Nguồn ngoài

An Introduction to the Electronic Structure of Atoms and Molecules

The beginning student of chemistry must have a knowledge of the theory which forms the basis for our understanding of chemistry and he must acquire this knowledge before he has the mathematical background required for a rigorous course of study in quantum mechanics. The present approach is designed to meet this need by stressing the physical or observable aspects of the theory through an extensive use of the electronic charge density.

Physical and Theoretical Chemistry Textbook Maps Chemistry

Tác giả: McMaster University
Nhà xuất bản: Richard F. W. Bader
Nguồn: LibreTexts
Giấy phép: CC BY-NC-SA
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

Đọc trực tuyến Tải PDF (nguồn mở)

Mục lục· 61 mục

01: The Nature of the Problem
1.01: Introduction
1.02: Some Important Experiments with Electrons and Light
1.03: Units of Measurement used in Atomic Physics
1.04: Further Reading
1.E: Exercises
02: The New Physics
2.01: A Contrast of the Old and New Physics
2.02: Probability Amplitudes
2.03: Further Reading
2.E: Exercises
03: The Hydrogen Atom
3.01: Introduction
3.02: The Quantization of Energy
3.03: The Probability Distribution of the Hydrogen Atom
3.04: Angular Momentum of an Electron in a Hydrogen Atom
3.05: Some Useful Expressions
3.E: Exercises
04: Many-Electron Atoms
4.01: Introduction
4.02: The Atomic Orbital Concept
4.03: The Magnetic Properties of the Electron
4.04: The Electronic Basis of the Periodic Table
4.05: Further Reading
4.E: Exercises
05: Electronic Basis for the Properties of the Elements
5.01: Introduction
5.02: Horizontal Variations
5.03: Vertical Relationships
5.04: Some Chemical Implications
5.E: Exercises
06: The Chemical Bond
6.01: Introduction
6.02: An Electrostatic Interpretation of the Chemical Bond
6.03: The Effect of the Pauli Principle on Chemical Binding
6.04: The Quantum Mechanical Explanation of Valency
6.05: Molecular Geometry
6.06: Literature References
6.E: Exercises
07: Ionic and Covalent Bonding
7.01: Introduction
7.02: Classification of Chemical Bonds
7.03: Molecular Charge Distribution of Homonuclear Diatomic Molecules
7.04: Dipole Moments and Polar Bonds
7.05: Electronegativity
7.06: Interaction Between Molecules
7.07: Literature References
7.08: Further Reading
7.A: Appendix
7.E: Exercises
08: Molecular Orbitals
8.01: Introduction
8.02: Angular Momentum in Diatomic Molecules
8.03: Symmetry Considerations
8.04: Molecular Orbitals for Homonuclear Diatomics
8.05: The Relative Binding Ability of Molecular Orbitals
8.06: Molecular Orbitals for Heteronuclear Molecules
8.07: Molecular Orbitals for Polyatomic Molecules
8.08: Further Reading
8.E: Exercises
09: Preface to Calculations