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CHE200 - Introduction to Organic Chemistry (Resch)

Chemistry

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Ngôn ngữ: EN
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01: Introduction to Organic Structure and Bonding I
1.01: Prelude to Atoms Electron Configurations and Lewis Structures
1.02: Drawing organic structures
1.03: Functional groups and organic nomenclature
1.04: Structures of some important biomolecules
1.4.01: Introduction to amino acids and proteins
1.4.02: Introduction to carbohydrate structure
1.4.03: Introduction to lipid structure
1.4.04: Introduction to nucleic acid (DNA and RNA) structure
1.05: Solutions to Chapter 1 Exercises
1.P: Problems for Chapter 1
1.01: Solutions to selected Chapter 1 problems
02: Introduction to Organic Structure and Bonding II
2.01: Prelude to Organic Structure and Bonding II
2.02: Valence Bond Theory
2.03: Molecular orbital theory- conjugation and aromaticity
2.04: Resonance
2.05: Non-covalent interactions
2.06: Physical properties of organic compounds
2.07: Solutions to Chapter 2 exercises
2.P: Problems for Chapter 2
1.01: Solutions to selected chapter 2 problems
03: Conformations and Stereochemistry
3.01: Prelude to Conformations and Stereochemistry
3.02: Conformations of open-chain organic molecules
3.03: Conformations of cyclic organic molecules
3.04: Chirality and stereoisomers
3.05: Naming chiral centers- the R and S system
3.06: Optical Activity
3.07: Compounds with multiple chiral centers
3.08: Meso Compounds
3.09: Fischer and Haworth projections
3.10: Stereochemistry of alkenes
3.11: Stereochemistry in biology and medicine
3.12: Prochirality
3.13: Solutions to Chapter 3 exercises
3.P: Problems for Chapter 3
04: Overview of Organic Reactivity
4.01: Prelude to Organic Reactivity
4.02: A First Look at Some Organic Reaction Mechanism
4.03: A Quick Review of Thermodynamics and Kinetics
4.04: Catalysis
4.05: Comparing Biological Reactions to Laboratory Reactions
4.E: Overview of Organic Reactivity (Exercises)
4.S: Overview of Organic Reactivity (Summary)
05: Acid-base Reactions
5.01: Prelude to Acid-base Reactions
5.02: Overview of Acid-Base Reactions
5.03: The Acidity Constant
5.04: Structural Effects on Acidity and Basicity
5.05: Acid-base Properties of Phenols
5.06: Acid-base properties of nitrogen-containing functional groups
5.07: Carbon Acids
5.08: Polyprotic Acids
5.09: Effects of enzyme microenvironment on acidity and basicity
5.E: Acid-base Reactions (Exercises)
5.S: Acid-base Reactions (Summary)
06: Radical Reactions
6.01: Prelude to Radical Reactions
6.02: Overview of Single-Electron Reactions and Free Radicals
6.03: Radical Chain Reactions
6.04: Useful Polymers formed by Radical Chain Reactions
6.05: Destruction of the Ozone Layer by a Radical Chain Reaction
6.06: Oxidative Damage to cells Vitamin C and Scurvy
6.07: Flavin as a One-Electron Carrier
6.E: Radical Reactions (Exercises)
07: Nucleophilic Substitution Reactions
7.01: Prelude to Nucleophilic Substitution Reactions
7.02: Two Mechanistic Models for Nucleophilic Substitution
7.03: Nucleophiles
7.04: Electrophiles
7.05: Leaving Groups
7.06: Regiochemistry of SN1 Reactions with Allylic Electrophiles
7.07: SN1 or SN2 Predicting the Mechanism
7.08: Biological Nucleophilic Substitution Reactions
7.09: Nucleophilic substitution in the Lab
7.E: Nucleophilic Substitution Reactions (Exercises)
