Nguồn ngoài

Structure & Reactivity V: Reactivity in Organic, Biological and Inorganic Chemistry 3

Redox Reactions, Radical Reactions, Photochemistry, Pericyclic Reactions

General Chemistry Chemistry

Tác giả: Chris Schaller
Nhà xuất bản: College of Saint Benedict/Saint John's University
Nguồn: LibreTexts
Giấy phép: CC BY-NC
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

Đọc trực tuyến Tải PDF (nguồn mở)

Mục lục· 103 mục

01: Reduction and Oxidation Reactions
1.01: Oxidation State
1.02: Redox Reactions
1.03: Reduction Potential
1.04: Reduction Potential and Energy Levels
1.05: Factors Influencing Redox Potential
1.06: Reduction of Ores
1.07: Reduction in Batteries
1.08: Balancing Redox Reactions
1.09: Outer Sphere Electron Transfer
1.10: Inner Sphere Electron Transfer
1.11: Cyclic Voltammetry
1.12: Organic Redox
1.13: Potential and Concentrations
1.14: Solutions to Selected Problems
02: Reduction Potentials of Metal Ions in Biology
2.01: Introduction
2.02: The Effect of Charge (Local Effects)
2.03: Effect of Charge- Distal Effects or Effects of the Medium
2.04: The Effect of pH
2.05: Hard and Soft Acid and Base Considerations
2.06: Effect of Geometry
2.07: Magnetic Measurements
2.08: Solutions for Selected Problems
03: Understanding Mechanism
3.01: Intermediates
3.02: Energetics
3.03: Arrow Conventions
3.04: Solutions to Selected Problems
04: Oxygen Binding and Reduction
4.01: Introduction
4.02: Oxygen Binding
4.03: Oxygen Reduction
4.04: Metal Oxos
4.05: Solutions to Selected Problems
05: Nitrogen Reduction
5.01: Introduction to Nitrogen Reduction
5.02: The Haber-Bosch Process
5.03: Nitrogenase
5.04: Model Studies for Nitrogen Binding
5.05: Model Studies for Nitrogen Reduction
5.06: Solutions for Selected Problems
06: Radical Reactions
6.01: Introduction to Radicals
6.02: Radical Initiation- Bond Homolysis
6.03: Radical Initiation- Radical Stability
6.04: Radical Initiation- Single Electron Transfer
6.05: Radical Propagation
6.06: Radical Termination
6.07: Radical Substitution
6.08: Radical Addition
6.09: Radical Polymerization
6.10: Living Radical Polymerisation
6.11: Detection of Unpaired Electrons
6.12: Solutions for Selected Problems
07: Oxidative Phosphorylation
7.01: Introduction to Oxidative Phosphorylation
7.02: Complex I
7.03: Complex II
7.04: Complex III
7.05: Complex IV
7.06: Complex V
7.07: Solutions for Selected Problems
08: Photochemical Reactions
8.01: Absorbance
8.02: Rules of Absorbance
8.03: Fluorescence and Phosphorescence
8.04: Photolysis
8.05: Atmospheric Photochemistry- Ozone
8.06: Applications of Photochemistry- Photoredox Catalysis
8.07: Photoredox Catalysis in Organic Chemistry
8.08: Solutions to Selected Problems
09: Photosynthesis
9.01: Solutions to Selected Problems
9.02: Introduction to Photosynthesis
9.03: Photosystem II- Harvesting the Photons
9.04: Photosystem II- Electron Transfer
9.05: Photosystem II - The Oxygen-Evolving Complex
9.06: Adding a Proton Pump- Cytochrome b6f Complex
9.07: Harvesting the Photons- Photosystem I
9.08: ATP Synthase
9.09: Carbon Capture and Carbohydrate Pool
9.10: Additional Problems
10: Reactions Under Orbital Control
10.01: Introduction
10.02: Cope and Claisen Rearrangements
10.03: The Diels Alder Reaction
10.04: Regiochemistry in Diels Alder Reactions
10.05: Endo and Exo Products
10.06: Photochemical Cycloaddition
10.07: Facial Selectivity
10.08: Alkene Oxidations
10.09: Decarboxylations
10.10: Olefin Metathesis
10.11: Sigma Bond Metathesis
10.12: Solutions to Selected Problems
11: Electrophilic Rearrangement
11.01: Introduction
11.02: Pinacol Rearrangement
11.03: Baeyer-Villiger Rearrangement
11.04: Beckmann Rearrangement
11.05: Wolff Rearrangement
11.06: Solutions