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Chem 26505: Organic Chemistry I

Nguồn ngoài

Chem 26505: Organic Chemistry I

A comprehensive study of the chemical principles underlying aliphatic and aromatic compounds. The syntheses and reactions of these materials are discussed. Modern theory and stereochemistry are stressed to illustrate the logic inherent in the subject matter and to demonstrate the predictability of many chemical transformations. Recommended for students majoring in chemistry.

Chemistry
Tác giả
Mark Lipton
Nhà xuất bản
Purdue University
Nguồn
LibreTexts
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CC BY-NC-SA
Ngôn ngữ
EN
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Mục lục· 76 mục
  1. Chapter 1. Electronic Structure and Chemical Bonding
  2. 1.01 Electronic Configuration of Atoms
  3. 1.02 The Octet Rule and Covalent Bonding
  4. 1.03 Valence electrons and open valences
  5. 1.04 Formal Charge
  6. 1.05: Resonance
  7. 1.06 Electronegativity and Bond Polarization
  8. 1.07 Atomic Orbitals and Covalent Bonding
  9. 1.08 Hybridization
  10. 1.09 Representation of Molecular Structure
  11. 1.10: Pi Conjugation
  12. 1.11: Aromaticity
  13. Chapter 2. Functional Groups and Nomenclature
  14. 2.01A Alkanes
  15. 2.01B: Cycloalkanes
  16. 2.02 Alkenes
  17. 2.03 Alkynes
  18. 2.04 Arenes
  19. 2.05 Alcohols
  20. 2.06 Ethers, Epoxides and Sulfides
  21. 2.07 Amines
  22. 2.08 Aldehydes and Ketones
  23. 2.09 Carboxylic Acids
  24. 2.10: Esters, Amides, Acid Halides, Anhydrides and Nitriles
  25. 2.050 Functional Groups
  26. Appendix - IUPAC Nomenclature Rules
  27. Chapter 3. Stereochemistry
  28. 3.1 Stereoisomerism
  29. 3.2 Conformations of Alkanes
  30. 3.3 Conformation of Cyclohexane
  31. 3.4 Chirality
  32. 3.5 Enantiomers
  33. 3.6 Cahn-Ingold Prelog Rules
  34. 3.7 Diastereomers
  35. 3.8 Meso Isomers
  36. Trans Isomerism
  37. Chapter 4. Intermolecular Forces and Physical Properties
  38. 4.1 Bond Polarity and Molecular Dipoles
  39. 4.2 Intermolecular Forces
  40. 4.3 Boiling Points
  41. 4.4 Solubility
  42. 4.5 Chromatography
  43. Chapter 5. Spectroscopy
  44. 5.1 Infrared Spectroscopy
  45. 5.2 Mass Spectrometry
  46. 5.3 Nuclear Magnetic Resonance (NMR) Spectroscopy
  47. 5.4 Ultraviolet (UV) Spectroscopy
  48. 5.5 Polarimetry
  49. Chapter 6. Reactive Intermediates
  50. 6.1 Carbocations
  51. 6.2: Carbanions
  52. 6.3 Free Radicals
  53. Chapter 7. Reactivity and Electron Movement
  54. 7.1 Nucleophiles and Electrophiles
  55. 7.2 How Electrons Move
  56. 7.3 Basics of Thermodynamics and Kinetics
  57. 7.4 Kinetics
  58. 7.5 Product Distributions
  59. 7.6 Hammond's Postulate
  60. Chapter 8. Acid-Base Reactions
  61. 8.1 Brønsted Acidity and Basicity
  62. 8.2 Factors Affecting Brønsted Acidity
  63. 8.3: pKa Values
  64. 8.4 Solvent Effects
  65. Chapter 9. Isomerization Reactions
  66. 9.1: Keto-Enol Tautomerization
  67. 9.2: 1,2-Shifts in Carbocations
  68. Course Content
  69. I. Chemical Bonding and Electronic Structure
  70. II. Functional groups and Nomenclature
  71. III. Stereochemistry
  72. IV. Intermolecular interactions and physical properties
  73. V. Reactive intermediates: carbocations, carbanions, free radicals
  74. VI. Spectroscopy
  75. VII. Reactivity and the movement of electrons
  76. VIII. Acid-Base Reactivity