7.S: Nucleophilic Substitution Reactions (Summary)
08: Nucleophilic Carbonyl Addition Reactions
8.01: Prelude to Nucleophilic Carbonyl Addition Reactions
8.02: Nucleophilic Additions to Aldehydes and Ketones - An Overview
8.03: Hemiacetals Hemiketals and Hydrates
8.04: Acetals and Ketals
8.05: N-glycosidic Bonds
8.06: Imines
8.07: A Look Ahead - Addition of Carbon and Hydride Nucleophiles to Carbonyls
8.E: Nucleophilic Carbonyl Addition Reactions (Exercises)
8.S: Nucleophilic Carbonyl Addition Reactions (Summary)
09: Nucleophilic Acyl Substitution Reactions
9.01: Prelude to Nucleophilic Acyl Substitution Reactions
9.02: Carboxylic Acid Derivatives
9.03: The Nucleophilic Acyl Substitution Mechanism
9.04: Acyl Phosphates
9.05: The Relative Reactivity of Carboxylic Acid Derivatives
9.06: Acyl Phosphates
9.07: Hydrolysis of Thioesters Esters and Amides
9.08: Protein Synthesis on the Ribosome
9.09: Nucleophilic Substitution at Activated Amides and Carbamides
9.10: Nucleophilic Acyl Substitution Reactions in the Laboratory
9.11: A Look Ahead - Acyl Substitution Reactions with a Carbanion or Hydride Ion Nucleophile
9.E: Nucleophilic Acyl Substitution Reactions (Exercises)
9.S: Nucleophilic Acyl Substitution Reactions (Summary)
10: Electrophilic Reactions
10.01: Prelude to Electrophilic Reactions
10.02: Electrophilic Addition to Alkenes
10.03: Elimination by the E1 Mechanism
10.04: Electrophilic Isomerization
10.05: Electrophilic Substitution
10.06: Carbocation Rearrangements
10.E: Electrophilic Reactions (Exercises)
10.S: Electrophilic Reactions (Summary)
11: Oxidation and Reduction Reactions
11.01: Prelude to Oxidation and Reduction Reactions
11.02: Oxidation and Reduction of Organic Compounds - An Overview
11.03: Oxidation and Reduction in the Context of Metabolism
11.04: Hydrogenation of Carbonyl and Imine Groups
11.05: Hydrogenation of alkenes and Dehydrogenation of Alkanes
11.06: Monitoring Hydrogenation and Dehydrogenation Reactions by UV Spectroscopy
11.07: Redox Reactions of Thiols and Disulfides
11.08: Flavin-Dependent Monooxygenase Reactions - Hydroxylation Epoxidation and the Baeyer-Villiger Oxidation
11.09: Hydrogen Peroxide is a Harmful - Reactive Oxygen Species
11.E: Oxidation and Reduction Reactions (Exercises)
11.S: Oxidation and Reduction Reactions (Summary)
12: Reactions at the -Carbon Part II
12.01: Prelude to Reactions at the -Carbon Part II
12.02: Decarboxylation
12.03: An Overview of Fatty Acid Metabolism
12.04: Claisen Condensation
12.05: Conjugate Addition and Elimination
12.06: Carboxylation
12.E: Reactions at the -Carbon Part II (Exercises)
12.S: Reactions at the -Carbon Part II (Summary)
13: Reactions at the -Carbon Part I
13.01: Prelude to Reactions at the -carbon part I
13.02: Review of Acidity at the -Carbon
13.03: Isomerization at the -Carbon
13.04: Aldol Addition
13.05: -Carbon Reactions in the Synthesis Lab - Kinetic vs. Thermodynamic Alkylation Products
13.E: Reactions at the -Carbon Part I (Exercises)
13.S: Reactions at the -Carbon Part I (Summary)
14: The Organic Chemistry of Vitamins
14.01: Prelude to the Organic Chemistry of Vitamins
14.02: Pyridoxal Phosphate (Vitamin B6)
14.03: Thiamine Diphosphate (Vitamin B1)
14.04: Thiamine Diphosphate Lipoamide and the Pyruvate Dehydrogenase Reaction
14.05: Folate
14.E: The Oganic Chemistry of Vitamins (Exercises)
14.S: The Oganic Chemistry of Vitamins (Summary)