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CHE360: Inorganic Chemistry
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Mục lục· 106 mục
- 01: Introduction to Inorganic Chemistry
- 1.01: What is Inorganic Chemistry
- 1.02: History of Inorganic Chemistry
- 02: Atomic Structure
- 2.01: Historical Development of Atomic Theory
- 2.02: The Periodic Table
- 2.03: Discovery of Subatomic Particles and the Bohr Atom
- 2.04: The Schrodinger equation particle in a box and atomic wavefunctions
- 2.4.01: Particle in a Box
- 2.05: Quantum Numbers and Atomic Wave Functions
- 2.06: Aufbau Principle
- 2.07: Shielding
- 2.08: Periodic Properties of Atoms
- 2.8.01: Covalent and Ionic Radii
- 2.09: Ionization energy
- 2.10: Electron Affinity
- 2.11: Lanthanide Contraction
- 03: Simple Bonding Theory
- 3.01: Lewis Electron-Dot Diagrams
- 3.02: Resonance
- 3.03: Breaking the octet rule with higher electron counts (hypervalent atoms)
- 3.04: Formal Charge
- 3.05: Lewis Fails to Predict Unusual Cases - Boron and Beryllium
- 3.06: Valence Shell Electron-Pair Repulsion
- 3.07: Lone Pair Repulsion
- 3.08: Multiple Bonds
- 3.09: Electronegativity and Atomic Size Effects
- 3.10: Ligand Close Packing
- 3.11: Molecular Polarity
- 3.12: Hydrogen Bonding
- 04: Coordination Chemistry I- Structures and Isomers
- 4.01: Prelude to Coordination Chemistry I - Structure and Isomers
- 4.02: History
- 4.03: Nomenclature and Ligands
- 4.04: Isomerism
- 4.05: Coordination Numbers and Structures
- 4.06: Coordination Frameworks
- 05: Symmetry and Group Theory
- 5.01: Symmetry Elements and Operations
- 5.02: Point Groups
- 5.03: Groups of Low and High Symmetry
- 5.04: Other Groups
- 5.05: Properties and Representations of Groups
- 5.06: Matrices
- 5.07: Representations of Point Groups
- 5.08: Character Tables
- 5.09: Examples and Applications of Symmetry
- 5.10: Chirality
- 5.11: Molecular Vibrations
- 06: Molecular Orbitals
- 6.01: Formation of Molecular Orbitals from Atomic Orbitals
- 6.02: Molecular Orbitals from s Orbitals
- 6.03: Molecular Orbitals from p Orbitals
- 6.04: Molecular orbitals from d orbitals
- 6.05: Nonbonding Orbitals and Other Factors
- 6.06: Homonuclear Diatomic Molecules
- 6.07: Molecular Orbitals
- 6.08: Orbital Mixing
- 6.09: Diatomic Molecules of the First and Second Periods
- 6.10: Heteronuclear Diatomic Molecules
- 6.11: Orbital ionization energies
- 6.12: Polar bonds
- 6.13: Larger (Polyatomic) Molecules
- 6.14: Bifluoride anion
- 6.15: Carbon Dioxide
- 6.16: HO
- 6.17: NH
- 6.18: CO (Revisted with Projection Operators)
- 6.19: BF
- 6.20: Ionic Compounds and Molecular Orbitals
- 07: Acid-Base and Donor-Acceptor Chemistry
- 7.01: Lewis Concept and Frontier Orbitals
- 7.02: The frontier orbital approach considers Lewis acid base reactions in terms of the donation of electrons from the base's highest occupied orbital into the acid's lowest unoccupied orbital.
- 7.03: All other things being equal electron withdrawing groups tend to make Lewis acids stronger and bases weaker while electron donating groups tend to make Lewis bases stronger and acids weaker
- 7.04: The electronic spectra of charge transfer complexes illustrate the impact of frontier orbital interactions on the electronic structure of Lewis-Acid base adducts
- 7.05: Hard and Soft Acids and Bases
- 7.06: Quantitative Measures of Hardness Softness and Acid-Base Interactions from a Hard Soft Acid-Base Principle perspective involve orbital energies and or apportioning acid-base bonding in terms of electrostatic and covalent factors
- 7.07: Hard-Hard and Soft-Soft preferences may be explained and quantified in terms of electrostatic and covalent and electronic stabilization on the stability of Lewis acid-base adducts
- 08: The Crystalline Solid State
- 8.01: Molecular Orbitals and Band Structure
- 8.02: Prelude to Electronic Properties of Materials - Superconductors and Semiconductors
- 8.03: Metal-Insulator Transitions
- 8.04: Periodic Trends- Metals Semiconductors and Insulators
- 8.05: Semiconductors- Band Gaps Colors Conductivity and Doping
- 8.06: Semiconductor p-n Junctions
- 8.07: Diodes LEDs and Solar Cells
- 8.08: Lattice Structures in Crystalline Solids
- 8.09: Superconductors
- 09: Coordination Chemistry II- Bonding
- 9.01: Evidence for Electronic Structures
- 9.02: Thermodynamic Data
- 9.03: Magnetic Susceptibility
- 9.04: Crystal Field Theory
- 9.05: Ligand Field Theory
- 9.06: Ligand Field Theory - Molecular Orbitals for an Octahedral Complex
- 9.07: Orbital Splitting and Electron Spin
- 9.08: Ligand Field Stabilization Energy
- 9.09: Tetrahedral Complexes
- 9.10: Ligand Field Theory New Page
- 9.11: Angular Overlap
- 9.12: Sigma Bonding in the Angular Overlap Model
- 9.13: Pi Acceptors in the Angular Overlap Model
- 9.14: Pi Donors in the Angular Overlap Model
- 9.15: The Spectrochemical Series
- 9.16: The Magnitude of Parameters e e and
- 9.17: The Jahn-Teller Effect