Thư viện Trường Đại học Phú Xuân
Klein and Straumanis Guided

Nguồn ngoài

Klein and Straumanis Guided

Nhà xuất bản
LibreTexts
Nguồn
LibreTexts
Giấy phép
CC BY-NC-SA
Ngôn ngữ
EN
Danh mục
Khoa học cơ bản
Mục lục· 492 mục
  1. 01: A Review of General Chemistry - Electrons Bonds and Molecular Properties
  2. 1.01: Introduction to Organic Chemistry
  3. 1.02: 1-3 Atomic Orbitals and Hybridization
  4. 1.2.01: (sp) Hybrid Orbitals and the Structure of Acetylene
  5. 1.2.02: (sp2) Hybrid Orbitals and the Structure of Ethylene
  6. 1.2.03: (sp3) Hybrid Orbitals and the Structure of Ethane
  7. 1.2.04: (sp3) Hybrid Orbitals and the Structure of Methane
  8. 1.03: Valence Bond Theory
  9. 1.04: Molecular Orbital Theory
  10. 1.05: Intermolecular Forces and Physical Properties
  11. 1.06: Solubility
  12. 1.07: 1-2 Electron-Dot Model of Bonding- Lewis Structures and Formal Charges
  13. 1.08: 1-4 Determining Molecular Shape
  14. 1.09: 1-5 Dipole Moments and Molecular Polarity
  15. 1.9.01: Polar Covalent Bonds- Electronegativity
  16. 1.9.02: Polar Covalent Bonds- Dipole Moments
  17. 1.10: 1-6 Induction and Polar Covalent Bonds
  18. 1.10.01: Noncovalent Interactions Between Molecules
  19. 1.E: A Review of General Chemistry (Exercises)
  20. 02: Molecular Representations
  21. 2.01: Molecular Representations
  22. 2.02: Bond-Line Structures
  23. 2.03: 2.2 Polar Covalent Bonds- Dipole Moments
  24. 2.04: Identifying Functional Groups
  25. 2.05: Carbon Atoms with Formal Charges
  26. 2.06: Identifying Lone Pairs
  27. 2.07: Three-Dimensional Bond-Line Structures
  28. 2.08: 2-2 Introduction to Resonance
  29. 2.8.01: Building Resonance Structures
  30. 2.8.02: Rules for Resonance Forms
  31. 2.09: Curved Arrows
  32. 2.10: Formal Charges in Resonance Structures
  33. 2.11: Assessing Relative Importance of Resonance Structures
  34. 2.12: Delocalized and Localized Lone Pairs
  35. 2.13: 2-1 Drawing Chemical Structures
  36. 2.14: 2-3 Drawing Resonance Structures
  37. 2.14.01: Drawing Resonance Forms Using Pattern Recognition
  38. 2.E: Molecular Representations (Exercises)
  39. 03: Acids and Bases
  40. 3.01: 1.21 How the Structure of an Acid Affects its pka Value
  41. 3.02: An Introduction to Brnsted-Lowry Acids and Bases
  42. 3.03: Flow of Electron Density - Curved Arrow Notation
  43. 3.04: Brnsted-Lowry Acidity - A Quantitative Perspective
  44. 3.05: Brnsted-Lowry Acidity - Qualitative Perspective
  45. 3.06: Position of Equilibrium and Choice of Reagents
  46. 3.07: Choice of Solvent
  47. 3.08: Solvating Effects
  48. 3.09: Counterions
  49. 3.10: Lewis Acids and Bases
  50. 3.11: Hydrogen Bonds
  51. 3.12: 3-1 Physical properties of organic compounds
  52. 3.13: 3-3 Acids and Bases Electrophiles and Nucleophiles
  53. 3.14: 3-4 Organic Acids and Bases
  54. 3.15: 3-5 How to Predict the Outcome of an Acid-Base Reaction
  55. 3.16: 3-6 How Substituents Affect the Strength of an Acid
  56. 3.17: 3-7 Factors That Determine Acid Strength
