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EM 4300: Inorganic Chemistry

Topics in inorganic chemistry, including molecular structure and bonding, symmetry, ionic structure and bonding, inorganic reactions, including acid base and oxidation-reduction reactions, coordination chemistry and bioinorganic chemistry.

Chemistry

Tác giả: Larry Mink
Nhà xuất bản: CSU San Bernardino
Nguồn: LibreTexts
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

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Mục lục· 143 mục

01: Atomic Structure
1.01: Historical Development of Atomic Theory
1.02: The quantum-mechanical model of the atom
1.03: Periodic Properties of Atoms
1.04: Concept Review Questions Chapter 1
1.05: Homework Problems Chapter 1
02: Symmetry and Group Theory
2.01: Symmetry Elements and Operations
2.02: Point Groups
2.03: Matrix Representations of Symmetry Operations and Character Tables
2.04: Concept Review Questions Chapter 2
2.05: Homework Problems Chapter 2
03: Review of Chemical Bonding
3.01: Prelude to Chemical Bonding
3.02: Valence Bond Theory- Lewis Dot Structures the Octet Rule Formal Charge Resonance and the Isoelectronic Principle
3.03: The Shapes of Molecules (VSEPR Theory) and Orbital Hybridization
3.04: Bond Polarity and Bond Strength
3.05: Discussion Questions
3.06: Problems
3.07: References
04: Molecular Orbital Theory
4.01: Prelude to Molecular Orbital Theory
4.02: Constructing Molecular Orbitals from Atomic Orbitals
4.03: Orbital Symmetry
4.04: and orbitals
4.05: Diatomic Molecules
4.06: Orbital Filling
4.07: Periodic Trends in Bonding
4.08: Three-center Bonding
4.09: Building up the MOs of More Complex Molecules- NH P
4.10: Homology of and orbitals in MO diagrams
4.11: Chains and Rings of -Conjugated Systems
4.12: Discussion Questions
4.13: Problems
4.14: References
05: Coordination Chemistry I - Structures and Isomers
5.01: History
5.02: Nomenclature
5.03: Coordination Numbers and Structures
5.04: Isomerism
5.05: Concept Review Questions Chapter 5
5.06: Homework Problems Chapter 5
06: Coordination Chemistry III - Bonding
6.01: 7.1 Bonding in Coordination Compounds
6.02: Concept Review Questions Chapter 7
6.03: Homework Problems Chapter 7
07: Metals and Alloys- Structure Bonding Electronic and Magnetic Properties
7.01: Prelude to Metals and Alloys
7.02: Unit Cells and Crystal Structures
7.03: Bravais Lattices
7.04: Crystal Structures of Metals
7.05: Bonding in Metals
7.06: Conduction in Metals
7.07: Atomic Orbitals and Magnetism
7.08: Ferro- Ferri- and Antiferromagnetism
7.09: Hard and Soft Magnets
7.10: Discussion Questions
7.11: Problems
7.12: References
08: Metals and Alloys - Mechanical Properties
8.01: Defects in Metallic Crystals
8.02: Work Hardening Alloying and Annealing
8.03: Malleability of Metals and Alloys
8.04: Iron and Steel
8.05: Amorphous Alloys
8.06: Discussion Questions
8.07: Problems
8.08: References
09: Ionic and Covalent Solids - Structures
9.01: Prelude to Ionic and Covalent Solids - Structures
9.02: Close-packing and Interstitial Sites
9.03: Structures Related to NaCl and NiAs
9.04: Tetrahedral Structures
9.05: Layered Structures and Intercalation Reactions
9.06: Bonding in TiS MoS and Pyrite Structures
9.07: Spinel Perovskite and Rutile Structures
9.08: Discussion Questions
9.09: Problems
9.10: References
10: Ionic and Covalent Solids - Energetics
10.01: Ionic Radii and Radius Ratios
10.02: Structure Maps
10.03: Energetics of Crystalline Solids- The Ionic Model
10.04: Born-Haber Cycles for NaCl and Silver Halides
10.05: Kapustinskii Equation
10.06: Discovery of Noble Gas Compounds
10.07: Stabilization of High and Low Oxidation States
10.08: Alkalides and Electrides
10.09: Resonance Energy of Metals
10.10: Prelude to Ionic and Covalent Solids - Energetics
10.11: The Strange Case of the Alkali Oxides
10.12: Lattice Energies and Solubility
10.13: Discussion Questions
10.14: Problems
10.15: References
11: Electronic Properties of Materials - Superconductors and Semiconductors
11.01: Prelude to Electronic Properties of Materials - Superconductors and Semiconductors
11.02: Metal-Insulator Transitions
11.03: Superconductors
11.04: Periodic Trends- Metals Semiconductors and Insulators
11.05: Semiconductors- Band Gaps Colors Conductivity and Doping
11.06: Semiconductor p-n Junctions
11.07: Diodes LEDs and Solar Cells
11.08: Amorphous Semiconductors
11.09: Discussion Questions
11.10: Problems
11.11: References
12: Physical Techniques in Inorganic Chemistry
13: Coordination Chemistry IV - Electronic Spectra
13.01: Microstates and Terms
13.02: Term splitting in ligand fields selection rules Tanabe-Sugano diagrams. Metal to ligand and ligand to metal transitions
13.03: Concept Review Questions Chapter 8
13.04: Homework Problems Chapter 8
14: Coordination Chemistry V - Reactions and Mechanisms
14.01: Substitution Reactions and their Mechanisms
14.02: Concept Review Questions Chapter 9
14.03: Homework Problems Chapter 9
15: Acid-Base Chemistry
15.01: Prelude to Acid-Base Chemistry
15.02: Brnsted and Lewis Acids and Bases
15.03: Hard and Soft Acids and Bases
15.04: The Electrostatic-Covalent (ECW) Model for Acid-Base Reactions
15.05: Frustrated Lewis Pairs
15.06: Discussion Questions
15.07: Problems
15.08: References
16: Redox Stability and Redox Reactions
16.01: Prelude to Redox Stability and Redox Reactions
16.02: Balancing Redox Reactions
16.03: Electrochemical Potentials
16.04: Latimer and Frost Diagrams
16.05: Redox Reactions with Coupled Equilibria
16.06: Pourbaix Diagrams
16.07: Discussion Questions
16.08: Problems
16.09: References
17: Transition-Metal Storage Transport and Biomineralization
17.01: Biological Significance of Iron Zinc Copper Molybdenum Cobalt Chromium Vanadium and Nickel
17.02: Biological Systems of Metal Storage
17.03: Chemical Properties Relative to Storage and Transport
17.04: Iron Biomineralization
17.05: Transport of Iron
17.06: Transport of Zinc Copper Vanadium Chromium Molybdenum and Cobalt