Nguồn ngoài

University of Arkansas at Little Rock: Chem 3572 Physical Chemistry for Life Sciences

Chemistry

Tác giả: Noureen Siraj
Nhà xuất bản: University of Arkansas at Little Rock
Nguồn: LibreTexts
Giấy phép: CC BY-NC-SA
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

Đọc trực tuyến Tải PDF (nguồn mở)

Mục lục· 150 mục

01: Introduction to Physical Chemistry
1.01: Nature of Physical Chemistry
1.02: Units
1.03: Atomic Mass Molecular Mass and the Chemical Mole
02: Properties of Gases
2.01: Some Definitions
2.02: An Operational Definition of Temperature
2.03: Ideal Gases
2.04: Real Gases
2.05: Condensation of Gases and the Critical State
2.06: Kinetic Theory of Gases
2.07: The Maxwell Distribution Laws
2.08: Molecular Collisions and the Mean Free Path
2.09: Graham's Laws of Diffusion and Effusion
2.10: Properties of Gases (Exercises)
03: The First Law of Thermodynamics
3.01: Work and Heat
3.02: The First Law of Thermodynamics
3.03: Heat Capacities
3.04: Gas Expansion
3.05: Calorimetry
3.06: Thermochemistry
3.07: Bond Energies and Bond Enthalpies
3.08: Exercises
04: The Second Law of Thermodynamics
4.01: Spontaneous Processes
4.02: Entropy
4.03: The Second Law of Thermodynamics
4.04: Entropy Changes
4.05: The Third Law of Thermodynamics
4.06: Gibbs Energy
4.07: Standard Molar Gibbs Energy of Formation
4.08: Dependence of Gibbs Energy on Temperature and Pressure
4.09: Phase Equilibria
4.10: Thermodynamics of Rubber Elasticity
4.11: Exercises
05: Solutions
5.01: Concentration Units
5.02: Partial Molar Quantities
5.03: The Thermodynamics of Mixing
5.04: Binary Mixtures of Volatile Liquids
5.05: Real Solutions
5.06: Colligative Properties
5.07: Electrolyte Solutions
5.08: Ionic Activity
5.09: Colligative Properties of Electrolyte Solutions
5.10: Biological Membranes
5.11: Solutions (Exercises)
06: Chemical Equilibrium
6.01: Chemical Equilibrium in Gaseous Systems
6.02: Reactions in Solutions
6.03: Heterogeneous Equilibria
6.04: The Influence of Temperature Pressure and Catalysts on the Equilibrium Constant
6.05: Binding of Ligands and Metal Ions to Macromolecules
6.06: Bioenergetics
6.07: Chemical Equilibrium (Exercises)
07: Electrochemistry
7.01: Electrochemical Cells
7.02: Single Electrode Potentials
7.03: Thermodynamics of Electrochemical Cells
7.04: Types of Electrochemical Cells
7.05: Applications of EMF Measurements
7.06: Biological Oxidation
7.07: Membrane Potential
7.08: Electrochemistry (Exercises)
08: Acids and Bases
8.01: Definitions of Acids and Bases
8.02: Acid-Base Properties of Water
8.03: Dissociation of Acids and Bases
8.04: Diprotic and Polyprotic Acids
8.05: Buffer Solutions
8.06: Acid-Base Titrations
8.07: Amino Acids
8.08: Maintaining the pH of Blood
09: Chemical Kinetics
9.01: Reaction Rates
9.02: Reaction Order
9.03: Molecularity of a Reaction
9.04: More Complex Reactions
9.05: The Effect of Temperature on Reaction Rates
9.06: Potential Energy Surfaces
9.07: Theories of Reaction Rates
9.08: Isotope Effects in Chemical Reactions
9.09: Reactions in Solution
9.10: Fast Reactions in Solution
9.11: Oscillating Reactions
9.12: Chemical Kinetics (Exercises)
10: Enzyme Kinetics
10.01: General Principles of Catalysis
10.02: The Equations of Enzyme Kinetics
10.03: Chymotrypsin as a Case Study
10.04: Multisubstrate Systems
10.05: Enzyme Inhibition
10.06: Allosteric Interactions
10.07: The Effect of pH on Enzyme Kinetics
10.08: The Effect of Temperature on Enzyme Kinetics
10.09: Exercises
11: Quantum Mechanics and Atomic Structure
11.01: The Wave Theory of Light
11.02: Planck's Quantum Theory
11.03: The Photoelectric Effect
11.04: Bohr's Theory of the Hydrogen Emission Spectrum
11.05: de Broglie's Postulate
11.06: The Heisenberg Uncertainty Principle
11.07: The Schrodinger Wave Equation
11.08: Particle in a One-Dimensional Box
11.09: Quantum-Mechanical Tunneling
11.10: The Schrodinger Wave Equation for the Hydrogen Atom
11.11: Many-Electron Atoms and the Periodic Table
11.12: Quantum Mechanics and Atomic Structure (Exercises)
12: The Chemical Bond
12.01: Lewis Structures
12.02: Valence Bond Theory
12.03: Hybridization of Atomic Orbitals
12.04: Electronegativity and Dipole Moment
12.05: Molecular Orbital Theory
12.06: Diatomic Molecules
12.07: Resonance and Electron Delocalization
12.08: Coordination Compounds
12.09: Coordination Compounds in Biological Systems
12.10: The Chemical Bond (Exercises)
13: Intermolecular Forces
13.01: Intermolecular Interactions
13.02: The Ionic Bond
13.03: Types of Intermolecular Forces
13.04: Hydrogen Bonding
13.05: The Structure and Properties of Water
13.06: Hydrophobic Interaction
13.07: Intermolecular Forces (Exercises)
14: Spectroscopy
14.01: Vocabulary
14.02: Microwave Spectroscopy
14.03: Infrared Spectroscopy
14.04: Electronic Spectroscopy
14.05: Nuclear Magnetic Resonance
14.06: Electron Spin Resonance
14.07: Fluorescence and Phosphorescence
14.08: Lasers
14.09: Optical Rotatory Dispersion and Circular Dichroism
14.10: Spectroscopy (Exercises)
15: Photochemistry and Photobiology
15.01: Introduction to Photochemistry
15.02: Photosynthesis
15.03: Vision
15.04: Biological Effects of Radiation
16: Macromolecules
16.01: Size Shape and Molar Mass of Macromolecules
16.02: Structure of Synthetic Polymers
16.03: Structure of Proteins and DNA
16.04: Protein Stability