  57. 3.E: Acids and Bases (Exercises)
  58. 04: Alkanes and Cycloalkanes
  59. 4.01: 3.5 Properties of Alkanes
  60. 4.02: 3-1 Conformations of open-chain organic molecules
  61. 4.2.01: Alkanes and Their Stereochemistry
  62. 4.03: 3-2 Conformations of cyclic organic molecules
  63. 4.3.01: Conformations of Cyclohexane
  64. 4.04: Introduction to Alkanes
  65. 4.05: Nomenclature of Alkanes
  66. 4.06: Constitutional Isomers of Alkanes
  67. 4.07: Relative Stability of Isomeric Alkanes
  68. 4.08: Sources and Uses of Alkanes
  69. 4.09: Drawing Newman Projections
  70. 4.10: Cycloalkanes
  71. 4.11: Conformations of Cyclohexane
  72. 4.12: Drawing Chair Conformations
  73. 4.13: Monosubstituted Cyclohexane
  74. 4.14: Disubstituted Cyclohexane
  75. 4.15: cis-trans Stereoisomerism
  76. 4.16: Polycyclic Systems
  77. 4.17: 4-1 Naming Alkanes
  78. 4.18: 4-2 Naming Cycloalkanes
  79. 4.19: 4-3 Cis-Trans Isomerism in Cycloalkanes
  80. 4.20: 4-4 Alkanes and Alkane Isomers
  81. 4.21: 4-5 Combustion. Heats of Reaction. Bond Energies
  82. 4.E: Alkanes and Cycloalkanes (Exercises)
  83. 05: Stereoisomerism
  84. 5.01: Prelude to Stereoisomerism
  85. 5.02: Overview of Isomerism
  86. 5.03: Introduction to Stereoisomerism
  87. 5.04: Designating Configuration Using the Cahn-Ingold-Prelog System
  88. 5.05: Optical Activity
  89. 5.06: 5-4 Stereoisomeric Relationships - Enantiomers and Diastereomers
  90. 5.6.01: 001 Pasteur's Discovery of Enantiomers
  91. 5.6.02: Diastereomers
  92. 5.6.03: Meso Compounds
  93. 5.07: Symmetry and Chirality
  94. 5.08: Fischer Projections
  95. 5.09: Conformationally Mobile Systems
  96. 5.10: Resolution of Enantiomers
  97. 5.11: Chiral Molecules
  98. 5.12: 5-1 Looking Glass ChemistryChiral and Achiral Molecules
  99. 5.13: 5-2 The Reason for Handedness in Molecules- Chirality
  100. 5.14: 5-3 Optical Activity
  101. 5.15: 5-5 Sequence Rules for Specifying Configuration
  102. 5.15.01: Diastereomers and Fischer Projections
  103. 5.E: Stereoisomerism (Exercises)
  104. 06: Chemical Reactivity and Mechanisms
  105. 6.01: Enthalpy
  106. 6.02: Entropy
  107. 6.03: Gibbs Free Energy
  108. 6.04: Equilibria
  109. 6.05: Kinetics
  110. 6.06: Reading Energy Diagrams
  111. 6.07: Mechanisms and Arrow Pushing
  112. 6.08: Combining the Patterns of Arrow Pushing
  113. 6.09: Catalysts
  114. 6.10: Drawing Curved Arrows
  115. 6.11: Carbocation Rearrangements
  116. 6.12: Nucleophiles and Electrophiles
  117. 6.13: 6-10 Describing a Reaction- Intermediates
  118. 6.14: 6-11 Reaction Mechanisms Involving Polar Functional Groups- Using Electron-Pushing' Arrows
  119. 6.15: 6-1 Writing Equations for Organic Reactions
  120. 6.16: 6-2 Kinds of Organic Reactions
  121. 6.17: 6-3 Bond Breaking and Bond Making
  122. 6.18: 6-4 Bond Dissociation Energy
  123. 6.19: 6-5 Thermodynamics
  124. 6.20: 6-6 Enthalpy and Entropy
  125. 6.21: 6-7 Energy Diagrams
  126. 6.22: 6-8 Energy Diagram for a Two-Step Reaction Mechanism
