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CHEM322: Inorganic Chemistry

Nguồn ngoài

CHEM322: Inorganic Chemistry

Chemistry
Tác giả
Amanda Reig
Nhà xuất bản
Ursinus College
Nguồn
LibreTexts
Ngôn ngữ
EN
Danh mục
Khoa học cơ bản
Đọc trực tuyến Tải PDF (nguồn mở)
Mục lục· 184 mục
  1. 01: Atomic Structure
  2. 1.01: Historical Development of Atomic Theory
  3. 1.1.01: Early Experiments of Atomic Theory
  4. 1.1.02: Discovery of Subatomic Particles
  5. 1.1.03: Quantization of Energy and Bohr Model of the Atom
  6. 1.1.04: Wave-Particle Duality
  7. 1.02: Electronic Structure of the Atom
  8. 1.2.01: Wave Quantization and Particle in a Box
  9. 1.2.02: The Schrodinger Equation
  10. 1.2.03: Quantum Numbers and Atomic Wave Functions
  11. 1.03: Multi-Electron Atoms
  12. 1.3.01: Orbital Energies
  13. 1.3.02: Shielding
  14. 1.3.03: Aufbau Principle
  15. 1.3.04: Slater's Rules
  16. 1.04: Periodic Properties of the Elements
  17. 1.4.01: Effective Nuclear Charge
  18. 1.4.02: Ionization energy
  19. 1.4.03: Electron Affinity
  20. 1.4.04: Covalent and Ionic Radii
  21. 1.4.05: Lanthanide Contraction
  22. 1.4.06: The Uniqueness Principle
  23. 1.05: Unit 1 Practice Problems
  24. 02: Molecular Structure
  25. 2.01: Chemical Bonding
  26. 2.1.01: Types of Chemical Bonds
  27. 2.1.02: Electronegativity and the Bonding Continuum
  28. 2.1.03: Polarizability and Percent Ionic Character
  29. 2.02: Lewis Structures and Molecular Shape
  30. 2.2.01: Lewis Electron-Dot Diagrams
  31. 2.2.02: Formal Charge
  32. 2.2.03: Resonance
  33. 2.2.04: Expanded Octets
  34. 2.2.05: Limitation of Lewis Theory
  35. 2.2.06: Valence Shell Electron-Pair Repulsion
  36. 2.2.07: Lone Pair Repulsion
  37. 2.2.08: Multiple Bonds
  38. 2.2.09: Electronegativity and Atomic Size Effects
  39. 2.2.10: Molecular Polarity
  40. 03: Molecular Symmetry
  41. 3.01: Symmetry Elements and Operations LOs
  42. 3.1.01: Definitions and Examples
  43. 3.02: Point Groups
  44. 3.2.01: Molecular Point Groups
  45. 3.2.02: Assigning Point Groups
  46. 3.2.03: Chirality
  47. 3.03: Unit 3 Practice Problems
  48. 04: Group Theory
  49. 4.01: Groups
  50. 4.1.01: Properties of Groups
  51. 4.02: Representations and Character Tables
  52. 4.2.01: Matrices
  53. 4.2.02: Representations of Point Groups
  54. 4.2.03: Character Tables
  55. 4.03: Application to Vibrational Spectroscopy
  56. 4.3.01: Molecular Vibrations
  57. 4.04: Unit 4 Practice Problems
  58. 05: Molecular Orbitals
  59. 5.01: Valence Bond Theory
  60. 5.1.01: The Shapes of Molecules (VSEPR Theory) and Orbital Hybridization
  61. 5.02: Linear Combination of Atomic Orbitals
  62. 5.2.01: Formation of Molecular Orbitals from Atomic Orbitals
  63. 5.2.02: Molecular Orbitals from s Orbitals
  64. 5.2.03: Molecular Orbitals from p Orbitals
  65. 5.2.04: Molecular orbitals from d orbitals
  66. 5.2.05: Nonbonding Orbitals and Other Factors
  67. 5.03: Diatomic MO Diagrams
  68. 5.3.01: Homonuclear Diatomic Molecules
  69. 5.3.1.01: Molecular Orbitals
  70. 5.3.1.02: Orbital Mixing
  71. 5.3.1.03: Diatomic Molecules of the First and Second Periods
  72. 5.3.1.04: Photoelectron Spectroscopy
  73. 5.3.02: Heteronuclear Diatomic Molecules
  74. 5.3.2.01: Orbital ionization energies
  75. 5.3.2.02: Polar bonds
  76. 5.3.2.03: Ionic Compounds and Molecular Orbitals
  77. 5.04: Polyatomic MO Diagrams
  78. 5.4.01: Ligand Group Orbitals and Generator Functions
  79. 5.4.02: Polyatomic Molecules
  80. 5.4.2.01: Bifluoride anion
  81. 5.4.2.02: Carbon Dioxide
  82. 5.4.2.03: HO
  83. 5.4.2.04: NH
  84. 5.4.03: Why is BeH Linear and HO Bent
  85. 5.05: Pi Bonding and Hypervalency
  86. 5.5.01: BF
  87. 5.5.02: Expanded Octets and Molecular Orbitals
  88. 06: Solid State Chemistry
  89. 6.01: Solid State Structures
  90. 6.1.01: Cubic Lattices and Close Packing
  91. 6.1.02: Ionic Radii and Radius Ratios
  92. 6.02: Crystalline Solids
  93. 6.2.01: Types of Crystalline Solids
