Nguồn ngoài

Statistical Thermodynamics

Basics of statistical mechanics and thermodynamics of classical and quantum systems. Concept of ensembles, microcanonical and canonical ensembles, ergodic theorem. Molecular and canonical partition functions and their connection with classical thermodynamics. Quantum statistics. Translational, rotational, vibrational, electronic and nuclear spin partition functions of gases. Determination of the equilibrium constants of gas phase reactions.

Physical and Theoretical Chemistry Textbook Maps Chemistry

Tác giả: Gunnar Jeschke
Nhà xuất bản: ETH Zürich
Nguồn: LibreTexts
Giấy phép: CC BY-NC
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

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Mục lục· 32 mục

01: Basics of Statistical Mechanics
1.01: Basic Assumptions of Statistical Thermodynamics
1.02: Phase space
1.03: Statistical Mechanics Based on Postulates
02: Probability Theory
2.01: Discrete Probability Theory
2.02: Continuous Probability Theory
03: Classical Ensembles
3.01: Statistical Ensembles
3.02: Microcanonical Ensemble
3.03: Canonical Ensemble
3.04: Grand Canonical Ensemble
04: Entropy
4.01: Swendsens Postulates of Thermodynamics
4.02: The Relation of State Functions to the Partition Function
4.03: Irreversibility
4.04: Entropy and Information
05: Quantum Ensembles
5.01: Quantum Canonical Ensemble
5.02: Quantum and Classical Statistics
5.03: Simple Quantum Systems
06: Partition Functions of Gases
6.01: Separation of Contributions
6.02: Translational Partition Function
6.03: Nuclear Spin Partition Function
6.04: Rotational Partition Function
6.05: Vibrational Partition Function
6.06: Electronic Partition Function
6.07: Equilibrium Constant for Gas Reactions
07: Macromolecules
7.01: Thermodynamics of Mixing
7.02: Entropic Elasticity