  127. 6.23: 6-9 Kinetics
  128. 6.E: Chemical Reactivity and Mechanisms (Exercises)
  129. 07: Substitution Reactions
  130. 7.01: 7-2 The (S N2) Reaction
  131. 7.02: 7-3 Characteristics of the (S N2) Reaction
  132. 7.03: 7-4 The (S N1) Reaction
  133. 7.04: 7-5 Characteristics of the (S N1) Reaction
  134. 7.05: Introduction to Substitution Reactions
  135. 7.06: Alkyl Halides
  136. 7.07: Possible Mechanisms for Substitution Reactions
  137. 7.08: The SN2 Mechanism
  138. 7.09: The SN1 Mechanism
  139. 7.10: Drawing the Complete Mechanism of an SN1 Reaction
  140. 7.11: Drawing the Complete Mechanism of an SN2 Reaction
  141. 7.12: Determining Which Mechanism Predominates
  142. 7.13: Selecting Reagents to Accomplish Functional Group Transformation
  143. 7.14: 7-7 When Is the Mechanism (S N1) or (S N2)
  144. 7.15: 7-1 Introduction to Nucleophilic Substitution Reactions
  145. 7.16: 7-8 Carbocation Structure and Stability
  146. 7.17: 7-9 Carbocation Stability
  147. 7.18: 7-6 Structural and Solvent Effects in (S N) Reactions
  148. 7.E: Substitution Reactions (Exercises)
  149. 08: Alkenes- Structure and Preparation via Elimination Reactions
  150. 8.01: Introduction to Elimination Reactions
  151. 8.02: Alkenes in Nature and in Industry
  152. 8.03: Nomenclature of Alkenes
  153. 8.04: Stereoisomerism in Alkenes
  154. 8.05: Alkene Stability
  155. 8.06: Possible Mechanisms for Elimination
  156. 8.07: The E2 Mechanism
  157. 8.08: Drawing the Products of an E2 Reaction
  158. 8.09: The E1 Mechanism
  159. 8.10: Drawing the Complete Mechanism of an E1 Process
  160. 8.11: Drawing the Complete Mechanism of an E2 Process 372
  161. 8.12: Substitution vs. Elimination- Identifying the Reagent
  162. 8.13: Substitution vs. Elimination- Identifying the Mechanism(s)
  163. 8.14: Substitution vs. Elimination- Predicting the Products
  164. 8.15: 8-1 Elimination Reactions- Zaitsev's Rule
  165. 8.16: 8-1 Nucleophilic Character of the Pi Bond- Electrophilic Addition of Hydrogen Halides
  166. 8.17: 8-3 The E2 Reaction and the Deuterium Isotope Effect
  167. 8.18: 8-2 Unimolecular Elimination- E1
  168. 8.19: 8-4 The E2 Reaction and Cyclohexane Conformation
  169. 8.20: 8-5 Keys to Success- Substitutin Versus Elimination-Structure Determines Function
  170. 8.E: Alkenes (Exercises)
  171. 09: Addition Reactions of Alkenes
  172. 9.01: Vicinal SYn Dihydroxylation with Osmium Tetroxide
  173. 9.02: Oxidative Cleavage- Ozonolysis
  174. 9.03: 9-6 Halogenation of Alkenes- Addition of (X 2)
  175. 9.04: 9-10 Hydration of Alkenes- Addition of (H 2O) by Hydroboration
  176. 9.05: Introduction to Addition Reactions
  177. 9.06: Addition vs. Elimination - A Thermodynamic Perspective
  178. 9.07: Hydrohalogenation
  179. 9.08: Acid-Catalyzed Hydration
  180. 9.09: Oxymercuration-Demercuration
  181. 9.10: Hydroboration-Oxidation
  182. 9.11: Catalytic Hydrogenation
  183. 9.12: Halogenation and Halohydrin Formation
  184. 9.13: Anti Dihydroxylation