  94. 6.2.02: Alloys and Intermetallics
  95. 6.2.03: The Imperfect Solid State
  96. 6.03: X-Ray Crystallography of Solids
  97. 6.3.01: Miller Indices (hkl)
  98. 6.3.02: X-rays and X-ray Diffraction
  99. 6.3.03: Powder X-ray Diffraction
  100. 6.04: Energetics of Ionic Solids
  101. 6.4.01: Lattice Enthlapies of Ionic Solids
  102. 6.4.02: Born Haber Cycles
  103. 6.4.03: Lattice Energies and Solubility
  104. 6.4.04: Theoretical Lattice Energy Calculations
  105. 6.4.05: Kapustinskii Equation
  106. 6.05: Band Theory and Conductivity
  107. 6.5.01: Bonding in Metals and Semicondoctors
  108. 6.5.02: The Fermi Level
  109. 6.5.03: Semiconductors- Band Gaps Colors Conductivity and Doping
  110. 6.5.04: Periodic Trends- Metals Semiconductors and Insulators
  111. 6.5.05: Semiconductor p-n Junctions
  112. 6.5.06: Diodes LEDs and Solar Cells
  113. 6.5.07: Superconductors
  114. 07: Acid-Base and Donor-Acceptor Chemistry
  115. 7.01: Acid Base Chemistry
  116. 7.1.01: Arrhenius Model
  117. 7.1.02: Brnsted-Lowry Model
  118. 7.1.03: Metal Ions as Acids
  119. 7.1.04: Autoionization and Solvent Leveling
  120. 7.1.05: Lewis Model and Frontier Orbitals
  121. 7.02: Hard Soft Acid Base Theory
  122. 7.2.01: Hard and Soft Acids and Bases
  123. 7.2.02: Applications of Hard Soft Acid Base Theory
  124. 7.2.03: Theoretical Interpretation of HSAB Theory
  125. 7.03: Unit 7 Practice Problems
  126. 08: Electronic Structure of Coordination Complexes
  127. 8.01: Introduction to Coordination Complexes
  128. 8.1.01: What are Coordination Complexes
  129. 8.1.02: History of Coordination Complexes
  130. 8.1.03: Nomenclature and Ligands
  131. 8.1.04: Coordination Numbers and Structures
  132. 8.1.05: Isomerism
  133. 8.02: Crystal Field Theory
  134. 8.2.01: Crystal Field Theory
  135. 8.2.02: Crystal Field Stabilization Energy
  136. 8.2.03: Non-octahedral Complexes
  137. 8.03: Crystal Field Theory and Magnetism
  138. 8.3.01: Jahn-Teller Distortions
  139. 8.3.02: Magnetism
  140. 8.3.03: Magnetic Moments of Transition Metals
  141. 8.3.04: Ferro- Ferri- and Antiferromagnetism
  142. 8.04: Ligand Field Theory
  143. 8.4.01: Ligand Field Theory
  144. 8.4.02: The Spectrochemical Series
  145. 8.4.03: Factors That Affect Ligand Field Splitting
  146. 8.4.04: Octahedral vs. Tetrahedral Geometries
  147. 8.05: Absorption Spectroscopy of Coordination Complexes
  148. 8.5.01: Absorption of Light
  149. 8.5.02: Colors of Coordination Complexes
  150. 8.5.03: Charge-Transfer Spectra
  151. 8.06: Tanabe Sugano Diagrams
  152. 8.6.01: Tanabe-Sugano Diagrams
  153. 8.6.02: Selection Rules
  154. 8.6.03: Applications of Tanabe-Sugano Diagrams
  155. 8.6.04: Tetrahedral Complexes
  156. 09: Reactions of Coordination Complexes
  157. 9.01: Substitution Reactions
  158. 9.1.01: Review of Reaction Thermodynamics and Kinetics
  159. 9.1.02: Introduction to Substitution Reactions
  160. 9.1.03: Ligand Substitution Mechanisms
  161. 9.1.04: Some Reasons for Differing Mechanisms
  162. 9.1.4.01: Dissociation
  163. 9.1.4.02: Associative Mechanisms
  164. 9.1.05: Thermodynamic Stability and Chelate Effect
  165. 9.1.06: Kinetic Lability
  166. 9.1.07: The Trans Effect
  167. 9.02: RedOx Reactions
  168. 9.2.01: Redox Mechanisms
  169. 9.2.02: Inner Sphere Electron Transfer
  170. 9.2.03: Outer Sphere Electron Transfer
  171. 9.03: Unit 9 Practice Problems
  172. 10: Organometallic Chemistry
  173. 10.01: Organometallic Complexes
  174. 10.1.01: Introduction to Organometallic Chemistry
  175. 10.1.02: Ligand Nomenclature and Classification
  176. 10.1.03: Survey of Common Organometallic Ligands
  177. 10.1.04: Electron Counting and the 18 Electron Rule
  178. 10.02: Organometallic Reactions
  179. 10.2.01: Ligand Dissociation and Substitution
  180. 10.2.02: Oxidative Addition
  181. 10.2.03: Reductive Elimination
  182. 10.2.04: Migratory Insertion- 12-Insertions
  183. 10.2.05: -Elimination Reactions
  184. 10.2.06: Organometallic Catalysts