Nguồn ngoài

Lecture Textbook

Chemistry

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Nguồn: LibreTexts
Ngôn ngữ: EN
Danh mục: Khoa học cơ bản

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Mục lục· 136 mục

01: Introduction to Organic Structure and Bonding I
1.01: Prelude to Atoms Electron Configurations and Lewis Structures
1.02: Drawing organic structures
1.03: Functional groups and organic nomenclature
1.04: Structures of some important biomolecules
1.4.01: Introduction to amino acids and proteins
1.4.02: Introduction to carbohydrate structure
1.4.03: Introduction to lipid structure
1.4.04: Introduction to nucleic acid (DNA and RNA) structure
1.05: Solutions to Chapter 1 Exercises
1.06: Problems for Chapter 1
1.6.01: Solutions to selected Chapter 1 problems
02: Introduction to Organic Structure and Bonding II
2.01: Prelude to Organic Structure and Bonding II
2.02: Valence Bond Theory
2.03: Molecular orbital theory- conjugation and aromaticity
2.04: Resonance
2.05: Non-covalent interactions
2.06: Physical properties of organic compounds
2.07: Solutions to Chapter 2 exercises
2.08: Problems for Chapter 2
2.8.01: Solutions to selected chapter 2 problems
03: Conformations and Stereochemistry
3.01: Prelude to Conformations and Stereochemistry
3.02: Conformations of open-chain organic molecules
3.03: Conformations of cyclic organic molecules
3.04: Chirality and stereoisomers
3.05: Naming chiral centers- the R and S system
3.06: Optical Activity
3.07: Compounds with multiple chiral centers
3.08: Meso Compounds
3.09: Fischer and Haworth projections
3.10: Stereochemistry of alkenes
3.11: Stereochemistry in biology and medicine
3.12: Prochirality
3.13: Solutions to Chapter 3 exercises
3.14: Problems for Chapter 3
04: Structure Determination I- UV-Vis and Infrared Spectroscopy Mass Spectrometry
4.01: Prelude to Structure Determination I
4.02: Introduction to molecular spectroscopy
4.03: Mass Spectrometry
4.04: Infrared spectroscopy
4.05: Ultraviolet and visible spectroscopy
4.06: Problems for Chapter 4
05: Overview of Organic Reactivity
5.01: Prelude to Organic Reactivity
5.02: A First Look at Some Organic Reaction Mechanisms
5.03: A Quick Review of Thermodynamics and Kinetics
5.04: Catalysis
5.05: Comparing Biological Reactions to Laboratory Reactions
5.06: Overview of Organic Reactivity (Problems)
5.07: Overview of Organic Reactivity (Summary)
06: Acid-base Reactions
6.01: Prelude to Acid-base Reactions
6.02: Overview of Acid-Base Reactions
6.03: The Acidity Constant
6.04: Structural Effects on Acidity and Basicity
6.05: Acid-base Properties of Phenols
6.06: Acid-base properties of nitrogen-containing functional groups
6.07: Carbon Acids
6.08: Polyprotic Acids
6.09: Effects of enzyme microenvironment on acidity and basicity
6.P: Acid-base Reactions (Problems)
6.S: Acid-base Reactions (Summary)
07: Nucleophilic Substitution Reactions
7.01: Prelude to Nucleophilic Substitution Reactions
7.02: Two Mechanistic Models for Nucleophilic Substitution
7.03: Nucleophiles
7.04: Electrophiles
7.05: Leaving Groups
7.06: Regiochemistry of SN1 Reactions with Allylic Electrophiles
7.07: SN1 or SN2 Predicting the Mechanism
7.08: Biological Nucleophilic Substitution Reactions
7.09: Nucleophilic substitution in the Lab
7.10: Nucleophilic Substitution Reactions (Problems)
7.11: Nucleophilic Substitution Reactions (Summary)
08: Alkyl Halides and Elimination Reactions
8.01: General Features of Elimination
8.02: The Mechanisms of Elimination
8.03: The E2 Mechanism
8.04: The Zaitsev Rule
8.05: The E1 Mechanism
8.06: SN1 and E1 Reactions
8.07: Stereochemistry of the E2 Reaction
8.08: E2 Reactions and Alkyne Synthesis
8.09: AlkenesThe Products of Elimination Reactions
8.10: When Is the Reaction SN1 SN2 E1 or E2
8.P: Nucleophilic Substitution and Elimination Reactions (Problems)
09: Structure Determination Part II - Nuclear Magnetic Resonance Spectroscopy
9.01: Prelude to Structure Determination
9.02: The Origin of the NMR Signal
9.03: Chemical Equivalence
9.04: The 1H-NMR experiment
9.05: The Basis for Differences in Chemical Shift
9.06: Spin-Spin Coupling
9.07: 13C-NMR Spectroscopy
9.08: Solving Unknown Structures
9.09: Complex Coupling in Proton Spectra
9.10: Other Applications of NMR
9.11: Structure Determination (Problems)
9.12: Structure Determination (Summary)
10: Electrophilic Reactions
10.01: Prelude to Electrophilic Reactions
10.02: Electrophilic Addition to Alkenes
10.03: Elimination by the E1 Mechanism
10.04: Electrophilic Isomerization
10.05: Electrophilic Substitution
10.06: Carbocation Rearrangements
10.07: Alkenes
10.P: Electrophilic Reactions (Problems)
10.S: Electrophilic Reactions (Summary)
11: Alkenes
11.01: Preparation of Alkenes
11.02: Introduction to Addition Reactions
11.03: Stereochemistry of Electrophilic Addition of HX
11.04: Stereochemistry of Halogenation
11.05: Keeping Track of Reactions
11.06: Interesting Alkenes
11.07: HydrohalogenationElectrophilic Addition of HX
11.08: Markovnikovs Rule
11.09: HydrationElectrophilic Addition of Water
11.10: HalogenationAddition of Halogen
11.11: HydroborationOxidation
11.12: LipidsPart 2
11.13: Alkenes and Alkynes I (Problems)
12: Alkynes
12.01: Interesting Alkynes
12.02: Preparation of Alkynes
12.03: Introduction to Alkyne Reactions
12.04: Addition of Hydrogen Halides to Alkynes
12.05: Addition of Halogen to Alkynes
12.06: Addition of Water to Alkynes
12.07: Reaction of Acetylide Anions
12.08: Synthesis
12.09: HydroborationOxidation of Alkynes
12.10: Alkenes and Alkynes II (Problems)