  185. 9.14: Syn Dihydroxylation
  186. 9.15: Oxidative Cleavage
  187. 9.16: Predicting Products of an Addition Reaction
  188. 9.17: Synthesis Strategies
  189. 9.18: 9-10 Reduction of Alkenes- Hydrogenation
  190. 9.19: 9-11 Catalytic Hydrogenation
  191. 9.20: 9-12 Reduction of Alkynes
  192. 9.21: 9-13 Oxidation of Alkenes- Cleavage to Carbonyl Compounds
  193. 9.22: 9-14 Naming Alkenes
  194. 9.23: 9-15 Cis-Trans Isomerism in Alkenes
  195. 9.24: 9-16 Sequence Rules- The EZ Designation
  196. 9.25: 9-1 Nucleophilic Character of the Pi Bond- Electrophilic Addition of Hydrogen Halides
  197. 9.26: 9-2 Alcohol Synthesis by Electrophilic Hydration- Thermodynamic Control
  198. 9.27: 9-3 Oxymercuration-Demercuration- A Special Elcctrophilic Addition
  199. 9.28: 9-4 Hydroboration-Oxidation- A Stereospecific Anti-Markovnikov Hydration
  200. 9.29: 9-7 Halohydrins from Alkenes- Addition of HOX
  201. 9.30: 9-8Radical Additions- Anti-Markovnikov Product Formation
  202. 9.31: 9-8 Oxacyclopropane ( Epoxide) Synthesis- Epoxidation by Peroxycarboxylic Acids
  203. 9.32: 9-9 Oxidation of Alkenes- Epoxidation and Hydroxylation
  204. 9.E: Addition Reactions of Alkenes (Exercises)
  205. 10: Alkynes
  206. 10.01: Alkylation of Terminal Alkynes
  207. 10.02: Synthesis Strategies
  208. 10.03: Introduction to Alkynes
  209. 10.04: Nomenclature of Alkynes
  210. 10.05: Acidity of Acetylene and Terminal Alkynes
  211. 10.06: Preparing Alkynes
  212. 10.07: Reduction of Alkynes
  213. 10.08: Hydrohalogenation of Alkynes
  214. 10.09: Hydration of Alkynes
  215. 10.10: Halogenation of Alkynes
  216. 10.11: Ozonolysis of Alkynes
  217. 10.12: 10-1 Naming Alkynes
  218. 10.13: 10-2 Alkyne Acidity- Formation of Acetylide Anions
  219. 10.14: 10-3 Alkylation of Acetylide Anions
  220. 10.15: 10-4 Preparation of Alkynes- Elimination Reactions of Dihalides
  221. 10.16: 10-6 Oxidative Cleavage of Alkynes
  222. 10.17: 10-7 Hydration of Triple Bonds
  223. 10.18: 10-8 HydroborationOxidation
  224. 10.19: 10-5 Reactions of Alkynes- Addition of HX and (X 2)
  225. 10.E: Alkynes (Exercises)
  226. 11: Radical Reactions
  227. 11.01: Radicals
  228. 11.02: Common Patterns in Radical Mechanisms
  229. 11.03: Chlorination of Methane
  230. 11.04: Thermodynamic Considerations for Halogenation Reactions
  231. 11.05: Regioselectivity of Halogenation
  232. 11.06: Stereochemistry of Halogenation
  233. 11.07: Allylic Bromination
  234. 11.08: Atmospheric Chemistry and the Ozone Layer
  235. 11.09: Autooxidation and Antioxidants
  236. 11.10: Addition of HBr- Anti-Markovnikov Addition
  237. 11.11: Radical Polymerization
  238. 11.12: Radical Processes in the Petrochemical Industry
  239. 11.13: Halogenation as a Synthetic Technique
  240. 11.14: 11-1 Preparing Alkyl Halides from Alkanes- Radical Halogenation
  241. 11.15: 11-2 Chlorination of Methane- The Radical Chain Mechanism
  242. 11.16: 11-3 Selectivity in Radical Halogenation with Fluorine and Bromine
