
Nguồn ngoài
AUCHE 252 - Organic Chemistry II
- Tác giả
- Brian Rempel
- Nhà xuất bản
- Augustana Faculty, University of Alberta
- Nguồn
- LibreTexts
- Ngôn ngữ
- EN
- Danh mục
- Khoa học cơ bản
Mục lục· 65 mục
- 01: Carbonyl Reactivity
- 1.01: Structure of the Carbonyl Group
- 1.02: Reactivity of the Carbonyl Group- Mechanisms of Addition
- 02: 1H NMR
- 2.01: Index of Hydrogen Deficiency (IHD)
- 2.02: Nuclear Magnetic Resonance Spectroscopy
- 2.03: The Nature of NMR Absorptions
- 2.04: Chemical Shifts
- 2.05: Chemical Shifts in H NMR Spectroscopy
- 2.06: Integration of H NMR Absorptions- Proton Counting
- 2.07: Spin-Spin Splitting in H NMR Spectra
- 2.08: H NMR Spectroscopy and Proton Equivalence
- 2.09: More Complex Spin-Spin Splitting Patterns
- 2.10: Uses of H NMR Spectroscopy
- 03: Alcohols and Ethers
- 3.01: Preparing Ethers
- 3.02: Crown Ethers
- 3.03: Reactions of Ethers- Acidic Cleavage
- 3.04: Cyclic Ethers - Epoxides
- 3.05: Reactions of Epoxides- Ring-opening
- 3.06: Nomenclature of Alcohols
- 3.07: Reactions of Alcohols
- 3.08: Conversion of Alcohols to Alkyl Halides with SOCl2 and PBr3
- 3.09: Protecting Groups in Organic Synthesis
- 04: Redox Reactions
- 4.01: Oxidation and Reduction of Organic Compounds - An Overview
- 4.02: Nucleophilic Addition of Hydride and Grignard Reagents- Alcohol Formation
- 4.03: Oxidation of Alcohols
- 05: Aldehydes and Ketones
- 5.01: Keto-Enol Tautomerism
- 5.02: Reactivity of Enols- The Mechanism of Alpha-Substitution Reactions
- 5.03: Alpha Halogenation of Aldehydes and Ketones
- 5.04: Reactivity of Enolate Ions
- 5.05: Alkylation of Enolate Ions
- 5.06: Carbonyl Condensations - The Aldol Reaction
- 5.07: Carbonyl Condensations versus Alpha Substitutions
- 5.08: Dehydration of Aldol Products - Synthesis of Enones
- 5.09: Mixed Aldol Reactions
- 5.10: Intramolecular Aldol Reactions
- 5.11: Nucleophilic Addition of Water- Hydration
- 5.12: Nucleophilic Addition of Alcohols- Acetal Formation
- 5.13: Nucleophilic Addition of Amines- Imine and Enamine Formation
- 06: Carboxylic Acid Derivatives
- 6.01: Nucleophilic Acyl Substitution Reactions
- 6.02: Nucleophilic Acyl Substitution Reactions of Carboxylic Acids
- 6.03: The Claisen Condensation Reaction
- 6.04: Mixed Claisen Condensations
- 6.05: Intramolecular Claisen Condensations - The Dieckmann Cyclization
- 07: Conjugated Pi Systems
- 7.01: Stability of Conjugated Dienes- Molecular Orbital Theory
- 7.02: Electrophilic Additions to Conjugated Dienes- Allylic Carbocations
- 7.03: Kinetic vs. Thermodynamic Control of Reactions
- 7.04: Naming Aromatic Compounds
- 7.05: Structure and Stability of Benzene
- 7.06: Aromaticity and the Huckel 4n 2 Rule
- 7.07: Aromatic Ions
- 7.08: Aromatic Heterocycles - Pyridine and Pyrrole
- 08: Electrophilic Aromatic Substitutions
- 8.01: Introduction
- 8.02: Electrophilic Aromatic Substitution Reactions - Bromination
- 8.03: Other Aromatic Substitutions
- 8.04: Alkylation and Acylation of Aromatic Rings - The Friedel-Crafts Reaction
- 8.05: Substituent Effects in Substituted Aromatic Rings
- 8.06: An Explanation of Substituent Effects
- 8.07: Clemmensen Reduction