Nguồn ngoài

Kinetics

Chemistry

Nhà xuất bản: Pacific Union College
Nguồn: LibreTexts
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

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Mục lục· 85 mục

01: Boltzmann
02: Boltzmann Statistics
2.01: The Independent-Molecule Approximation
2.02: The Probability of An Energy Level at Constant N, V, and T
2.03: The Population Sets of a System at Equilibrium at Constant N, V, and T
2.04: How can Infinitely Many Probabilities Sum to Unity?
2.05: The Total Probability Sum at Constant N, V, and T
2.06: The Most Probable Population Set at Constant N, V, and T
2.07: The Microstates of a Given Population Set
2.08: The Probabilities of Microstates that Have the Same Energy
2.09: The Probabilities of the Population Sets of an Isolated System
2.10: Entropy and Equilibrium in an Isolated System
2.11: Thermodynamic Probability and Equilibrium in an Isomerization Reaction
2.12: The Degeneracy of an Isolated System and Its Entropy
2.13: The Degeneracy of an Isolated System and its Entropy
2.14: Effective Equivalence of the Isothermal and Constant-energy Conditions
2.15: Problems
03: The Boltzmann Distribution Function
3.01: Finding the Boltzmann Equation
3.02: Lagrange's Method of Undetermined Multipliers
3.03: Deriving the Boltzmann Equation I
3.04: Deriving the Boltzmann Equation II
3.05: Partition Functions and Equilibrium - Isomeric Molecules
3.06: Finding ß and the Thermodynamic Functions for Distinguishable Molecules
3.07: The Microscopic Model for Reversible Change
3.08: The Third Law of Thermodynamics
3.09: The Partition Function for a System of N Molecules
3.10: Problems
04: Some Basic Applications of Statistical Thermodynamics
4.01: Interpreting the Partition Function
4.02: Conditions under which Integrals Approximate Partition Functions
4.03: Probability Density Functions from the Energies of Classical-mechanical Models
4.04: Partition Functions and Average Energies at High Temperatures
4.05: Energy Levels for a Three-dimensional Harmonic Oscillator
4.06: Energy and Heat Capacity of the "Einstein Crystal"
4.07: Applications of Other Entropy Relationships
4.08: Problems
05: The Ensemble Treatment
5.01: Ensembles of N-molecule Systems
5.02: The Ensemble Entropy and the Value of ß
5.03: The Thermodynamic Functions of the N-molecule System
06: The Distribution of Gas Velocities
6.01: Distribution Functions for Gas-velocity Components
6.02: Probability Density Functions for Velocity Components in Spherical Coordinates
6.03: Maxwell's Derivation of the Gas-velocity Probability-density Function
6.04: The Probability-density Function for Gas Velocities in One Dimension
6.05: Combining the One-dimensional Probability Density Functions
6.06: Boyle's Law from the Maxwell-Boltzmann Probability Density
6.07: Experimental Test of the Maxwell-Boltzmann Probability Density
6.08: Statistics for Molecular Speeds
6.09: Pressure Variations for Macroscopic Samples
6.10: Collisions between Gas Molecules Relative Velocity Coordinates
6.11: The Probability Density Function for the Relative Velocity
6.12: The Frequency of Collisions between Unlike Gas Molecules
6.13: The Rate of Collisions between Unlike Gas Molecules
6.14: Collisions between like Gas Molecules
6.15: The Geometry of A Collision between Spherical Molecules
6.16: The Energy of A Collision between Gas Molecules
6.17: Problems
07: Diffusion
08: Chemical Kinetics
8.01: Reaction Rates
8.02: Reaction Order
8.03: Molecularity of a Reaction
8.04: More Complex Reactions
8.05: The Effect of Temperature on Reaction Rates
8.06: Potential Energy Surfaces
8.07: Theories of Reaction Rates
8.08: Isotope Effects in Chemical Reactions
8.09: Reactions in Solution
8.10: Fast Reactions in Solution
8.11: Oscillating Reactions
8.E: Chemical Kinetics (Exercises)
09: Enzyme Kinetics
9.01: General Principles of Catalysis
9.02: The Equations of Enzyme Kinetics
9.03: Chymotrypsin- A Case Study
9.04: Multisubstrate Systems
9.05: Enzyme Inhibition
9.06: Allosteric Interactions
9.07: The Effect of pH on Enzyme Kinetics
9.08: The Effect of Temperature on Enzyme Kinetics
9.E: Exercises
Numerical Solutions to Rate Laws
Numerical Solutions