  243. 11.17: 11-4 Radical Halogenation at an Allylic Carbon
  244. 11.18: 11-5 Radical chain reactions
  245. 11.19: 11-6Radical Additions- Anti-Markovnikov Product Formation
  246. 11.E: Radical Reactions (Exercises)
  247. 12: Synthesis
  248. 12.01: One-Step Syntheses
  249. 12.02: Retrosynthetic Analysis
  250. 12.03: Practical Tips for Increasing Proficiency
  251. 12.04: An Introduction to Organic Synthesis
  252. 12.05: Building the Carbon Skeleton
  253. 12.06: The Logic of Synthesis
  254. 12.E: Synthesis (Exercises)
  255. 13: Alcohols and Phenols
  256. 13.01: Physical Properties of Alcohols Hydrogen Bonding
  257. 13.02: Preparation of Alcohols via Reduction
  258. 13.03: Preparation of Diols
  259. 13.04: Reactions of Alcohols - Substitution and Elimination
  260. 13.05: Reactions of Alcohols- Oxidation
  261. 13.06: Biological Redox Reactions
  262. 13.07: Oxidation of Phenol
  263. 13.08: Synthesis Strategies
  264. 13.09: Physical Properties of Alcohols Hydrogen Bonding
  265. 13.10: Acidity of Alcohols and Phenols
  266. 13.11: Synthesis of Alcohols - Review
  267. 13.12: Dehydration Reactions of Alcohols
  268. 13.13: Oxidation Reactions of Alcohols
  269. 13.14: Alcohols from Reaction of Carbonyl Compounds- Grignard Reagents
  270. 13.15: 13.7 Reactions of Alcohols
  271. 13.16: Protection of Alcohols
  272. 13.17: 13.9 Alcohols from Carbonyl Compounds- Reduction
  273. 13.E: Alcohols and Phenols (Exercises)
  274. 14: Ethers and Epoxides Thiols and Sulfides
  275. 14.01: Introduction to Ethers
  276. 14.02: Nomenclature of Ethers
  277. 14.03: Crown Ethers
  278. 14.04: Nomenclature of Epoxides
  279. 14.05: Enantioselective Epoxidation
  280. 14.06: Reactions of Epoxides - Ring-opening
  281. 14.07: Thiols and Sulfides
  282. 14.08: Synthesis Strategies Involving Epoxides
  283. 14.09: Names and Properties of Ethers
  284. 14.10: Synthesis of Ethers
  285. 14.11: Reactions of Ethers - Acidic Cleavage
  286. 14.E: Ethers and Epoxides Thiols and Sulfides (Exercises)
  287. 15: Infrared Spectroscopy and Mass Spectrometry
  288. 15.01: 6-1 Spectroscopy and the Electromagnetic Spectrum
  289. 15.02: 6-2 Infrared Spectroscopy
  290. 15.03: 6-3 Interpreting Infrared Spectra
  291. 15.04: 6-4 Infrared Spectra of Some Common Functional Groups
  292. 15.05: 6-5 Mass Spectrometry of Small Molecules- Magnetic-Sector Instruments
  293. 15.5.01: Mass Spectroscopy in Further Detail
  294. 15.06: 6-6 Interpreting Mass Spectra
  295. 15.07: 6-7 Mass Spectrometry of Some Common Functional Groups
  296. 15.08: 6-8 Isotopes in Mass Spectrometry
  297. 15.09: 6-9 Fragmentation Patterns of Organic Molecules
  298. 15.9.01: More Fragmentation
  299. 16: Nuclear Magnetic Resonance Spectroscopy
  300. 16.01: Introduction to NMR Spectroscopy
  301. 16.02: Acquiring a H NMR Spectrum
  302. 16.03: Characteristics of a H NMR Spectrum
  303. 16.04: Number of Signals
  304. 16.05: Chemical Shift
  305. 16.06: Integration
  306. 16.07: Multiplicity
