cycloaddition Reactions of Alkynes