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Physical Chemistry for the Biosciences

This textbook offers a thorough introduction to physical chemistry, covering foundational concepts, gas behavior, and detailed thermodynamics. It explores solutions, equilibrium, electrochemistry, acids and bases, and kinetics, including enzymes. Quantum mechanics leads to bonding theories, followed by intermolecular forces, spectroscopy, and photochemistry and ends with macromolecules, bridging theory with biological and real-world applications.

Physical and Theoretical Chemistry Textbook Maps Chemistry

Nhà xuất bản: LibreTexts Textmap
Nguồn: LibreTexts
Giấy phép: CC BY-NC-SA
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

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01: Introduction to Physical Chemistry
1.01: Nature of Physical Chemistry
1.02: Units
1.03: Atomic Mass Molecular Mass and the Chemical Mole
02: Properties of Gases
2.01: Some Definitions
2.02: An Operational Definition of Temperature
2.03: Ideal Gases
2.04: Real Gases
2.05: Condensation of Gases and the Critical State
2.06: Kinetic Theory of Gases
2.07: The Maxwell Distribution Laws
2.08: Molecular Collisions and the Mean Free Path
2.09: Graham's Laws of Diffusion and Effusion
2.E: Properties of Gases (Exercises)
03: The First Law of Thermodynamics
3.01: Work and Heat
3.02: The First Law of Thermodynamics
3.03: Heat Capacities
3.04: Gas Expansion
3.05: Calorimetry
3.06: Thermochemistry
3.07: Bond Energies and Enthalpies
3.E: Exercises
04: The Second Law of Thermodynamics
4.01: Spontaneous Processes
4.02: Entropy
4.03: The Second Law of Thermodynamics
4.04: The Third Law of Thermodynamics
4.05: Evaluating Entropy and Entropy Changes
4.06: Gibbs Energy
4.07: Standard Molar Gibbs Energy of Formation
4.08: Dependence of Gibbs Energy on Temperature and Pressure
4.09: Phase Equilibria
4.10: Thermodynamics of Rubber Elasticity
4.E: Exercises
05: Solutions
5.01: Concentration Units
5.02: Partial Molar Quantities
5.03: The Thermodynamics of Mixing
5.04: Binary Mixtures of Volatile Liquids
5.05: Real Solutions
5.06: Colligative Properties
5.07: Electrolyte Solutions
5.08: Ionic Activity
5.09: Colligative Properties of Electrolyte Solutions
5.10: Biological Membranes
5.E: Solutions (Exercises)
06: Chemical Equilibrium
6.01: Chemical Equilibrium in Gaseous Systems
6.02: Reactions in Solutions
6.03: Heterogeneous Equilibria
6.04: The Influence of Temperature Pressure and Catalysts on the Equilibrium Constant
6.05: Binding of Ligands and Metal Ions to Macromolecules
6.06: Bioenergetics
6.E: Chemical Equilibrium (Exercises)
07: Electrochemistry
7.01: Electrochemical Cells
7.02: Single Electrode Potentials
7.03: Thermodynamics of Electrochemical Cells
7.04: Types of Electrochemical Cells
7.05: Applications of EMF Measurements
7.06: Biological Oxidation
7.07: Membrane Potential
7.E: Electrochemistry (Exercises)
08: Acids and Bases
8.01: Definitions of Acids and Bases
8.02: Acid-Base Properties of Water
8.03: Dissociation of Acids and Bases
8.04: Diprotic and Polyprotic Acids
8.05: Buffer Solutions
8.06: Acid-Base Titrations
8.07: Amino Acids
8.08: Maintaining the pH of Blood
09: Chemical Kinetics
9.01: Reaction Rates
9.02: Reaction Order
9.03: Molecularity of a Reaction
9.04: More Complex Reactions
9.05: The Effect of Temperature on Reaction Rates
9.06: Potential Energy Surfaces
9.07: Theories of Reaction Rates
9.08: Isotope Effects in Chemical Reactions
9.09: Reactions in Solution
9.10: Fast Reactions in Solution
9.11: Oscillating Reactions
9.E: Chemical Kinetics (Exercises)
10: Enzyme Kinetics
10.01: General Principles of Catalysis
10.02: The Equations of Enzyme Kinetics
10.03: Chymotrypsin- A Case Study
10.04: Multisubstrate Systems
10.05: Enzyme Inhibition
10.06: Allosteric Interactions
10.07: The Effect of pH on Enzyme Kinetics
10.08: The Effect of Temperature on Enzyme Kinetics
10.E: Exercises
11: Quantum Mechanics and Atomic Structure
11.01: The Wave Theory of Light
11.02: Planck's Quantum Theory
11.03: The Photoelectric Effect
11.04: Bohr's Theory of the Hydrogen Emission Spectrum
11.05: de Broglie's Postulate
11.06: The Heisenberg Uncertainty Principle
11.07: The Schrodinger Wave Equation
11.08: Particle in a One-Dimensional Box
11.09: Quantum-Mechanical Tunneling
11.10: The Schrodinger Wave Equation for the Hydrogen Atom
11.11: Many-Electron Atoms and the Periodic Table
11.E: Quantum Mechanics and Atomic Structure (Exercises)
12: The Chemical Bond
12.01: Lewis Structures
12.02: Valence Bond Theory
12.03: Hybridization of Atomic Orbitals
12.04: Electronegativity and Dipole Moment
12.05: Molecular Orbital Theory
12.06: Diatomic Molecules
12.07: Resonance and Electron Delocalization
12.08: Coordination Compounds
12.09: Coordination Compounds in Biological Systems
12.E: The Chemical Bond (Exercises)
13: Intermolecular Forces
13.01: Intermolecular Interactions
13.02: The Ionic Bond
13.03: Types of Intermolecular Forces
13.04: Hydrogen Bonding
13.05: The Structure and Properties of Water
13.06: Hydrophobic Interaction
13.E: Intermolecular Forces (Exercises)
14: Spectroscopy
14.01: Vocabulary
14.02: Microwave Spectroscopy
14.03: Infrared Spectroscopy
14.04: Electronic Spectroscopy
14.05: Nuclear Magnetic Resonance
14.06: Electron Spin Resonance
14.07: Fluorescence and Phosphorescence
14.08: Lasers
14.09: Optical Rotatory Dispersion and Circular Dichroism
14.E: Spectroscopy (Exercises)
15: Photochemistry and Photobiology
15.01: Introduction to Photochemistry
15.02: Photosynthesis
15.03: Vision
15.04: Biological Effects of Radiation
16: Macromolecules
16.01: Size Shape and Molar Mass of Macromolecules
16.02: Structure of Synthetic Polymers
16.03: Structure of Proteins and DNA
16.04: Protein Stability