  307. 16.08: Using H NMR Spectroscopy to Distinguish between Compounds
  308. 16.09: Analyzing a H NMR Spectrum
  309. 16.10: Acquiring a C NMR Spectrum
  310. 16.11: Chemical Shifts in C NMR Spectroscopy
  311. 16.12: DEPT C NMR Spectroscopy
  312. 16.13: Drawing the Expected H NMR Spectrum of a Compound
  313. 16.14: 16-10 Integration of H NMR Absorptions- Proton Counting
  314. 16.15: 16-10 Spin-Spin Splitting in H NMR Spectra
  315. 16.16: 16-11 More Complex Spin-Spin Splitting Patterns
  316. 16.17: 16-12 Nuclear Magnetic Resonance Spectroscopy - Extra Details
  317. 16.18: 16-1 Nuclear Magnetic Resonance Spectroscopy
  318. 16.19: 16-2 The Nature of NMR Absorptions
  319. 16.20: 16-3 Chemical Shifts
  320. 16.21: 16-4 C NMR Spectroscopy- Signal Averaging and FT-NMR
  321. 16.22: 16-5 Characteristics of C NMR Spectroscopy
  322. 16.23: 16-6 DEPT C NMR Spectroscopy
  323. 16.24: 16-7 Uses of C NMR Spectroscopy
  324. 16.25: 16-8 H NMR Spectroscopy and Proton Equivalence
  325. 16.26: 16-9 Chemical Shifts in H NMR Spectroscopy
  326. 16.27: Structure Determination - Nuclear Magnetic Resonance Spectroscopy
  327. 16.E: Nuclear Magnetic Resonance Spectroscopy (Exercises)
  328. 17: Conjugated Pi Systems and Pericyclic Reactions
  329. 17.01: An Introduction to Pericyclic Reactions
  330. 17.02: MO Description of Cycloadditions
  331. 17.03: Electrocyclic Reactions
  332. 17.04: Sigmatropic Rearrangements
  333. 17.05: Electronic Spectra- Ultraviolet and Visible Spectroscopy
  334. 17.06: Color
  335. 17.07: The Chemistry of Vision
  336. 17.08: Introduction
  337. 17.09: Two Neighboring Double Bonds- Conjugated Dienes
  338. 17.10: Two Neighboring Double Bonds- Conjugated Dienes and MO Theory
  339. 17.11: 13- or Conjugated Dienes. Electrophilic and Radical Addition
  340. 17.12: Electrophilic Attack on Conjugated Dienes-Kinetic and Thermodynamic Control
  341. 17.13: Kinetic versus Thermodynamic Control
  342. 17.14: Polymerization Reactions of Conjugated Dienes
  343. 17.15: The Diels-Alder Cycloaddition
  344. 17.16: Diels-Alder - a closer look
  345. 17.17: Electrocyclic Reactions
  346. 17.E: Conjugated Pi Systems and Pericyclic Reactions (Exercises)
  347. 18: Aromatic Compounds
  348. 18.01: Aromaticity and the Huckel 4n 2 Rule
  349. 18.02: Introduction to Aromatic Compounds
  350. 18.03: Nomenclature of Benzene Derivatives
  351. 18.04: Reactions at the Benzylic Position
  352. 18.05: Reduction of the Aromatic Moiety
  353. 18.06: Delocalized Electrons Explain Benzenes Structure
  354. 18.07: Structure and Resonance Energy of Benzene- A First Look at Aromaticity
  355. 18.08: Spectral Characteristics of the Benzene Ring
  356. 18.E: Aromatic Compounds (Exercises)
  357. 19: Aromatic Substitution Reactions
  358. 19.01: Nitration
  359. 19.02: Friedel-Crafts Alkylation
  360. 19.03: Friedel-Crafts Acylation
  361. 19.04: Halogens - The Exception
  362. 19.05: Activation or Deactivation by Substituents on a Benzene Ring
  363. 19.06: Trisubstituted Benzenes - Additivity of Effects
  364. 19.07: An Explanation of Substituent Effects
  365. 19.08: Synthesis of Polysubstituted Benzenes
  366. 19.09: Nucleophilic Aromatic Substitution
  367. 19.10: Benzyne
  368. 19.11: Elimination-Addition
  369. 19.12: 19.15 Identifying the Mechanism of an Aromatic Substitution Reaction
  370. 19.13: Synthesis of Benzene Derivatives- Electrophilic Aromatic Substitution
  371. 19.14: Electrophilic Aromatic Substitution Reactions - Bromination
  372. 19.15: Other Aromatic Substitutions
  373. 19.16: Substituent Effects in Substituted Aromatic Rings
  374. 19.17: An Explanation of Substituent Effects
  375. 19.E: Aromatic Substitution Reactions (Exercises)
  376. 20: Aldehydes and Ketones
  377. 20.01: 19.5 Nucleophilic Addition of
  378. 20.1.01: (H 2O
  379. 20.1.1.01: 20.4 Nucleophilic Addition of (H 2O)- Hydration
  380. 20.02: Mechanism Strategies
  381. 20.03: Sulfur Nucleophiles
  382. 20.04: Hydrogen Nucleophiles
  383. 20.05: 20.10 Nucleophilic Addition of Phosphorus Ylides- The Wittig Reaction
  384. 20.06: Baeyer-Villiger Oxidation of Aldehydes and Ketones
  385. 20.07: Synthesis Strategies
  386. 20.08: Spectroscopic Analysis of Aldehydes and Ketones
  387. 20.09: 20.1 Oxidation of Aldehydes and Ketones
  388. 20.10: 20.2 Naming Aldehydes and Ketones
  389. 20.11: 20.3 Preparing Aldehydes and Ketones
  390. 20.12: Nucleophilic Addition of Alcohols- Acetal Formation
  391. 20.13: 20.5a Nucleophilic Addition Reactions of Aldehydes and Ketones
  392. 20.14: Nucleophilic Addition of Amines- Imine and Enamine Formation
  393. 20.15: 20.7a Nucleophilic Addition of Hydrazin - The Wolff-Kishner Reaction
  394. 20.E: Aldehydes and Ketones (Exercises)
  395. 21: Carboxylic Acids and Their Derivatives
  396. 21.01: 20.2 Naming Carboxylic Acids and Nitriles
  397. 21.02: 20.3 Structure and Properties of Carboxylic Acids
  398. 21.03: Introduction to Carboxylic Acids
  399. 21.04: Nomenclature of Carboxylic Acids
  400. 21.05: Preparation of Carboxylic Acids
  401. 21.06: Introduction to Carboxylic Acid Derivatives
  402. 21.07: 21.10 Chemistry of Esters
  403. 21.08: Reactions of Esters
  404. 21.09: 21.12 Chemistry of Amides
  405. 21.10: 21.13 Preparing Carboxylic Acids
  406. 21.11: Synthesis Strategies
  407. 21.12: Spectroscopy of Carboxylic Acids and Their Derivatives
  408. 21.13: 21.4 Preparing Carboxylic Acids
  409. 21.14: 21.5 Structure and Properties of Carboxylic Acids
  410. 21.15: 21.7 Nucleophilic Acyl Substitution Reactions
  411. 21.16: 21.8 Chemistry of Acid Halides
  412. 21.17: 21.8 Nucleophilic Acyl Substitution Reactions of Carboxylic Acids
  413. 21.18: 21.9 Chemistry of Acid Anhydrides
  414. 21.E: Carboxylic Acids and Their Derivatives (Exercises)
  415. 22: Alpha Carbon Chemistry- Enols and Enolates
  416. 22.01: 19.13 Conjugate Nucleophilic Addition to
  417. 22.1.01: (
  418. 22.1.1.01: alpha
  419. 22.1.1.1.01: )
  420. 22.1.1.1.1.01: (
  421. 22.1.1.1.1.1.01: beta
  422. 22.02: 22.1 Intro to Enols and Enolates
  423. 22.03: Halogenation of Aldehydes and Ketones
  424. 22.04: 22.3a Carbonyl Condensations - The Aldol Reaction
  425. 22.05: 22.3b Dehydration of Aldol Products - Synthesis of Enones
  426. 22.06: 22.4 Claisen Condensation Reactions
  427. 22.07: Alkylation of the Alpha Position
  428. 22.08: 22.5 Alkylation of Enolate Ions
  429. 22.09: 22.6 Conjugate Nucleophilic Addition to (alpha) (beta)-unsaturated Aldehydes and Ketones
  430. 22.10: Synthesis Strategies
  431. 22.E: Alpha Carbon Chemistry- Enols and Enolates (Exercises)
  432. 23: Amines
  433. 23.01: Introduction to Amines
  434. 23.02: Preparation of Amines - A Review
  435. 23.03: Preparation of Amines via Substitution Reactions
  436. 23.04: Preparation of Amines via Reductive Amination
  437. 23.05: Synthesis Strategies
  438. 23.06: Acylation of Amines
  439. 23.07: The Hofmann Elimination
  440. 23.08: Reactions of Amines with Nitrous Acid
  441. 23.09: Reactions of Aryldiazonium Ions
  442. 23.10: Nitrogen Heterocycles
  443. 23.11: 23.12 Heterocyclic Amines
  444. 23.12: Spectroscopy of Amines
  445. 23.13: 23.2 Naming Amines
  446. 23.14: 23.3 Basicity of Amines
  447. 23.15: 23.3 Structure and Properties of Amines
  448. 23.16: Synthesis of Amines by Alkylation
  449. 23.17: 23.5 Synthesis of Amines
  450. 23.E: Amines (Exercises)
  451. 24: Carbohydrates
  452. 24.01: Introduction to Carbohydrates
  453. 24.02: Classification of Monosaccharides
  454. 24.03: Configuration of Aldoses
  455. 24.04: Configuration of Ketoses
  456. 24.05: Cyclic Structures of Monosaccharides
  457. 24.06: Reactions of Monosaccharides
  458. 24.07: Disaccharides
  459. 24.08: Polysaccharides
  460. 24.09: Amino Sugars
  461. 24.10: N-Glycosides
  462. 24.E: Carbohydrates (Exercises)
  463. 25: Amino Acids Peptides and Proteins
  464. 25.01: Introduction to Amino Acids Peptides and Proteins
  465. 25.02: Structure and Properties of Amino Acids
  466. 25.03: Amino Acid Synthesis
  467. 25.04: Structure of Peptides
  468. 25.05: Sequencing a Peptide
  469. 25.06: Peptide Synthesis
  470. 25.07: Protein Structure
  471. 25.08: Protein Function
  472. 25.E: Amino Acids Peptides and Proteins (Exercises)
  473. 26: Lipids
  474. 26.01: Introduction to Lipids
  475. 26.02: Waxes
  476. 26.03: Triglycerides
  477. 26.04: Reactions of Triglycerides
  478. 26.05: Phospholipids
  479. 26.06: Steroids
  480. 26.07: Prostaglandins
  481. 26.08: Terpenes
  482. 26.E: Lipids (Exercises)
  483. 27: Synthetic Polymers
  484. 27.01: Introduction to Synthetic Polymers
  485. 27.02: Nomenclature of Synthetic Polymers
  486. 27.03: Copolymers
  487. 27.04: Polymer Classification by Reaction Type
  488. 27.05: Polymer Classification by Mode of Assembly
  489. 27.06: Polymer Classification by Structure
  490. 27.07: Polymer Classification by Properties
  491. 27.08: Polymer Recycling
  492. 27.E: Synthetic Polymers (Exercises)